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Off-Diagonal Long-Range Order

Off-diagonal long-range order (ODLRO) is macroscopic coherence encoded in a reduced density matrix. Its basis-independent signature is an eigenvalue whose scaling is parametrically larger than the ordinary background:

bosonic one-body condensation⟺N0=O(N),fermion-pair condensation⟺Λ0=O(N).\begin{gathered} \text{bosonic one-body condensation} \\ \Longleftrightarrow \\ N_0 = O(N), \\ \text{fermion-pair condensation} \\ \Longleftrightarrow \\ \Lambda_0 = O(N). \end{gathered}

Here N0N_0 is an eigenvalue of the one-body reduced density matrix, whereas Λ0\Lambda_0 is an eigenvalue of the fermionic two-body density matrix on antisymmetric pair space. The two criteria have the same logic but act on different body ranks because Pauli exclusion prevents a fermionic one-body eigenvalue from becoming macroscopic.

The word “off-diagonal” does not mean that some matrix element happens to be nonzero in a chosen basis. It refers historically to matrix elements between configurations that remain macroscopically separated. The spectral criterion is safer: eigenvalues survive basis changes, while individual diagonal and off-diagonal entries do not.

ODLRO supplies a number-conserving language for condensates. A fixed-particle-number state can have

⟨ψ(x)⟩=0\langle\psi(x)\rangle = 0

or

⟨ψ↓(x)ψ↑(x′)⟩=0\langle\psi_\downarrow(x)\psi_\uparrow(x')\rangle = 0

and still possess a macroscopic density-matrix eigenvalue. This distinction connects exact finite systems, symmetry-preserving thermodynamic states, and broken-symmetry approximations without identifying them.

This page is the canonical home for:

  • the reduced-density-matrix definition of ODLRO;
  • the common reduced-density-matrix logic connecting the Penrose–Onsager bosonic criterion to Yang’s fermion-pair criterion;
  • the relation between macroscopic eigenvalues and long-distance one-body or pair-correlation limits;
  • simple and fragmented condensation;
  • fixed-number and broken-number descriptions of the same long-distance coherence;
  • pair internal structure, center-of-mass motion, and finite-momentum condensates;
  • gauge covariance of density-matrix kernels and the special caution required for charged pairs;
  • finite-size, low-dimensional, numerical, and experimental diagnostics;
  • distinctions from pair binding, a spectral gap, superfluid stiffness, Meissner response, and entanglement.

Neighboring pages retain separate ownership:

  • One-Body Operators owns one-body lifting, expectation values, and the basic one-body density-matrix convention.
  • Two-Body Operators owns two-body operator ordering, trace conventions, contractions, and representability caveats.
  • Equal-Time Correlations owns the general static one-body and pair correlators.
  • Bose–Einstein Condensation owns the full Penrose–Onsager treatment, ideal-gas saturation mechanism, critical temperature, condensate fraction, traps, and the distinction from superfluid fraction.
  • BCS Mean-Field Theory owns the Cooper instability, anomalous decoupling, gap and number equations, coherence factors, and quasiparticles.
  • Order Parameters owns the general operator–source–response dictionary.
  • Spontaneous Symmetry Breaking owns phase selection, noncommuting limits, finite-size symmetric states, and broken-symmetry sectors.
  • Long-Range Order owns diagonal correlation plateaus, volume averages, and structure-factor scaling for local order.

The purpose here is to expose the common density-matrix structure without repeating those derivations.

Use Superfluidity in Condensed Matter when a density-matrix coherence diagnostic must be joined to neutral-material stiffness, critical flow, or two-fluid evidence. Use Superfluidity and Superconductivity for charged, defect, or device routing; this page retains ODLRO ownership.

Thermodynamic and Normalization Conventions

Section titled “Thermodynamic and Normalization Conventions”

ODLRO is a statement about a sequence of systems. Unless stated otherwise:

  • NN particles occupy a region of volume V=LdV=L^d;
  • N,V→∞N,V\to\infty at fixed density n=N/Vn=N/V;
  • the body rank of the reduced density matrix remains fixed;
  • reduced density matrices are unnormalized, so their traces count particles or ordered particle tuples;
  • the thermodynamic limit is taken before the large-separation limit;
  • a macroscopic eigenvalue means an eigenvalue proportional to NN, with a nonzero limiting ratio.

At finite size, every density matrix merely has finite eigenvalues. It is therefore more precise to say that a finite system shows scaling consistent with ODLRO than to claim a strict long-range limit from one size.

For variable particle number, NN in ratios should be replaced by ⟨N⟩\langle N\rangle and number fluctuations should be reported. Comparing a canonical calculation at fixed NN with a grand-canonical calculation at fixed chemical potential can otherwise confuse ensemble effects with condensation.

For one field species, define the unnormalized pp-body kernel

Γ(p)(x1,…,xp;x1′,…,xp′)=⟨ψ†(x1′)⋯ψ†(xp′)ψ(xp)⋯ψ(x1)⟩.\begin{aligned} \Gamma^{(p)} (&x_1,\ldots,x_p; x_1',\ldots,x_p') \\ ={}& \left\langle \psi^\dagger(x_1') \cdots \psi^\dagger(x_p') \psi(x_p) \cdots \psi(x_1) \right\rangle . \end{aligned}

Each xx may include position, spin, species, band, or another one-particle label. In a fixed-NN sector,

Tr⁡Γ(p)=N(N−1)⋯(N−p+1).\operatorname{Tr}\Gamma^{(p)} = N(N-1)\cdots(N-p+1).

The first two levels are

γ=Γ(1),Γ(2).\gamma = \Gamma^{(1)}, \qquad \Gamma^{(2)}.

They answer different questions:

KernelNatural modesMacroscopic coherence diagnosed here
bosonic γ\gammaone-particle orbitalsBose condensation
fermionic γ\gammaone-particle orbitalsno one-body ODLRO because occupations are Pauli bounded
fermionic Γ(2)\Gamma^{(2)}antisymmetric pair wavefunctionspair condensation
bosonic Γ(p)\Gamma^{(p)}symmetric pp-particle modeshigher-body coherence, with normalization-dependent powers of NN

The last row warns against a common overgeneralization. In a simple bosonic condensate, the leading pp-body eigenvalue scales as the falling factorial N(N−1)⋯(N−p+1)N(N-1)\cdots(N-p+1), not merely as NN. The O(N)O(N) two-body criterion discussed below is specifically the conventional fermion-pair criterion on normalized antisymmetric pair space.

The one-body reduced density matrix is

γ(x,x′)=⟨ψ†(x′)ψ(x)⟩.\gamma(x,x') = \left\langle \psi^\dagger(x') \psi(x) \right\rangle .

In an orthonormal one-particle basis,

γij=⟨aj†ai⟩.\gamma_{ij} = \left\langle a_j^\dagger a_i \right\rangle .

It is Hermitian:

γ(x,x′)∗=γ(x′,x).\gamma(x,x')^* = \gamma(x',x).

