Common Many-Body Hamiltonians
A many-body Hamiltonian is not fully specified by one line of algebra. The same formula can describe different physics when the Hilbert space, statistics, lattice, boundary conditions, filling, sign conventions, cutoff, or ensemble changes.
If the unresolved question is which family can predict a material observable, start with Choosing a Model for Quantum Matter. This page begins after that choice and supplies convention-aware formulas and canonical model links.
This page collects eleven standard Hamiltonian families:
- continuum bosons with contact interactions;
- continuum fermions with two-body interactions;
- tight-binding particles;
- the spinless – chain;
- the fermionic Hubbard model;
- the Bose–Hubbard model;
- the Heisenberg model;
- the transverse-field Ising model;
- the reduced BCS pairing model;
- the Anderson impurity model;
- the Kondo impurity model.
It is a convention-aware lookup sheet. The Model Encyclopedia owns convention-complete dossiers, comparisons, solution-status labels, and benchmark handoffs. The linked teaching pages own derivations, phase structure, methods, and applications. The Model-to-Volume Cross-Link Index records which page owns each layer and where planned applications will live.
Read the Formula with Its Data
Section titled “Read the Formula with Its Data”Before using any row, state:
- the Hilbert space and local degrees of freedom;
- bosonic, fermionic, spin, or constrained statistics;
- continuum or lattice geometry and spatial dimension;
- open, periodic, twisted, or other boundary conditions;
- fixed particle number or grand-canonical controls;
- which bonds or ordered pairs are included in each sum;
- whether spin operators or Pauli matrices are used;
- the ultraviolet regulator or lattice spacing;
- the approximation and energy window in which the model is valid.
The notation
denotes a grand Hamiltonian. Many papers call simply “the Hamiltonian.” This sheet keeps and distinct whenever the distinction prevents a convention error.
Quick Comparison
Section titled “Quick Comparison”| Model | Degrees of freedom | Competing scales | Canonical continuation |
|---|---|---|---|
| continuum contact bosons | bosonic field | kinetic energy, , density | Field Operators in Many-Body Models |
| continuum interacting fermions | spinful fermionic fields | kinetic energy, interaction, density | Field Operators in Many-Body Models |
| tight binding | particles in localized orbitals | hopping, onsite energies | Tight-Binding Chain |
| spinless – chain | one spinless fermion mode per site | , , filling | Spinless Fermion Chains |
| Hubbard | spin- lattice fermions | , , filling | Hubbard Model |
| Bose–Hubbard | lattice bosons | , , | Bose–Hubbard Model |
| Heisenberg | localized spins | exchange , fields | Heisenberg Model |
| transverse-field Ising | spin- sites | Ising exchange, transverse field | Transverse-Field Ising Model |
| reduced BCS | time-reversed fermion pairs | attraction, cutoff, density of states | Exact dossier; BCS Mean-Field Theory |
| Anderson impurity | one correlated orbital and bath fermions | , , hybridization function | model dossier; teaching preview |
| Kondo | impurity spin and conduction fermions | , bandwidth, density of states | model dossier; screening and RG |
Continuum Bosons with Contact Interaction
Section titled “Continuum Bosons with Contact Interaction”Hilbert space and algebra
Section titled “Hilbert space and algebra”Use bosonic Fock space over a continuum one-particle space, with equal-time algebra
The density and total number are
Hamiltonian
Section titled “Hamiltonian”A common effective Hamiltonian is
The corresponding grand Hamiltonian is
The factor avoids double counting pairs. The displayed contact term is normal ordered.
Convention and validity notes
Section titled “Convention and validity notes”- denotes repulsion in the displayed convention.
- Coincident-point products require a regulator and matching prescription.
- In a dilute three-dimensional pseudopotential regime,
where is the -wave scattering length.
- This relation is not a cutoff-independent microscopic identity at arbitrary density, range, or dimension.
- The model conserves when no source or conversion term is added.
Useful limits
Section titled “Useful limits”| Limit | Result |
|---|---|
| ideal continuum Bose gas | |
| weak depletion and low temperature | Bogoliubov expansion around a condensate |
| strong short-range repulsion in one dimension | Lieb–Liniger and Tonks–Girardeau regimes, with convention changes |
| periodic potential and localized Wannier basis | Bose–Hubbard model after projection |
For the detailed operator form, momentum-space normalization, and regularization cautions, use Field Operators in Many-Body Models.
