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Ginzburg–Landau Theory

Ginzburg–Landau theory is the static, gauge-covariant effective theory of a superconducting order parameter that may vary in space. It extends London Theory by allowing the condensate amplitude to heal, vanish at boundaries and vortex cores, and respond nonlinearly to magnetic field and current.

The theory is phenomenological in the precise sense that symmetry and locality determine the form of the free energy, while experiment or a microscopic calculation determines its coefficients. Near a continuous superconducting transition, that separation is powerful enough to predict two material lengths, magnetic critical scales, the type-I/type-II criterion, flux-carrying vortices, and characteristic temperature dependences.

This page owns the material phenomenology of the single-component local theory. Landau–Ginzburg Theory Preview owns the generic coarse-grained field, Gaussian correlation length, interfaces, fluctuations, and Ginzburg criterion. BCS Mean-Field Theory owns the microscopic paired saddle and gap equation. Full critical field theory and renormalization belong to the field-theory continuation.

Use the Superfluidity and Superconductivity gateway when the question instead concerns fixed-amplitude electrodynamics, microscopic pairing, vortex motion, weak links, proximity, or unconventional evidence.

Required background. London Theory supplies the fixed-amplitude electromagnetic limit, while Landau–Ginzburg Theory Preview supplies the coarse-grained functional, stability, correlation-length, and fluctuation language used here.

Helpful background. Order Parameters supplies normalization and symmetry discipline, while Minimal Coupling in Wave Mechanics supplies the gauge-covariant gradient construction.

We use SI units and the free-energy density convention

fpot=α∣ψ∣2+β2∣ψ∣4.f_{\mathrm{pot}} = \alpha|\psi|^2 + \frac{\beta}{2}|\psi|^4.

The symbols mean:

  • ψ(r)\psi(\mathbf r) is a coarse-grained complex superconducting order parameter;
  • q∗q^\ast is the signed charge carried by the coherent field;
  • m∗m^\ast is the mass parameter in the gradient term;
  • α\alpha and β\beta are phenomenological coefficients;
  • A\mathbf A is the vector potential and B=∇×A\mathbf B=\boldsymbol{\nabla}\times\mathbf A;
  • μ0\mu_0 is the vacuum permeability;
  • Φ0=h/∣q∗∣\Phi_0=h/|q^\ast| is the flux quantum.

For an ordinary Cooper-pair condensate,

q∗=−2e,Φ0=h2e.q^\ast=-2e, \qquad \Phi_0=\frac{h}{2e}.

We choose the convenient normalization

∣ψ∣2=ns,|\psi|^2=n_s,

so ∣ψ∣2|\psi|^2 has the dimensions of a pair density and the gradient coefficient is written with m∗m^\ast. This normalization is not universal. A rescaling

ψ⟶cψ\psi\longrightarrow c\psi

reshuffles α\alpha, β\beta, and the gradient coefficient without changing observables. A quoted GL coefficient has meaning only together with the order-parameter normalization.

Near a mean-field transition,

α(T)=α0(T−Tc),α0>0,β>0,\alpha(T) = \alpha_0(T-T_c), \qquad \alpha_0>0, \qquad \beta>0,

while β\beta and m∗m^\ast are often approximated as smooth constants. This linear form is an asymptotic expansion near TcT_c, not a global law down to zero temperature.

The magnetic thermodynamic ensemble also matters. The functional below includes the internal field energy and is convenient when fields and boundary conditions are solved together. At fixed applied field, equilibrium comparison requires the appropriate Gibbs potential and the energy of the external-field apparatus. One must distinguish:

Happl,H,B,\mathbf H_{\mathrm{appl}}, \qquad \mathbf H, \qquad \mathbf B,

and include demagnetizing fields before comparing a bulk formula with a measured magnetization.

Write

ψ(r)=∣ψ(r)∣eiθ(r).\psi(\mathbf r) = |\psi(\mathbf r)|e^{i\theta(\mathbf r)}.