It is positive semidefinite. For a normalized orbital ff with

af=∫ddx f∗(x)ψ(x),a_f = \int d^d x\, f^*(x)\psi(x),

one has

⟨f∣γ∣f⟩=⟨af†af⟩≥0.\langle f\vert\gamma\vert f\rangle = \langle a_f^\dagger a_f\rangle \geq 0.

Its trace is the mean particle number:

Tr⁡γ=∫ddx γ(x,x)=⟨N⟩.\operatorname{Tr}\gamma = \int d^d x\, \gamma(x,x) = \langle N\rangle .

These properties make γ\gamma a positive one-particle operator even though it is not normalized to unit trace.

The spectral problem is

∫ddx′ γ(x,x′)ϕα(x′)=Nαϕα(x).\int d^d x'\, \gamma(x,x') \phi_\alpha(x') = N_\alpha\phi_\alpha(x).

The orthonormal eigenfunctions ϕα\phi_\alpha are natural orbitals, and the eigenvalues NαN_\alpha are natural occupations. The spectral decomposition is

γ(x,x′)=∑αNαϕα(x)ϕα∗(x′).\gamma(x,x') = \sum_\alpha N_\alpha \phi_\alpha(x) \phi_\alpha^*(x').

Positivity and the trace rule imply

Nα≥0,∑αNα=⟨N⟩.N_\alpha \geq 0, \qquad \sum_\alpha N_\alpha = \langle N\rangle .

A change of one-particle basis conjugates γ\gamma by a unitary operator. It changes the entries and coordinates of the natural orbitals but not the multiset of eigenvalues.

The complete bosonic treatment and its ideal-gas applications belong to Bose–Einstein Condensation. The criterion is recorded here in the notation needed to compare one-body and pair ODLRO.

A simple bosonic condensate has one extensive natural occupation:

lim⁡N→∞N0N=f0>0,\lim_{N\to\infty} \frac{N_0}{N} = f_0 > 0,

while

Nα>0N⟶0.\frac{N_{\alpha>0}}{N} \longrightarrow 0.

The number f0f_0 is the condensate fraction in this convention. This definition does not require the condensate orbital to be an eigenstate of the bare one-particle Hamiltonian. In an interacting, disordered, rotating, or trapped system, ϕ0\phi_0 is determined by the many-body state through γ\gamma.

A large occupation at one finite size is not yet a limiting statement. One must test whether N0N_0 remains proportional to NN along a controlled thermodynamic sequence.

From a Macroscopic Eigenvalue to a Spatial Limit

Section titled “From a Macroscopic Eigenvalue to a Spatial Limit”

In a translation-invariant box, write

γ(r)=⟨ψ†(0)ψ(r)⟩.\gamma(\mathbf r) = \left\langle \psi^\dagger(\mathbf0) \psi(\mathbf r) \right\rangle .

With plane-wave occupations nkn_{\mathbf k},

γ(r)=1V∑knkeik⋅r.\gamma(\mathbf r) = \frac{1}{V} \sum_{\mathbf k} n_{\mathbf k} e^{i\mathbf k\cdot\mathbf r}.

If the k=0\mathbf k=\mathbf0 mode has

n0V⟶n0>0\frac{n_{\mathbf0}}{V} \longrightarrow n_0 > 0

and the noncondensed momentum distribution is sufficiently regular, its Fourier transform decays at large separation. Therefore

lim⁡∣r∣→∞lim⁡V→∞γ(r)=n0.\lim_{\lvert\mathbf r\rvert\to\infty} \lim_{V\to\infty} \gamma(\mathbf r) = n_0.

Since n=N/Vn=N/V,

f0=n0n.f_0 = \frac{n_0}{n}.

The real-space plateau and the extensive plane-wave occupation are then equivalent descriptions of the same simple homogeneous condensate.

If the macroscopic orbital is a plane wave at k0\mathbf k_0, then

γ(r)=n0eik0⋅r+γreg(r),\gamma(\mathbf r) = n_0 e^{i\mathbf k_0\cdot\mathbf r} + \gamma_{\mathrm{reg}}(\mathbf r),

and the phase-demodulated limit is

lim⁡∣r∣→∞lim⁡V→∞e−ik0⋅rγ(r)=n0.\lim_{\lvert\mathbf r\rvert\to\infty} \lim_{V\to\infty} e^{-i\mathbf k_0\cdot\mathbf r} \gamma(\mathbf r) = n_0.

Condensation therefore need not mean zero momentum. Rotation, synthetic gauge fields, multiple band minima, or driven settings can select nonzero momentum. The ordering wavevector must be diagnosed rather than assumed.

At fixed finite VV, periodic images, exact recurrences, a largest available separation, and symmetry-induced level splittings prevent a literal infinite-distance limit. The meaningful order is

lim⁡∣r∣→∞lim⁡V→∞,\lim_{\lvert\mathbf r\rvert\to\infty} \lim_{V\to\infty},

not

lim⁡V→∞lim⁡∣r∣→∞.\lim_{V\to\infty} \lim_{\lvert\mathbf r\rvert\to\infty}.

This is the same thermodynamic discipline required for other forms of long-range order. A plateau observed only near L/2L/2 can be a boundary or periodic-image artifact.

In a trap or an explicitly inhomogeneous state, translation averaging is unavailable. A simple condensate contributes

γ(x,x′)=N0ϕ0(x)ϕ0∗(x′)+γreg(x,x′).\gamma(x,x') = N_0 \phi_0(x) \phi_0^*(x') + \gamma_{\mathrm{reg}}(x,x').

The condensate orbital may decay toward the edge, so no position-independent plateau exists even when N0=O(N)N_0=O(N). The spectrum of γ\gamma is the canonical diagnostic; a separation-only fit is not.

The thermodynamic limit for a trap must also be declared. Holding the trapping frequency fixed while increasing NN is not the same sequence as weakening the trap so the cloud size grows at fixed central density.

A condensate is fragmented when two or more natural occupations remain extensive:

lim⁡N→∞NαN=fα>0\lim_{N\to\infty} \frac{N_\alpha}{N} = f_\alpha > 0

for more than one α\alpha. The macroscopic eigenspace, rather than any one vector inside a degenerate subspace, is then the invariant object.

Fragmentation can reflect:

  • exact symmetries or conserved quantities;
  • degenerate one-particle minima;
  • multicomponent structure;
  • rotation or finite-momentum sectors;
  • strong correlations and interaction-driven constraints;
  • averaging over symmetry-related condensates.

Two large occupations in an arbitrary orbital basis do not prove fragmentation. One must diagonalize γ\gamma. Conversely, a nearly degenerate pair of large finite-size eigenvalues may collapse to one extensive eigenvalue after a symmetry-selecting field is applied. Genuine fragmentation and finite-size symmetry restoration must therefore be distinguished by controlled limits.