Continuum Fermions with Two-Body Interaction
Section titled “Continuum Fermions with Two-Body Interaction”Hilbert space and algebra
Section titled “Hilbert space and algebra”For components ,
The total number is
General number-conserving Hamiltonian
Section titled “General number-conserving Hamiltonian”A standard one-body operator is
The grand Hamiltonian is
Convention and validity notes
Section titled “Convention and validity notes”- Hermiticity requires the interaction kernel to obey the appropriate exchange-conjugation relation.
- The factor assumes the integration counts both ordered particle pairs.
- For identical single-component fermions, a zero-range -wave contact term vanishes because two fields at the same point anticommute.
- A two-component contact interaction can be written
with the sign of setting attraction or repulsion in the displayed convention.
- Coulomb, dipolar, finite-range, and effective interactions require their own kernels and regularization.
- Random Phase Approximation owns the self-consistent density response and screened interaction generated from a specified direct kernel.
Useful limits
Section titled “Useful limits”| Limit | Result |
|---|---|
| ideal Fermi gas | |
| weak short-range attraction | Cooper instability and BCS reduction near the Fermi surface |
| periodic potential and one-band projection | tight-binding or Hubbard descriptions |
| low-energy quasiparticle regime | Landau Fermi-liquid description when applicable |
Tight-Binding Hamiltonian
Section titled “Tight-Binding Hamiltonian”The derivation, finite boundaries, graph form, and band connection are developed in Tight-Binding Model. This section is the compact convention reference.
Hilbert space
Section titled “Hilbert space”Choose localized orbitals . The same one-body form can act on a one-particle Hilbert space or on a bosonic or fermionic Fock space. Filling and statistics must be specified before assigning many-body meaning.
General form
Section titled “General form”Hermiticity requires
For real nearest-neighbor hopping with each unordered bond counted once,
One-dimensional dispersion
Section titled “One-dimensional dispersion”For a periodic chain with lattice spacing ,
The sign of fixes where the band minimum occurs in this convention. It can be changed by a sublattice gauge transformation only for selected bipartite hopping networks.
What is absent
Section titled “What is absent”The tight-binding term alone contains no interaction. Calling a partially filled tight-binding band a metal, insulator, magnet, or superconductor requires filling, dimensionality, symmetry, interactions, disorder, and boundary conditions.
Spinless t–V Chain
Section titled “Spinless t–V Chain”Hilbert space and algebra
Section titled “Hilbert space and algebra”Retain one spinless fermionic mode per site,
For sites, the fixed- sector has dimension .
Centered Hamiltonian
Section titled “Centered Hamiltonian”For an open chain,
The centered convention makes particle-hole symmetry occur at on an even bipartite chain. Replacing the interaction by requires a corresponding chemical-potential and constant shift.
For a ring, include the th bond and specify
The twist , the filling , and whether the model is defined directly or obtained through the Jordan–Wigner Transformation are part of the Hamiltonian data.
Standard one-dimensional facts
Section titled “Standard one-dimensional facts”At ,
At half filling for , the uniform thermodynamic chain is phase separated for , is a gapless Luttinger liquid for , and has gapped period-two charge order for . The endpoint at is a Berezinskii–Kosterlitz–Thouless transition.
After a staggered hopping-sign transformation, the XXZ parameters are
Spinless Fermion Chains owns the free solution, correlators, phase interpretation, transport twist, and finite-size parity caveats. XXZ Spin Chain owns the canonical spin-chain treatment.
Fermionic Hubbard Model
Section titled “Fermionic Hubbard Model”Hilbert space
Section titled “Hilbert space”Each site has four local states,
For sites, the unrestricted Fock space has dimension .
Fixed-number Hamiltonian
Section titled “Fixed-number Hamiltonian”Here
The grand Hamiltonian is
Sign and filling conventions
Section titled “Sign and filling conventions”- in the displayed nearest-neighbor convention.
- is repulsive and attractive.
- The filling is
- Half filling is , because each site has two spin modes.
- Each unordered bond appears once when the Hermitian conjugate is written explicitly.
Useful limits
Section titled “Useful limits”| Limit | Result |
|---|---|
| spinful tight-binding fermions | |
| independent atomic sites | |
| repulsive near half filling | low-energy spin model with superexchange |
| onsite pairing tendency |
At half filling in the large-repulsion regime, the leading exchange scale is
for the standard two-site hopping convention. Higher-order and lattice-dependent terms are omitted.