Under the electromagnetic gauge transformation

A⟶A+∇χ,θ⟶θ+q∗ℏχ,\begin{aligned} \mathbf A &\longrightarrow \mathbf A+\boldsymbol{\nabla}\chi, \\ \theta &\longrightarrow \theta+\frac{q^\ast}{\hbar}\chi, \end{aligned}

the order parameter transforms as

ψ⟶eiq∗χ/ℏψ.\psi \longrightarrow e^{iq^\ast\chi/\hbar}\psi.

The phase by itself is gauge dependent. Gauge-invariant information resides in ∣ψ∣|\psi|, magnetic field, current, phase winding around a closed contour, and the covariant phase gradient

ℏ∇θ−q∗A.\hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A.

The GL order parameter is not a literal two-electron Schrödinger wavefunction. It is a coarse-grained collective field whose normalization and microscopic relation depend on the derivation. Off-Diagonal Long-Range Order supplies the number-conserving many-body coherence diagnostic.

With no field, current, or spatial variation, minimize

fpot(u)=αu+β2u2,u=∣ψ∣2.f_{\mathrm{pot}}(u) = \alpha u + \frac{\beta}{2}u^2, \qquad u=|\psi|^2.

The stationary solutions satisfy

ψ(α+β∣ψ∣2)=0.\psi \left( \alpha+\beta|\psi|^2 \right) =0.

For α>0\alpha>0, the stable minimum is

ψ∞=0.\psi_\infty=0.

For α<0\alpha<0,

∣ψ∞∣2=−αβ.|\psi_\infty|^2 = - \frac{\alpha}{\beta}.

The phase is undetermined until gradients, boundaries, or external couplings are specified. The condensation free-energy density relative to the normal state is

Δfcond=fs−fn=−α22β.\Delta f_{\mathrm{cond}} = f_s-f_n = - \frac{\alpha^2}{2\beta}.

Equating its magnitude to the magnetic energy density defines the thermodynamic critical induction BcB_c:

Bc22μ0=α22β,\frac{B_c^2}{2\mu_0} = \frac{\alpha^2}{2\beta},

so

Bc=∣α∣μ0β.B_c = |\alpha| \sqrt{\frac{\mu_0}{\beta}}.

This is a bulk thermodynamic scale. An observed entry or exit field can differ because of surface barriers, pinning, geometry, metastability, or type-II vortex physics.

Define the mechanical-momentum operator

Π=−iℏ∇−q∗A.\boldsymbol{\Pi} = - i\hbar\boldsymbol{\nabla} - q^\ast\mathbf A.

The minimal isotropic single-component functional is

FGL[ψ,A]=∫Ωd3r[α∣ψ∣2+β2∣ψ∣4+12m∗∣Πψ∣2+∣B∣22μ0].\begin{aligned} F_{\mathrm{GL}}[\psi,\mathbf A] = \int_\Omega\mathrm d^3r \bigg[ & \alpha|\psi|^2 + \frac{\beta}{2}|\psi|^4 \\ & + \frac{1}{2m^\ast} \left| \boldsymbol{\Pi}\psi \right|^2 + \frac{|\mathbf B|^2}{2\mu_0} \bigg]. \end{aligned}

Each term has a distinct role:

TermPhysical contentWhat fixes its coefficient
α∣ψ∣2+β∣ψ∣4/2\alpha\lvert\psi\rvert^2+\beta\lvert\psi\rvert^4/2local preference for normal or superconducting amplitudetemperature, pressure, composition, microscopic pairing
∣Πψ∣2/(2m∗)\lvert\boldsymbol{\Pi}\psi\rvert^2/(2m^\ast)amplitude gradients and gauge-invariant phase stiffnessband structure, interactions, disorder, normalization
B2/(2μ0)B^2/(2\mu_0)electromagnetic field energyMaxwell electrodynamics

Terms omitted from the minimal model can include anisotropic gradient tensors, several order-parameter components, couplings to strain or magnetism, higher gradients, crystal-symmetry invariants, surface energies, and nonlocal kernels.

Varying with respect to ψ∗\psi^\ast gives

12m∗Π2ψ+αψ+β∣ψ∣2ψ=0.\frac{1}{2m^\ast} \boldsymbol{\Pi}^2\psi + \alpha\psi + \beta|\psi|^2\psi =0.