For a simple condensate, the ratio

N1N0⟶0\frac{N_1}{N_0} \longrightarrow 0

is often informative. It is not universal: critical, low-dimensional, or nearly degenerate systems can have several subextensive eigenvalues with nontrivial scaling.

Let

∣N:ϕ0⟩=(a0†)NN!∣0⟩\lvert N:\phi_0\rangle = \frac{ \left(a_0^\dagger\right)^N }{ \sqrt{N!} } \lvert0\rangle

be a number state with every boson in ϕ0\phi_0. Number conservation gives

⟨N:ϕ0∣ψ(x)∣N:ϕ0⟩=0.\langle N:\phi_0\vert \psi(x) \vert N:\phi_0\rangle = 0.

Nevertheless,

γ(x,x′)=Nϕ0(x)ϕ0∗(x′),\gamma(x,x') = N \phi_0(x) \phi_0^*(x'),

so γ\gamma has the eigenvalue NN. The state has maximal one-body ODLRO even though its field expectation vanishes exactly.

In a source-selected or symmetry-breaking state, define

Φ(x)=⟨ψ(x)⟩.\Phi(x) = \langle\psi(x)\rangle.

If the selected phase clusters,

γ(x,x′)⟶Φ(x)Φ∗(x′)\gamma(x,x') \longrightarrow \Phi(x)\Phi^*(x')

when the two points separate through the bulk. The outer product generates the macroscopic eigenvalue.

A phase average can restore

⟨ψ(x)⟩=0\langle\psi(x)\rangle = 0

while retaining the same number-neutral kernel γ\gamma. Thus the anomalous one-point field is a useful representative in a selected phase, whereas the one-body density matrix is the number-conserving diagnostic.

For a simple homogeneous condensate under appropriate clustering assumptions, the following descriptions agree in the thermodynamic limit:

N0=O(N),γ(r)⟶n0eik0⋅r,Φ(r)≠0in a selected phase.\begin{gathered} N_0 = O(N), \\ \gamma(\mathbf r) \longrightarrow n_0e^{i\mathbf k_0\cdot\mathbf r}, \\ \Phi(\mathbf r) \neq 0 \quad \text{in a selected phase}. \end{gathered}

The qualifications matter. Fragmentation, traps, gauge fields, finite-size symmetry restoration, and algebraic order can break a naive one-to-one translation among these statements.

For a normalized fermionic orbital ff,

nf=cf†cfn_f = c_f^\dagger c_f

is a projector. Therefore

0≤⟨nf⟩≤1.0 \leq \langle n_f\rangle \leq 1.

The variational characterization of the largest eigenvalue then gives

0≤να≤10 \leq \nu_\alpha \leq 1

for every eigenvalue να\nu_\alpha of the fermionic one-body density matrix. Since

∑ανα=N,\sum_\alpha\nu_\alpha = N,

fermions occupy O(N)O(N) one-particle natural orbitals rather than placing O(N)O(N) particles in one orbital. A normal Fermi sea can have a slowly decaying one-body kernel and a sharp Fermi surface, but it cannot have bosonic one-body ODLRO.

Pairing changes the body rank of the question. A pair mode can be macroscopically occupied even though neither constituent one-particle orbital is.

Choose an orthonormal one-particle basis and label an unordered fermion pair by

A=(a,b),a<b.A = (a,b), \qquad a<b.

Define

PA=cbca,PA†=ca†cb†.P_A = c_b c_a, \qquad P_A^\dagger = c_a^\dagger c_b^\dagger.

The pair density matrix is

MAB=⟨PA†PB⟩.\mathcal M_{AB} = \left\langle P_A^\dagger P_B \right\rangle.

It is positive semidefinite because, for

Bu=∑AuAPA,B_u = \sum_A u_A P_A,

one has

u†Mu=⟨Bu†Bu⟩≥0.u^\dagger\mathcal M u = \langle B_u^\dagger B_u\rangle \geq 0.

In a fixed-NN sector its trace on unordered pair space is

Tr⁡M=N(N−1)2.\operatorname{Tr}\mathcal M = \frac{N(N-1)}{2}.

The full ordered-index convention used for Γ(2)\Gamma^{(2)} has trace N(N−1)N(N-1). The two conventions differ by bookkeeping factors but yield the same scaling classification when used consistently.

Diagonalize

∑BMABuB(α)=ΛαuA(α).\sum_B \mathcal M_{AB} u_B^{(\alpha)} = \Lambda_\alpha u_A^{(\alpha)}.

Fermionic pair ODLRO is present when

lim⁡N→∞Λ0N=λ0>0.\lim_{N\to\infty} \frac{\Lambda_0}{N} = \lambda_0 > 0.

The leading eigenvector specifies the condensed pair mode. Its labels contain both constituent orbitals, so it carries the internal spin, orbital, band, and relative-coordinate structure of the pair.

Although Tr⁡M=O(N2)\operatorname{Tr}\mathcal M=O(N^2), ordinary uncorrelated pairs distribute that trace over O(N2)O(N^2) pair modes with eigenvalues of order one. Pair ODLRO concentrates an order-NN weight into one pair eigenmode. That concentration is the nontrivial statement.

It is common to quote 2Λ0/N2\Lambda_0/N as a pair condensate fraction. This normalization can be convenient, but it is not automatically a probability between zero and one for every interacting convention. Overlapping Cooper-pair operators are composite and do not obey exact canonical-boson commutation relations. Report the pair basis and normalization with the number.

Using the first-pair-as-annihilation convention,

Γ(2)(1,2;1′,2′)=⟨ψ†(1′)ψ†(2′)ψ(2)ψ(1)⟩.\begin{aligned} \Gamma^{(2)} (&1,2;1',2') \\ ={}& \left\langle \psi^\dagger(1') \psi^\dagger(2') \psi(2) \psi(1) \right\rangle . \end{aligned}

The pair eigenproblem is

∫d1′ d2′ Γ(2)(1,2;1′,2′)×Φα(1′,2′)=ΛαΦα(1,2).\begin{aligned} &\int d1'\,d2'\, \Gamma^{(2)} (1,2;1',2') \\ &\qquad\times \Phi_\alpha(1',2') = \Lambda_\alpha \Phi_\alpha(1,2). \end{aligned}

For fermions,

Φα(1,2)=−Φα(2,1).\Phi_\alpha(1,2) = - \Phi_\alpha(2,1).

The antisymmetry can be carried by spin, spatial, orbital, or combined internal structure. Saying only “the pair wavefunction” is incomplete until the one-particle labels and normalization are declared.

For a continuum pair, introduce

R=r1+r22,r=r1−r2.\mathbf R = \frac{\mathbf r_1+\mathbf r_2}{2}, \qquad \mathbf r = \mathbf r_1-\mathbf r_2.