The full conventions, symmetries, limits, and strong-coupling derivation live in Hubbard Model.
Bose–Hubbard Model
Section titled “Bose–Hubbard Model”Hilbert space
Section titled “Hilbert space”Each lattice site is a bosonic mode with
Numerical calculations often impose a maximum occupation as a truncation. That cutoff is not part of the exact model.
Grand Hamiltonian
Section titled “Grand Hamiltonian”For a fixed- calculation, omit the chemical-potential term and restrict the Hilbert space to
Convention notes
Section titled “Convention notes”- is onsite repulsion.
- The factor counts unordered onsite pairs.
- is the atomic limit.
- The competition between and organizes the standard Mott-lobe diagram.
- At integer filling, large suppresses number fluctuations; large favors phase coherence.
The full conventions, limits, optical-lattice reduction, and mean-field boundary live in Bose–Hubbard Model. Bose–Hubbard Dimer owns the exact two-mode fixed-number specialization, while Bose–Hubbard Chain owns the one-dimensional soft-core model and its hard-core and Luttinger limits. The compact model card remains a lookup entry, while Quantum Phase Transitions owns the generic critical interpretation.
Heisenberg Model
Section titled “Heisenberg Model”Hilbert space
Section titled “Hilbert space”Place a spin- representation on each site:
Let be dimensionless spin operators satisfying
Isotropic exchange Hamiltonian
Section titled “Isotropic exchange Hamiltonian”Each unordered bond is counted once. The field is measured in energy units.
For uniform nearest-neighbor exchange,
Sign convention
Section titled “Sign convention”With the displayed plus sign:
- is antiferromagnetic;
- is ferromagnetic.
For two spin- sites,
Common variants
Section titled “Common variants”is anisotropic and generally has less symmetry than the isotropic model. Dzyaloshinskii–Moriya exchange, longer-range bonds, single-ion anisotropy, and multi-spin interactions are distinct extensions.
For the uniform spin- chain with and , use XXZ Spin Chain for phase structure, Jordan–Wigner fermions, and integrability.
Use Heisenberg Model for exchange spectra, symmetries, limiting cases, and approximation methods.
Transverse-Field Ising Model
Section titled “Transverse-Field Ising Model”Hilbert space and convention
Section titled “Hilbert space and convention”For spin- sites with Pauli matrices,
The Ising interaction and transverse-field terms do not commute.
Symmetry
Section titled “Symmetry”The global spin flip
satisfies
It changes
Pauli versus spin operators
Section titled “Pauli versus spin operators”If
then
Couplings must therefore be rescaled when changing notation.
One-dimensional benchmark
Section titled “One-dimensional benchmark”For the infinite nearest-neighbor chain in the displayed convention, the critical point is
Boundary conditions and parity sectors matter in the finite Jordan–Wigner solution. Use Ising Chain for the compact model card, Transverse-Field Ising Model for the model treatment and exact-solution preview, and Quantum Phase Transitions for general critical scaling.
Reduced BCS Pairing Hamiltonian
Section titled “Reduced BCS Pairing Hamiltonian”Hilbert space
Section titled “Hilbert space”Use spinful fermionic momentum modes. The reduced interaction scatters pairs of time-reversed states,
Define
Grand Hamiltonian
Section titled “Grand Hamiltonian”Here
denotes attraction in the displayed convention, and is the pairing shell or model space.
Number conservation and mean field
Section titled “Number conservation and mean field”The reduced interaction has two creation and two annihilation operators, so the exact reduced Hamiltonian conserves total particle number:
The usual BCS mean-field approximation introduces
and obtains quasiparticle energies
The unprojected mean-field state is not an eigenstate of . Do not confuse that approximation with number nonconservation in the exact reduced pairing Hamiltonian.
Use Reduced BCS Model for seniority sectors, Richardson equations, and the exact finite-level benchmark; BCS Mean-Field Theory for the Cooper instability, gap equation, and quasiparticle derivation; and BCS Model for the compact model card.
Anderson Impurity Hamiltonian
Section titled “Anderson Impurity Hamiltonian”Hilbert space
Section titled “Hilbert space”The model combines:
- one spinful localized fermion orbital with states , , , and ;
- a Fock space of noninteracting bath fermions;
- coherent bath–impurity tunneling.
Hamiltonian
Section titled “Hamiltonian”With all one-particle energies measured relative to the equilibrium chemical potential,
The atomic impurity energies are
For repulsive , the atomic local-moment window is
Hybridization means that impurity charge is not conserved even though total charge is.