This nonlinear elliptic equation determines the equilibrium order-parameter profile. It resembles a stationary Schrödinger equation, but the analogy must not be overread:

  • the eigenvalue is not an energy level;
  • the equation is nonlinear;
  • ψ\psi is a thermodynamic order parameter;
  • the coefficients depend on temperature and material;
  • the vector potential is solved self-consistently rather than prescribed in general.

Current and second Ginzburg–Landau equation

Section titled “Current and second Ginzburg–Landau equation”

The electromagnetic current follows from

js=−δFGLδA.\mathbf j_s = - \frac{\delta F_{\mathrm{GL}}}{ \delta\mathbf A }.

Explicitly,

js=q∗2m∗[ψ∗Πψ+(Πψ)∗ψ].\mathbf j_s = \frac{q^\ast}{2m^\ast} \left[ \psi^\ast\boldsymbol{\Pi}\psi + \left( \boldsymbol{\Pi}\psi \right)^\ast\psi \right].

Equivalently,

js=q∗m∗Re⁡(ψ∗Πψ).\mathbf j_s = \frac{q^\ast}{m^\ast} \operatorname{Re} \left( \psi^\ast\boldsymbol{\Pi}\psi \right).

Variation with respect to A\mathbf A supplies magnetostatic Ampère law inside the material:

∇×B=μ0(js+jext).\boldsymbol{\nabla}\times\mathbf B = \mu_0 \left( \mathbf j_s+\mathbf j_{\mathrm{ext}} \right).

In a region without an imposed bulk current density,

∇×B=μ0js.\boldsymbol{\nabla}\times\mathbf B = \mu_0\mathbf j_s.

Using ψ=∣ψ∣eiθ\psi=|\psi|e^{i\theta},

js=q∗m∗∣ψ∣2(ℏ∇θ−q∗A).\mathbf j_s = \frac{q^\ast}{m^\ast} |\psi|^2 \left( \hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A \right).

This expression makes gauge invariance and the connection to London electrodynamics manifest.

Variation of the bulk functional leaves a surface term. For an ideal superconductor–insulator boundary with no normal supercurrent and no surface pair breaking,

n^⋅Πψ=0.\hat{\mathbf n}\cdot \boldsymbol{\Pi}\psi =0.

A more general de Gennes boundary condition can be written

n^⋅Πψ=−iℏψb,\hat{\mathbf n}\cdot \boldsymbol{\Pi}\psi = - i\hbar \frac{\psi}{b},

up to the orientation convention for n^\hat{\mathbf n}. The extrapolation length bb encodes surface enhancement or suppression. A superconductor–normal-metal interface, a vacuum surface, and a strongly pair-breaking boundary are not interchangeable.

Far from boundaries and vortex cores, suppose the amplitude is nearly uniform:

∣ψ∣≃∣ψ∞∣.|\psi| \simeq |\psi_\infty|.

Then the GL current reduces to the London current with

ns=∣ψ∞∣2.n_s=|\psi_\infty|^2.

Taking a curl away from phase singularities gives

∇×js=−(q∗)2∣ψ∞∣2m∗B.\boldsymbol{\nabla}\times\mathbf j_s = - \frac{(q^\ast)^2|\psi_\infty|^2}{ m^\ast } \mathbf B.

The GL penetration depth is therefore

λ2=m∗μ0(q∗)2∣ψ∞∣2=m∗βμ0(q∗)2∣α∣.\lambda^2 = \frac{ m^\ast }{ \mu_0(q^\ast)^2|\psi_\infty|^2 } = \frac{ m^\ast\beta }{ \mu_0(q^\ast)^2|\alpha| }.

London theory is recovered by freezing the amplitude at its bulk minimum. GL theory adds the energetic cost and spatial profile of departures from that minimum.

The coefficient of spatial gradients competes with the local curvature of the potential. The standard GL coherence length is

ξ2=ℏ22m∗∣α∣.\xi^2 = \frac{ \hbar^2 }{ 2m^\ast|\alpha| }.

This ξ\xi controls several related but not identical statements:

  • decay of the linearized order parameter into a region where α>0\alpha>0;
  • the scale entering nucleation at the upper critical field;
  • the order of magnitude of a vortex-core radius;
  • spatial recovery of a suppressed superconducting amplitude.