The internal coordinate r\mathbf r describes pair size and symmetry. The center coordinate R\mathbf R describes the collective motion of pairs. A projected pair annihilator is

Δf(R)=∫ddr f(r)×ψ↓(R−r2)×ψ↑(R+r2).\begin{aligned} \Delta_f(\mathbf R) ={}& \int d^d r\, f(\mathbf r) \\ &\times \psi_\downarrow \left( \mathbf R-\frac{\mathbf r}{2} \right) \\ &\times \psi_\uparrow \left( \mathbf R+\frac{\mathbf r}{2} \right). \end{aligned}

The form factor ff selects an internal channel. On a lattice, the integral becomes a sum over onsite, bond, plaquette, or longer-range relative coordinates.

Define

Pf(R,R′)=⟨Δf†(R)Δf(R′)⟩.P_f(\mathbf R,\mathbf R') = \left\langle \Delta_f^\dagger(\mathbf R) \Delta_f(\mathbf R') \right\rangle .

For a homogeneous zero-momentum pair condensate,

lim⁡∣R−R′∣→∞lim⁡V→∞Pf(R,R′)=Pf>0\lim_{\lvert\mathbf R-\mathbf R'\rvert\to\infty} \lim_{V\to\infty} P_f(\mathbf R,\mathbf R') = \mathcal P_f > 0

when ff has nonzero overlap with the condensed internal mode. The pair size is held microscopic while the separation between pair centers becomes macroscopic.

A finite-momentum pair condensate instead has

Pf(R,R′)⟶PfeiQ⋅(R′−R).P_f(\mathbf R,\mathbf R') \longrightarrow \mathcal P_f e^{i\mathbf Q\cdot(\mathbf R'-\mathbf R)}.

This includes pair-density-wave and η\eta-pairing-type structures. Demodulating by the candidate Q\mathbf Q or diagonalizing the full pair matrix avoids averaging the signal to zero.

The limit is channel dependent. Projecting onto an ss-wave form factor can miss dd-wave order, and summing bonds with the wrong relative signs can cancel the leading eigenvector.

One-body and pair off-diagonal long-range order represented by distant configurations and macroscopic density-matrix eigenvalues.

ODLRO is a spectral statement about a reduced density matrix. Bosonic one-body coherence connects distant one-particle configurations and produces N0∼NN_0\sim N. Fermionic pair coherence keeps each pair internally compact while separating its center of mass, producing Λ0∼N\Lambda_0\sim N. One extensive eigenvalue indicates simple condensation; several indicate fragmentation or multiple condensed channels; a wholly subextensive spectrum has no true ODLRO.

The BCS state provides a transparent illustration, not the definition. Let

bk=c−k↓ck↑,b_{\mathbf k} = c_{-\mathbf k\downarrow} c_{\mathbf k\uparrow},

and define

Fk=⟨bk⟩,nk=⟨ck↑†ck↑⟩.F_{\mathbf k} = \langle b_{\mathbf k}\rangle, \qquad n_{\mathbf k} = \left\langle c_{\mathbf k\uparrow}^\dagger c_{\mathbf k\uparrow} \right\rangle .

For the standard spin-balanced Gaussian BCS state, Wick’s theorem gives

Mkk′=⟨bk†bk′⟩=Fk∗Fk′+δkk′nk2.\begin{aligned} M_{\mathbf k\mathbf k'} &= \left\langle b_{\mathbf k}^\dagger b_{\mathbf k'} \right\rangle \\ &= F_{\mathbf k}^* F_{\mathbf k'} + \delta_{\mathbf k\mathbf k'} n_{\mathbf k}^2. \end{aligned}

The first term is rank one. Its nonzero eigenvalue is

∑k∣Fk∣2.\sum_{\mathbf k} \lvert F_{\mathbf k}\rvert^2.

When FkF_{\mathbf k} remains appreciable over an extensive set of momentum modes,

∑k∣Fk∣2=O(V)=O(N).\sum_{\mathbf k} \lvert F_{\mathbf k}\rvert^2 = O(V) = O(N).

The diagonal term has bounded entries, so it changes the leading eigenvalue by at most an order-one amount under the standard thermodynamic assumptions. The pair matrix therefore has one extensive eigenvalue.

This calculation separates several objects that are often conflated:

ObjectRole
FkF_{\mathbf k}anomalous pair amplitude in a broken-number Gaussian state
Δk\Delta_{\mathbf k}self-consistent mean field entering the BCS Hamiltonian
leading eigenvector of MMnumber-conserving condensed pair mode
quasiparticle gapspectral excitation scale
Λ0\Lambda_0occupation scale of the condensed pair mode

These objects are related within BCS mean field, but they are not definitions of one another. In particular,

∑k∣Fk∣2\sum_{\mathbf k} \lvert F_{\mathbf k}\rvert^2

is generally not N/2N/2. Weak-coupling Cooper pairs overlap strongly; they are not a gas of distinguishable, tightly bound molecules whose number can be read off by dividing the fermion count by two.

In an exact fixed-NN state or a number-projected BCS state,

Fk=0F_{\mathbf k} = 0

by the number selection rule. The neutral matrix

Mkk′=⟨bk†bk′⟩M_{\mathbf k\mathbf k'} = \langle b_{\mathbf k}^\dagger b_{\mathbf k'}\rangle

can still retain its extensive eigenvalue. This is precisely why the density-matrix criterion is more fundamental than the anomalous average.

Under a one-particle unitary transformation UU,

γ⟼UγU†\gamma \longmapsto U\gamma U^\dagger

up to the chosen index convention. The eigenvalues are unchanged. The induced transformation on antisymmetric pair space similarly conjugates M\mathcal M, so its eigenvalues are unchanged.

A single entry such as

⟨ai†aj⟩\langle a_i^\dagger a_j\rangle

can become diagonal, off diagonal, or zero after a basis rotation. ODLRO cannot be defined by that entry alone.

Under

ψ⟼eiθψ,\psi \longmapsto e^{i\theta}\psi,

the one-point field and pair amplitude transform as

⟨ψ⟩⟼eiθ⟨ψ⟩,⟨ψψ⟩⟼e2iθ⟨ψψ⟩.\langle\psi\rangle \longmapsto e^{i\theta}\langle\psi\rangle, \qquad \langle\psi\psi\rangle \longmapsto e^{2i\theta}\langle\psi\psi\rangle.

The neutral kernels

⟨ψ†(x′)ψ(x)⟩\langle\psi^\dagger(x')\psi(x)\rangle

and

⟨Δ†(R)Δ(R′)⟩\langle\Delta^\dagger(\mathbf R)\Delta(\mathbf R')\rangle

are invariant under a spatially uniform number rotation. This is why they can diagnose coherence in fixed-number states.

For a field of charge qq, a local gauge transformation acts as

ψ(x)⟼eiqχ(x)/ℏψ(x).\psi(x) \longmapsto e^{iq\chi(x)/\hbar} \psi(x).

The one-body kernel transforms covariantly:

γ(x,x′)⟼eiq[χ(x)−χ(x′)]/ℏγ(x,x′).\gamma(x,x') \longmapsto e^{iq[\chi(x)-\chi(x')]/\hbar} \gamma(x,x').