Bath convention
Section titled “Bath convention”The bath and tunneling amplitudes enter through
For the retarded boundary value,
with
Thus an unweighted bath density of states is not enough to specify the impurity problem. In the common wide-band convention, constant is the half-width of the noninteracting impurity resonance.
The Anderson Impurity Model dossier owns the compact specification, hybridization conventions, regime and exact-status map, observable–method dictionary, and finite benchmark. Anderson Impurity Model Preview owns the resonant-level derivation, impurity spectra, thermodynamics, transport, solution-method narrative, and DMFT connection. Effective Hamiltonians in Many-Body Systems owns the comparative Kondo reduction and its validity audit.
Kondo Impurity Hamiltonian
Section titled “Kondo Impurity Hamiltonian”Hilbert space
Section titled “Hilbert space”The model combines:
- a localized impurity spin ;
- a Fock space of conduction electrons;
- a local exchange interaction at the impurity position.
Hamiltonian
Section titled “Hamiltonian”where the local conduction-electron spin density is
The normalization of determines the units assigned to . A bandwidth or ultraviolet cutoff and conduction density of states are part of the model.
Sign convention and physics
Section titled “Sign convention and physics”With the displayed plus sign:
- is antiferromagnetic and favors local singlet formation;
- is ferromagnetic.
For an isolated pair of spin- objects,
The many-electron Kondo problem is not merely this two-spin spectrum. Repeated low-energy scattering produces logarithmic scale dependence and, for antiferromagnetic exchange, a Kondo scale schematically of the form
up to convention-dependent prefactors and definitions. Here is a conduction-band cutoff and is the spin-summed local density of states. With a per-spin density , the same exponent is . This formula is an asymptotic weak-coupling scale, not an exact universal equality.
Common extensions include potential scattering, anisotropic exchange, multiple channels, multiple impurities, and lattice versions. Each changes the symmetry and possible low-energy behavior.
The Kondo Model dossier owns the compact specification, normalization conventions, solvability map, controlled limits, observable–method dictionary, and finite benchmark. The Kondo Model Preview owns the one-loop flow, screening interpretation, thermodynamics, screening cloud, and low-energy local Fermi-liquid narrative.
Conserved Quantities at a Glance
Section titled “Conserved Quantities at a Glance”| Model as displayed | Total particle number | Spin symmetry | Translation symmetry |
|---|---|---|---|
| continuum bosons | conserved | depends on components | if and regulator permit |
| continuum fermions | conserved | depends on | if kernels are translation invariant |
| tight binding | conserved | often spin independent | only for a periodic uniform lattice |
| spinless – chain | conserved | no retained spin degree of freedom | only for a periodic uniform chain |
| Hubbard | conserved | spin for the standard spin-independent form | only for a uniform lattice |
| Bose–Hubbard | conserved | not applicable for one component | only for a uniform lattice |
| Heisenberg | no particle number | global without anisotropy or field | only for a uniform exchange network |
| TFIM | no particle number | discrete | only for uniform couplings |
| reduced BCS | conserved exactly | reduced by the pairing structure | momentum-space form assumes translation invariance |
| Anderson impurity | total bath-plus-impurity number conserved | for spin-independent parameters | broken by the impurity |
| Kondo impurity | conduction number conserved | for isotropic exchange | broken by the impurity |
Additional conserved quantities can arise from integrability, point-group symmetry, bipartite structure, or special parameter choices.
How the Models Connect
Section titled “How the Models Connect”Continuum to lattice
Section titled “Continuum to lattice”Expanding a continuum field in localized orbitals,
turns kinetic and periodic-potential terms into hopping matrix elements and short-range interactions into onsite and extended lattice couplings. Truncating to one band is an approximation controlled only when higher bands remain sufficiently separated.
Tight binding to Hubbard
Section titled “Tight binding to Hubbard”Adding an onsite interaction to spinful tight-binding fermions gives the standard single-band Hubbard structure:
Spinless fermions to XXZ
Section titled “Spinless fermions to XXZ”In one dimension, the Jordan–Wigner Transformation maps nearest-neighbor spinless hopping and density interaction to transverse and longitudinal spin exchange. With centered density and a staggered hopping-sign convention,
For a periodic chain, the spin boundary induces a fermionic twist tied to total parity. The local bulk parameter map does not remove that finite-size boundary condition.