This is unitary conjugation, so the spectrum is invariant when the one-particle Hilbert space and background fields are transformed consistently. The phase of a spatial matrix element is not itself gauge invariant.

For a compact charged pair,

P(R,R′)=⟨Δ†(R)Δ(R′)⟩P(\mathbf R,\mathbf R') = \langle \Delta^\dagger(\mathbf R) \Delta(\mathbf R') \rangle

also acquires an endpoint phase under a local gauge transformation. Define the line integral along a declared path by

IA(R,R′)=∫RR′A⋅dℓ,\mathcal I_A(\mathbf R,\mathbf R') = \int_{\mathbf R}^{\mathbf R'} \mathbf A\cdot d\boldsymbol\ell,

and the charge-2q2q parallel transporter by

W2q(R,R′)=exp⁡[−2iqℏIA(R,R′)].W_{2q}(\mathbf R,\mathbf R') = \exp\left[ -\frac{2iq}{\hbar} \mathcal I_A(\mathbf R,\mathbf R') \right] .

A gauge-covariant comparison is then, schematically,

Pinv(R,R′)=⟨Δ†(R)W2q(R,R′)×Δ(R′)⟩,\begin{aligned} P_{\mathrm{inv}}(\mathbf R,\mathbf R') ={}& \bigl\langle \Delta^\dagger(\mathbf R) W_{2q}(\mathbf R,\mathbf R') \\ &\qquad\times \Delta(\mathbf R') \bigr\rangle , \end{aligned}

for the convention

A⟼A+∇χ.\mathbf A \longmapsto \mathbf A+\boldsymbol\nabla\chi.

The path, electromagnetic fluctuations, and nonlocal internal pair structure can matter. In a fixed gauge one may study the ordinary pair kernel, but its phase plateau should not be presented as a standalone gauge-invariant observable.

Local gauge redundancy is not an ordinary physical symmetry that must literally break. Superconductivity is established through a consistent collection of number-conserving coherence and electromagnetic-response diagnostics, not by assigning physical meaning to a gauge-dependent field expectation alone.

Let K(R−R′)K(\mathbf R-\mathbf R') denote a translation-invariant one-body or projected pair kernel over center coordinates. If

K(R)∼1Rp,K(\mathbf R) \sim \frac{1}{R^p},

then its largest long-wavelength eigenvalue scales as the integrated correlation:

λmax⁡(L)∼∫aLdR Rd−1−p.\lambda_{\max}(L) \sim \int_a^L dR\, R^{d-1-p}.

Thus

λmax⁡(L)∼{Ld,p=0,Ld−p,0<p<d,log⁡L,p=d,O(1),p>d.\lambda_{\max}(L) \sim \begin{cases} L^d, & p=0, \\ L^{d-p}, & 0<p<d, \\ \log L, & p=d, \\ O(1), & p>d. \end{cases}

Since N∝LdN\propto L^d,

λmax⁡N∼{const.>0,p=0,L−p,0<p<d,L−dlog⁡L,p=d,L−d,p>d.\frac{\lambda_{\max}}{N} \sim \begin{cases} \text{const.}>0, & p=0, \\ L^{-p}, & 0<p<d, \\ L^{-d}\log L, & p=d, \\ L^{-d}, & p>d. \end{cases}

The first line is true ODLRO, the middle two are algebraic or marginal coherence, and the last is integrable short-range order. This table applies to the center-coordinate kernel after fixing or resolving the internal channel. It should not be applied blindly to the full O(V2)O(V^2) pair-coordinate space.

Useful finite-size quantities include

f0(L)=N0(L)N(L)f_0(L) = \frac{N_0(L)}{N(L)}

for bosons and

λ0(L)=Λ0(L)N(L)\lambda_0(L) = \frac{\Lambda_0(L)}{N(L)}

for fermion pairs. Also inspect

λ1(L)λ0(L)\frac{\lambda_1(L)}{\lambda_0(L)}

or

λ0(L)−λ1(L)N(L)\frac{\lambda_0(L)-\lambda_1(L)}{N(L)}

with notation adapted to the matrix being studied. A stable isolated leading eigenvalue supports simple condensation; several extensive eigenvalues support fragmentation or multiple condensed channels.

An apparent eigenvalue gap at one size is not decisive. Near a transition, a finite correlation length larger than the simulated box can mimic extensive scaling over a short range of LL.

In a homogeneous simple condensate, compare:

N0V\frac{N_0}{V}

with the large-distance one-body plateau, or compare

Λ0V\frac{\Lambda_0}{V}

with a channel-projected pair plateau after matching normalizations. Agreement catches Fourier factors, pair-counting factors, and center-of-mass averaging errors.

The eigenvector should also have the expected symmetry. A large eigenvalue in an unexpected edge-localized, boundary-pinned, or phase-separated mode may not diagnose the proposed bulk condensate.

Use γ\gamma for bosonic one-particle condensation and a fermionic pair matrix for superconducting or molecular pair coherence. Do not search for a fermionic one-body eigenvalue of order NN.

State whether an index includes site, position, momentum, spin, band, orbital, and species. For pair matrices, state whether pairs are ordered or restricted to an antisymmetric basis.

Record

Tr⁡γ=N\operatorname{Tr}\gamma = N

and either

Tr⁡M=N(N−1)2\operatorname{Tr}\mathcal M = \frac{N(N-1)}{2}

or the corresponding full-index trace. Trace and Hermiticity checks should pass before eigenvalue scaling is interpreted.

Block diagonalization by conserved momentum, spin, point-group representation, or species can reduce cost and identify the condensed channel. Averaging over a form factor with the wrong signs can instead project the signal away.

Compute several leading eigenvalues, not only the largest. Scale N0/NN_0/N or Λ0/N\Lambda_0/N across fixed density and comparable shapes. Include uncertainties from Monte Carlo sampling, tensor-network truncation, eigensolver tolerance, and extrapolation.

Plot the leading orbital or pair wavefunction. Check bulk support, center-of-mass momentum, internal parity, spin structure, nodes, and boundary localization.

Measure the corresponding long-distance kernel with the same channel and normalization. The spectrum is canonical, but the real-space profile reveals whether a large eigenvalue comes from a plateau, algebraic decay, domain structure, or localization.

For a claimed superfluid or superconductor, separately examine stiffness, current response, flux sensitivity, or other appropriate transport and electromagnetic observables. ODLRO and response are complementary, not interchangeable labels.

Keep aspect ratio, boundary conditions, filling, and flux sector controlled. Open boundaries can localize the leading orbital; periodic boundaries can force commensurate momenta; twisted boundaries can split or move condensate minima.

A global eigenvalue can be dominated by a dense central region. Compare natural-orbital support with the density profile, and define the trap thermodynamic sequence before extrapolating.

Pair-center averaging improves statistics in a homogeneous state:

P‾f(r)=1V∫ddR Pf(R,R+r).\overline P_f(\mathbf r) = \frac{1}{V} \int d^d R\, P_f(\mathbf R,\mathbf R+\mathbf r).

It can hide domains, interfaces, disorder, or boundary localization in an inhomogeneous state. Inspect unaveraged data before imposing translation symmetry.

The internal pair extent must remain small compared with LL for a clean separation between relative and center coordinates. In weak-coupling BCS systems, the coherence length can be large, so boxes smaller than the pair size can strongly distort the eigenvector and scaling.

Nearly degenerate ss-, dd-, triplet, valley, or finite-momentum channels can rotate under small perturbations. Track the macroscopic subspace and symmetry quantum numbers rather than matching eigenvectors by raw component overlap alone.

Exact reduced density matrices are positive semidefinite. Sampling noise can produce small negative eigenvalues and unstable leading eigenvectors. Symmetrize only in ways justified by exact symmetries, propagate covariance where possible, and report whether positivity was imposed during estimation.

In a grand-canonical calculation, large number fluctuations can affect both the trace and the apparent leading eigenvalue. Scale against ⟨N⟩\langle N\rangle, record

⟨(ΔN)2⟩,\langle(\Delta N)^2\rangle,

and compare ensembles when fluctuations are anomalously large.

In many one-dimensional ground states and two-dimensional finite-temperature superfluids,

γ(r)∼r−η\gamma(r) \sim r^{-\eta}

or

Pf(r)∼r−η.P_f(r) \sim r^{-\eta}.

The leading eigenvalue then diverges as

λmax⁡∼Ld−η,\lambda_{\max} \sim L^{d-\eta},

but

λmax⁡N∼L−η⟶0.\frac{\lambda_{\max}}{N} \sim L^{-\eta} \longrightarrow 0.

This is quasi-long-range order or algebraic coherence, not true ODLRO. A finite system can nevertheless have a very large leading eigenvalue and a visually flat correlation function when η\eta is small.

For short-range neutral systems with a continuous U(1)U(1) symmetry, ordinary finite-temperature symmetry breaking and a constant off-diagonal plateau are excluded under the standard assumptions. A Berezinskii–Kosterlitz–Thouless phase can retain algebraic coherence and nonzero stiffness.

Therefore

ρs>0\rho_s > 0

does not imply

lim⁡r→∞γ(r)>0\lim_{r\to\infty}\gamma(r) > 0

in two dimensions at nonzero temperature.

The finite-temperature restriction does not automatically forbid a two-dimensional ground-state condensate. Three-dimensional systems can support true ODLRO at nonzero temperature. In both cases, the result remains model and phase dependent; dimensionality permits rather than guarantees condensation.

Low-Dimensional Quantum Gases develops the infrared mechanisms and trap qualifications.

Magnetic or density-wave order is diagnosed by correlations of local number-neutral operators. ODLRO instead concerns reduced-density kernels that transfer a particle or pair between distant configurations. A phase may have either, both, or neither.

A negative two-particle binding energy or enhanced short-range pair correlation says that two particles favor being near each other. Pair ODLRO says that pair transfer remains coherent across macroscopic distances. A gas of localized, mutually incoherent bound pairs can have strong binding and no extensive pair-matrix eigenvalue.

A single-particle gap can arise from band structure, Mott localization, symmetry breaking, or pairing without global phase coherence. A pseudogap regime can retain local pairing correlations while the long-distance pair matrix remains short ranged. Conversely, some condensed phases possess gapless excitations.

The superfluid density or helicity modulus measures the free-energy response to phase twists or flow. Condensate fraction and superfluid fraction coincide only in special limits. Liquid helium, lattice bosons, disordered systems, and low-dimensional phases make the distinction operationally important.

For charged matter, magnetic-field expulsion and electromagnetic rigidity are response properties. Pair ODLRO is an important coherence diagnostic, but a complete superconducting claim must handle gauge covariance and electromagnetic coupling. Ginzburg–Landau Theory gives the material-scale amplitude and field functional, while the Josephson Effect makes a gauge-invariant phase difference operational through weak-link current and interference. One should not infer those response coefficients from one matter-only density-matrix eigenvalue without additional assumptions.

An anomalous average is representation and phase-sector dependent:

⟨ψψ⟩≠0\langle\psi\psi\rangle \neq 0

can be useful in a selected mean-field state, while it vanishes in every exact fixed-number state. ODLRO resides in a neutral density matrix and survives number projection.

A normal Fermi sea has algebraic one-body correlations at zero temperature and natural occupations bounded by one. Slow decay alone does not turn its fermionic one-body density matrix into a condensate.

Reduced density matrices here are reduced by particle body rank, not necessarily by a spatial tensor-product partition. Their eigenvalues diagnose occupation and coherence, not an entanglement entropy. ODLRO can coexist with little or substantial many-body entanglement.

A Glauber coherent state has a nonzero field expectation and Poissonian number fluctuations. A fixed-NN condensate has the same rank-one one-body density matrix at leading order but a sharp particle number. Condensation is not synonymous with preparation of a coherent state.

For a homogeneous gas, the momentum distribution is the Fourier transform of the one-body kernel:

n(k)=∫ddr e−ik⋅rγ(r).n(\mathbf k) = \int d^d r\, e^{-i\mathbf k\cdot\mathbf r} \gamma(\mathbf r).

A macroscopic natural occupation can produce a sharp momentum-space component, and matter-wave interference probes relative phase coherence. Finite imaging resolution, trap inhomogeneity, interactions during expansion, and finite system size broaden the signal. A narrow peak must be scaled before it is called a thermodynamic condensate.

Pair momentum distributions, pair-transfer interference, noise correlations, and Josephson-type coupling can probe aspects of pair coherence. Most experiments access response functions or projected correlators rather than diagonalizing the complete two-body density matrix. The inferred channel, gauge convention, and dynamical assumptions should be stated.

For superconductors, phase-sensitive junctions, flux quantization, magnetic response, and electrodynamics provide information not contained in a matter-only equal-time pair matrix. Agreement among coherence, spectroscopy, and response diagnostics is stronger evidence than any single proxy.

Individual matrix entries depend on basis and gauge. Diagonalize the reduced density matrix or establish a controlled large-separation limit.

Taking separation to infinity at fixed size

Section titled “Taking separation to infinity at fixed size”

A finite torus or box has no independent infinite-distance limit. Extrapolate the thermodynamic sequence first.

Using a bare-orbital occupation in an interacting trap

Section titled “Using a bare-orbital occupation in an interacting trap”

The condensate orbital is a natural orbital of γ\gamma, not necessarily the noninteracting ground orbital.

Reporting only the largest eigenvalue can miss several extensive eigenvalues or a symmetry-restored macroscopic subspace.

Pauli exclusion bounds every fermionic natural occupation by one. Superconducting coherence belongs in the two-body pair matrix.