Hubbard to Heisenberg
Section titled “Hubbard to Heisenberg”At exact half filling in the no-doublon sector and for , virtual hopping through doubly occupied states produces antiferromagnetic exchange:
Inside the singly occupied subspace, on occupied bonds, so the density term is an additive constant.
Effective Hamiltonians in Many-Body Systems derives the projection and explains why doped systems also retain projected hopping and same-order three-site terms.
Fermions to reduced BCS
Section titled “Fermions to reduced BCS”Projecting an attractive interaction onto time-reversed states near a Fermi surface yields the reduced pairing model. The projection discards other scattering channels and introduces a cutoff or model shell.
Anderson impurity to Kondo
Section titled “Anderson impurity to Kondo”When
the empty and doubly occupied impurity states are virtual at low energy. A Schrieffer–Wolff transformation projects onto the singly occupied doublet and generates
for the normalized local-orbital convention. The reduction fails near a charge degeneracy or in mixed valence.
The two charge denominators, potential-scattering term, and normalization conventions are derived in Effective Hamiltonians in Many-Body Systems.
Lattice spins to continuum fields
Section titled “Lattice spins to continuum fields”Near a continuous transition, a spin Hamiltonian can produce a continuum order-parameter or quasiparticle field theory. That continuum theory is an effective long-wavelength description, not a literal replacement of Pauli matrices at every lattice scale.
Model-Specification Checklist
Section titled “Model-Specification Checklist”For reproducible work, record:
- the exact Hamiltonian or grand Hamiltonian;
- the operator algebra and local Hilbert space;
- lattice graph, dimension, and boundary conditions;
- bond-counting convention;
- parameter signs and units;
- particle number, filling, or chemical potential;
- conserved symmetry sector;
- ultraviolet cutoff, basis truncation, or maximum occupation;
- energy, temperature, and momentum regime;
- approximation method and omitted terms;
- observable definitions;
- finite-size and thermodynamic-limit procedure.
Common Mistakes
Section titled “Common Mistakes”- Calling a fixed- Hamiltonian without stating the convention.
- Counting each lattice bond twice while also writing an explicit Hermitian conjugate.
- Switching between Pauli matrices and spin operators without rescaling couplings.
- Using the same symbol with opposite ferro- and antiferromagnetic sign conventions.
- Treating as a universal bare coupling at every cutoff.
- Writing a same-component fermion -wave contact term without addressing antisymmetry.
- Calling a one-body tight-binding band a correlated many-body model.
- Treating the spinless – chain as free when .
- Mixing centered and uncentered – conventions without shifting .
- Forgetting the parity-dependent boundary twist when the chain comes from periodic spins.
- Forgetting that half filling in the spinful Hubbard model is .
- Omitting the onsite-pair factor in the Bose–Hubbard interaction.
- Treating as exact outside the large- low-energy regime.
- Assuming the reduced BCS Hamiltonian itself violates number conservation.
- Treating the impurity charge as fixed in an Anderson model with nonzero hybridization.
- Specifying an Anderson bath without the weighted hybridization function.
- Replacing an Anderson impurity by a Kondo spin outside the local-moment regime.
- Quoting a Kondo temperature without defining the bandwidth, density of states, and coupling convention.
- Applying a model beyond the band, density, temperature, or interaction regime used to derive it.
Cross-Links
Section titled “Cross-Links”- Many-Body and Quantum Statistical Mechanics
- Choosing a Model for Quantum Matter
- Symbols and Conventions
- Common Spin Hamiltonians
- Operator Identities
- Occupation-Number Representation
- Field Operators in Many-Body Models
- Many-Particle Hamiltonians
- Hubbard Model
- Heisenberg Model
- XXZ Spin Chain
- Spinless Fermion Chains
- Anderson Impurity Model
- Anderson Impurity Model Preview
- Kondo Model
- Kondo Model Preview
- Quantum Phase Transitions
- Tight-Binding Chain
- Bose–Hubbard Model
- Bose–Hubbard Model Card
- BCS Mean-Field Theory
- BCS Model
- Ising Chain
- Many-Body Model Cards
- Spin Model Cards
- Most-Used Hamiltonians
- Common Hamiltonians Table
- Ensemble Formula Sheet
References
Section titled “References”- A. L. Fetter and J. D. Walecka, Quantum Theory of Many-Particle Systems, Dover (2003).