Confusing pair binding with pair condensation

Section titled “Confusing pair binding with pair condensation”

Short-distance enhancement, double occupancy, or a two-body bound state does not establish coherence between distant pair centers.

Equating the BCS gap with condensed-pair number

Section titled “Equating the BCS gap with condensed-pair number”

The gap, anomalous amplitude, pair eigenvector, and leading pair eigenvalue are distinct quantities even when mean-field equations relate them.

Ordered and unordered pair bases differ by factors of two. State the trace convention and normalize eigenvectors on the chosen pair space.

Treating a charged pair plateau as gauge invariant

Section titled “Treating a charged pair plateau as gauge invariant”

Specify a gauge or include the appropriate parallel transporter. Physical superconductivity also requires response information.

Fitting an algebraic finite system to a constant

Section titled “Fitting an algebraic finite system to a constant”

Slow power-law decay can mimic a plateau. Compare constant, algebraic, and finite-correlation-length fits and scale the leading eigenvalue.

Exercise 1: Positivity, trace, and condensate fraction

Section titled “Exercise 1: Positivity, trace, and condensate fraction”

Let

γij=⟨aj†ai⟩\gamma_{ij} = \langle a_j^\dagger a_i\rangle

for NN bosons. Prove that γ\gamma is positive semidefinite and has trace NN. Explain why one eigenvalue equal to fN+o(N)fN+o(N) with f>0f>0 defines a basis-independent condensate fraction.

Solution

For an arbitrary vector vv, define

av=∑ivi∗ai.a_v = \sum_i v_i^*a_i.

Then

v†γv=∑ijvi∗⟨aj†ai⟩vj=⟨av†av⟩≥0.\begin{aligned} v^\dagger\gamma v &= \sum_{ij} v_i^* \langle a_j^\dagger a_i\rangle v_j \\ &= \langle a_v^\dagger a_v\rangle \geq 0. \end{aligned}

Thus γ\gamma is positive semidefinite. In a complete one-particle basis,

Tr⁡γ=∑i⟨ai†ai⟩=⟨N⟩=N.\operatorname{Tr}\gamma = \sum_i \langle a_i^\dagger a_i\rangle = \langle N\rangle = N.

Under a one-particle basis change,

γ⟼UγU†,\gamma \longmapsto U\gamma U^\dagger,

so its eigenvalues are unchanged. Hence

f=lim⁡N→∞N0Nf = \lim_{N\to\infty} \frac{N_0}{N}

does not depend on which orbital coordinates were used to represent the state.

Exercise 2: Plane-wave occupation and spatial plateau

Section titled “Exercise 2: Plane-wave occupation and spatial plateau”

In a periodic translation-invariant box, suppose

n0=n0Vn_{\mathbf0} = n_0V

and the remaining momentum distribution has a thermodynamic-limit density n~reg(k)\widetilde n_{\mathrm{reg}}(\mathbf k) whose Fourier transform vanishes at large distance. Show that

γ(r)⟶n0.\gamma(\mathbf r) \longrightarrow n_0.

How does the result change for a condensate at k0≠0\mathbf k_0\neq\mathbf0?

Solution

Separate the macroscopic mode:

γ(r)=n0V+1V∑k≠0nkeik⋅r⟶n0+∫ddk(2π)dn~reg(k)eik⋅r.\begin{aligned} \gamma(\mathbf r) &= \frac{n_{\mathbf0}}{V} + \frac{1}{V} \sum_{\mathbf k\neq\mathbf0} n_{\mathbf k} e^{i\mathbf k\cdot\mathbf r} \\ &\longrightarrow n_0 + \int \frac{d^d k}{(2\pi)^d} \widetilde n_{\mathrm{reg}}(\mathbf k) e^{i\mathbf k\cdot\mathbf r}. \end{aligned}

By the assumed regularity, the second term vanishes as ∣r∣→∞\lvert\mathbf r\rvert\to\infty. Therefore the plateau is n0n_0.

For a condensate at k0\mathbf k_0,

γ(r)⟶n0eik0⋅r.\gamma(\mathbf r) \longrightarrow n_0e^{i\mathbf k_0\cdot\mathbf r}.

Equivalently,

e−ik0⋅rγ(r)⟶n0.e^{-i\mathbf k_0\cdot\mathbf r} \gamma(\mathbf r) \longrightarrow n_0.

Exercise 3: Number conservation does not remove ODLRO

Section titled “Exercise 3: Number conservation does not remove ODLRO”

For

∣N:ϕ⟩=(aϕ†)NN!∣0⟩,\lvert N:\phi\rangle = \frac{(a_\phi^\dagger)^N}{\sqrt{N!}} \lvert0\rangle,

compute ⟨ψ(x)⟩\langle\psi(x)\rangle and γ(x,x′)\gamma(x,x'). Identify the natural occupations.

Solution

The field changes particle number by one, so orthogonality of different number sectors gives

⟨ψ(x)⟩=0.\langle\psi(x)\rangle = 0.

Decompose

ψ(x)=ϕ(x)aϕ+ψ⊥(x).\psi(x) = \phi(x)a_\phi + \psi_\perp(x).

The orthogonal modes are empty, while

⟨aϕ†aϕ⟩=N.\langle a_\phi^\dagger a_\phi \rangle = N.

Therefore

γ(x,x′)=Nϕ(x)ϕ∗(x′).\gamma(x,x') = N\phi(x)\phi^*(x').

The sole nonzero natural occupation is N0=NN_0=N, with natural orbital ϕ\phi. The state has maximal simple ODLRO despite its vanishing field expectation.

Show that every eigenvalue of a fermionic one-body density matrix lies in [0,1][0,1]. Why does this rule out fermionic one-body ODLRO but not pair ODLRO?

Solution

For a normalized orbital ff,

nf=cf†cfn_f = c_f^\dagger c_f

satisfies

nf2=nfn_f^2 = n_f

by the canonical anticommutation relations. Its expectation therefore obeys

0≤⟨nf⟩≤1.0 \leq \langle n_f\rangle \leq 1.

The largest natural occupation is the maximum of ⟨nf⟩\langle n_f\rangle over normalized ff, so every one-body eigenvalue is at most one. None can scale as NN.

A normalized pair mode is not a single fermionic orbital, and its occupation operator is not a one-particle projector. Antisymmetry permits the leading eigenvalue of the two-body pair matrix to scale as NN, so pair ODLRO remains possible.

Exercise 5: Extensive eigenvalue in the BCS pair matrix

Section titled “Exercise 5: Extensive eigenvalue in the BCS pair matrix”

Suppose

Mkk′=Fk∗Fk′+δkk′dk,M_{\mathbf k\mathbf k'} = F_{\mathbf k}^*F_{\mathbf k'} + \delta_{\mathbf k\mathbf k'}d_{\mathbf k},

where 0≤dk≤10\leq d_{\mathbf k}\leq1 and

∑k∣Fk∣2=cV\sum_{\mathbf k} \lvert F_{\mathbf k}\rvert^2 = cV

with c>0c>0. Show that the largest eigenvalue is cV+O(1)cV+O(1).

Solution

Write

M=∣F⟩⟨F∣+D,M = \lvert F\rangle\langle F\rvert + D,

where DD is diagonal and

0≤D≤I.0 \leq D \leq I.

The rank-one matrix has eigenvalues

⟨F∣F⟩=cV\langle F\vert F\rangle = cV

and zero otherwise. Weyl’s eigenvalue inequalities give

cV≤λmax⁡(M)≤cV+1.cV \leq \lambda_{\max}(M) \leq cV+1.

Hence

λmax⁡(M)=cV+O(1).\lambda_{\max}(M) = cV+O(1).

At fixed density, V∝NV\propto N, so the eigenvalue is extensive.

Exercise 6: Algebraic coherence and pseudo-condensation

Section titled “Exercise 6: Algebraic coherence and pseudo-condensation”

Let a translation-invariant center-coordinate kernel in dd dimensions obey

K(R)∼R−p,0<p<d.K(R) \sim R^{-p}, \qquad 0<p<d.

Estimate the leading eigenvalue and its ratio to N∝LdN\propto L^d. Explain why a large finite-size occupation need not imply true ODLRO.

Solution

The largest long-wavelength eigenvalue scales as

λmax⁡(L)∼∫aLdR Rd−1−p∼Ld−p.\begin{aligned} \lambda_{\max}(L) &\sim \int_a^L dR\, R^{d-1-p} \\ &\sim L^{d-p}. \end{aligned}

Therefore

λmax⁡N∼Ld−pLd=L−p⟶0.\frac{\lambda_{\max}}{N} \sim \frac{L^{d-p}}{L^d} = L^{-p} \longrightarrow 0.

The eigenvalue diverges and can be numerically large, but it is subextensive. This is algebraic coherence or pseudo-condensation rather than true ODLRO.

Exercise 7: Gauge covariance of a charged pair correlator

Section titled “Exercise 7: Gauge covariance of a charged pair correlator”

Let a compact pair field of constituent charge qq transform as

Δ(R)⟼e2iqχ(R)/ℏΔ(R),\Delta(\mathbf R) \longmapsto e^{2iq\chi(\mathbf R)/\hbar} \Delta(\mathbf R),

while

A⟼A+∇χ.\mathbf A \longmapsto \mathbf A+\boldsymbol\nabla\chi.

Find the transformation of

⟨Δ†(R)Δ(R′)⟩\langle \Delta^\dagger(\mathbf R) \Delta(\mathbf R') \rangle

and verify that the Wilson-line-dressed correlator used above is invariant.

Solution

Write the undressed correlator as

C(R,R′)=⟨Δ†(R)Δ(R′)⟩.C(\mathbf R,\mathbf R') = \left\langle \Delta^\dagger(\mathbf R) \Delta(\mathbf R') \right\rangle .

It transforms as

C(R,R′)⟼e2iq[χ(R′)−χ(R)]/ℏ×C(R,R′).\begin{aligned} C(\mathbf R,\mathbf R') \longmapsto{}& e^{2iq[\chi(\mathbf R')-\chi(\mathbf R)]/\hbar} \\ &\times C(\mathbf R,\mathbf R'). \end{aligned}

The line integral transforms according to

∫RR′A⋅dℓ⟼∫RR′A⋅dℓ+χ(R′)−χ(R).\begin{aligned} \int_{\mathbf R}^{\mathbf R'} \mathbf A\cdot d\boldsymbol\ell \longmapsto{}& \int_{\mathbf R}^{\mathbf R'} \mathbf A\cdot d\boldsymbol\ell \\ & + \chi(\mathbf R') - \chi(\mathbf R). \end{aligned}

Hence the exponential transporter acquires the inverse endpoint phase,

e−2iq[χ(R′)−χ(R)]/ℏ,e^{-2iq[\chi(\mathbf R')-\chi(\mathbf R)]/\hbar},

which cancels the phase of the pair correlator. The dressed product is gauge invariant for the stated conventions.

Consider MM orthonormal localized pair modes PRP_R with

⟨PR†PR′⟩=npδRR′,\left\langle P_R^\dagger P_{R'} \right\rangle = n_p\delta_{RR'},

where np=O(1)n_p=O(1) as M→∞M\to\infty. Find the pair-matrix eigenvalues. Does the state have pair ODLRO even though every site can have strong local pair occupancy?

Solution

The pair matrix is

M=npIM.\mathcal M = n_p I_M.

All MM eigenvalues equal np=O(1)n_p=O(1). Its trace is extensive in the number of pair locations,

Tr⁡M=Mnp,\operatorname{Tr}\mathcal M = Mn_p,

but no eigenvalue is extensive. The state can contain many localized bound pairs while lacking coherence between different centers.

Pair ODLRO would require off-diagonal coherence that concentrates weight into a collective mode, for example

⟨PR†PR′⟩⟶P\langle P_R^\dagger P_{R'} \rangle \longrightarrow \mathcal P

at large separation, producing an eigenvalue of order MM.

  • ODLRO is a basis-independent macroscopic-eigenvalue property of a reduced density matrix.
  • Bosonic condensation appears in the one-body density matrix; fermionic pair condensation appears in the two-body density matrix because Pauli exclusion bounds one-body occupations.
  • In homogeneous simple condensates, the spectral criterion becomes a one-body or pair-correlation plateau after the thermodynamic limit is taken first.
  • Fixed-number states can have full ODLRO while every number-charged one-point or anomalous average vanishes.
  • Natural orbitals and pair eigenvectors reveal the spatial, internal, and finite-momentum structure of the condensate.
  • Fragmentation means several extensive eigenvalues, not several large occupations in an arbitrary basis.
  • Algebraic coherence produces a divergent but subextensive leading eigenvalue and no true condensate fraction.
  • Pair binding, a spectral gap, stiffness, Meissner response, anomalous averages, and entanglement are distinct diagnostics.
  • Charged pair kernels are gauge covariant; gauge-invariant claims require consistent background fields or parallel transport and independent electromagnetic response.
  • Penrose and Onsager give the basis-independent one-body eigenvalue criterion for Bose condensation.
  • Yang develops the reduced-density-matrix hierarchy and the two-body criterion for superconducting pair order.
  • Coleman analyzes structural constraints and eigenvalue bounds for fermionic reduced density matrices.
  • Girardeau clarifies generalized condensation and the order of thermodynamic and separation limits.
  • Rensink exhibits the extensive two-body eigenvalue in BCS theory.
  • Leggett discusses condensate definitions, broken symmetry, and experimentally relevant Bose-gas distinctions.
  • Bose–Einstein Condensates Overview connects the one-body criterion to trapped-gas order parameters, interference, collective response, and experimental evidence.
  • BCS Theory connects fermionic pair coherence to superconducting gaps, thermodynamics, stiffness, and material diagnostics without identifying those observables with one another.
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