- A. Altland and B. Simons, Condensed Matter Field Theory, 2nd ed., Cambridge University Press (2010).
- P. Coleman, Introduction to Many-Body Physics, Cambridge University Press (2015).
- J. Hubbard, “Electron Correlations in Narrow Energy Bands”, Proceedings of the Royal Society A 276, 238–257 (1963).
- M. P. A. Fisher, P. B. Weichman, G. Grinstein, and D. S. Fisher, “Boson Localization and the Superfluid-Insulator Transition”, Physical Review B 40, 546–570 (1989).
- W. Heisenberg, “Zur Theorie des Ferromagnetismus”, Zeitschrift für Physik 49, 619–636 (1928).
- P. Pfeuty, “The One-Dimensional Ising Model with a Transverse Field”, Annals of Physics 57, 79–90 (1970).
- J. Bardeen, L. N. Cooper, and J. R. Schrieffer, “Theory of Superconductivity”, Physical Review 108, 1175–1204 (1957).
- P. W. Anderson, “Localized Magnetic States in Metals”, Physical Review 124, 41–53 (1961).
- J. Kondo, “Resistance Minimum in Dilute Magnetic Alloys”, Progress of Theoretical Physics 32, 37–49 (1964).
- J. R. Schrieffer and P. A. Wolff, “Relation between the Anderson and Kondo Hamiltonians”, Physical Review 149, 491–492 (1966).
- A. C. Hewson, The Kondo Problem to Heavy Fermions, Cambridge University Press (1993).
- P. Jordan and E. Wigner, “Über das Paulische Äquivalenzverbot”, Zeitschrift für Physik 47, 631–651 (1928).
- E. Lieb, T. Schultz, and D. Mattis, “Two Soluble Models of an Antiferromagnetic Chain”, Annals of Physics 16, 407–466 (1961).
Exercises
Section titled “Exercises”- Hermiticity of hopping. Show that
is Hermitian when .
Solution
Take the adjoint:
Relabel :
If
then
For a restricted bond sum, the same condition is implemented by writing the Hermitian-conjugate hopping explicitly.
- Onsite boson pair counting. Explain why the Bose–Hubbard interaction energy on a site with bosons is rather than .
Solution
The number of unordered pairs among particles is
If each onsite pair costs energy , then
The expression vanishes for and , as it should because no pair is present. The alternative contains an unphysical one-particle self-interaction unless compensated by a linear term.
- Number conservation in the reduced BCS model. Show by operator counting that the pair-scattering term commutes with total number.
Solution
For total fermion number ,
The pair-scattering monomial
contains two creation and two annihilation operators. Using the commutator product rule, its net number change is
Therefore the exact reduced BCS Hamiltonian commutes with . Number uncertainty enters the usual unprojected mean-field ansatz, not the exact pair-scattering operator.
- Exchange sign for two spins. For two spin- sites with
find the singlet and triplet energies and identify which is favored for each sign of .
Solution
Use
For two spin- objects,
The singlet has total spin , so
The triplet has total spin , so
Thus favors the singlet and is antiferromagnetic, while favors the triplet and is ferromagnetic in the displayed convention.
- Hubbard superexchange scale. Explain why the leading low-energy exchange near half filling scales as and state the standard coefficient.
Solution
In the large- singly occupied subspace, one hop creates a virtual doubly occupied site and an empty site. That intermediate state costs energy of order . A second hop returns the system to the low-energy subspace, possibly exchanging the two spins.
Second-order perturbation theory therefore produces an amplitude proportional to
For the standard nearest-neighbor Hubbard hopping convention, adding the allowed virtual processes gives
For , this is positive and therefore antiferromagnetic in the convention
The result assumes , near-half filling, and projection to the low-energy subspace.
- Kondo exchange sign. Treat the impurity and one local conduction spin as two spin- objects. What energy splitting does produce?
Solution
The same two-spin eigenvalues apply:
Therefore
and the splitting is
Antiferromagnetic favors the singlet. The full Kondo effect additionally involves the continuum of conduction states and logarithmic renormalization; it is not exhausted by this two-spin calculation.
- Anderson impurity charge window. In the atomic limit, compare the energies of , , and . For , determine when the singly occupied states have the lowest energy.
Solution
The atomic energies are
Single occupation lies below the empty state when
It lies below the doubly occupied state when
or
Therefore the atomic local-moment window is
Finite hybridization rounds the charge boundaries and makes the impurity occupancy fluctuate.