Convention matters. Consider zero field and a real order parameter in x>0x>0 with an idealized strongly pair-breaking boundary,

ψ(0)=0,ψ(∞)=ψ∞.\psi(0)=0, \qquad \psi(\infty)=\psi_\infty.

Set

f(x)=ψ(x)ψ∞.f(x) = \frac{\psi(x)}{\psi_\infty}.

The first GL equation becomes

−ξ2d2fdx2−f+f3=0.- \xi^2 \frac{\mathrm d^2f}{\mathrm dx^2} - f + f^3 =0.

Its solution is

f(x)=tanh⁡(x2ξ).f(x) = \tanh \left( \frac{x}{ \sqrt{2}\xi } \right).

Thus the conventional parameter ξ\xi appears with 2\sqrt{2} in this nonlinear profile, and the far-tail amplitude deviation decays over ξ/2\xi/\sqrt{2}. Calling every operational healing length simply “the coherence length” without stating the definition invites factor-of-2\sqrt{2} disagreements.

Ginzburg–Landau potential, superconducting healing profiles, and the type-I/type-II criterion

The material ledger of the minimal Ginzburg–Landau theory below TcT_c. The local potential selects a nonzero amplitude. Boundaries and defects force ∣ψ∣|\psi| to heal over a scale set by ξ\xi, while magnetic induction changes over λ\lambda. Their ratio κ=λ/ξ\kappa=\lambda/\xi controls the sign of the normal–superconducting interface energy and, in the single-component local bulk theory, separates type I from type II at κ=1/2\kappa=1/\sqrt{2}.

The dimensionless ratio

κ≡λξ\kappa \equiv \frac{\lambda}{\xi}

compares magnetic screening with amplitude healing. In the normalization used here,

κ2=2(m∗)2βμ0(q∗)2ℏ2.\kappa^2 = \frac{ 2(m^\ast)^2\beta }{ \mu_0(q^\ast)^2\hbar^2 }.

The simple temperature dependences give

λ(T)∝(Tc−T)−1/2,\lambda(T) \propto (T_c-T)^{-1/2},

and

ξ(T)∝(Tc−T)−1/2,\xi(T) \propto (T_c-T)^{-1/2},

so κ\kappa approaches a constant near TcT_c within mean-field GL theory.

At a flat boundary between normal and superconducting regions at the thermodynamic critical field, the interface energy changes sign at

κc=12.\kappa_c = \frac{1}{\sqrt{2}}.

For the minimal local bulk model:

RegimeInterface energyFlux organization
κ<1/2\kappa<1/\sqrt{2}positivetype I; macroscopic normal and superconducting domains are favored
κ=1/2\kappa=1/\sqrt{2}zero in the ideal modelBogomolny point; special degeneracies occur
κ>1/2\kappa>1/\sqrt{2}negativetype II; quantized vortices can form a mixed state

The criterion is exact for the ideal single-component isotropic GL model near its regime of validity. Multicomponent condensates, nonlocal electrodynamics, strong anisotropy, finite size, and interfaces can produce richer behavior. “Type-1.5” language, for example, requires more than inserting one effective λ\lambda and one effective ξ\xi into the table.

Three field scales organize the ideal bulk problem. We report them in tesla using

Bci≡μ0HciB_{ci} \equiv \mu_0H_{ci}

for the ideal bulk geometry. In a shaped sample, internal induction, internal auxiliary field, and applied field must still be distinguished.

The condensation-energy relation gave

Bc2=μ0α2β.B_c^2 = \mu_0 \frac{\alpha^2}{\beta}.

Using λ\lambda, ξ\xi, and Φ0\Phi_0,

Bc=Φ022πλξ.B_c = \frac{ \Phi_0 }{ 2\sqrt{2}\pi\lambda\xi }.

This identity follows from the chosen single-component GL normalization. It should not be used as an exact low-temperature identity in a material far outside the GL regime.

Near the loss of superconductivity, ψ\psi is small, so the cubic term may be neglected:

12m∗Π2ψ+αψ=0.\frac{1}{2m^\ast} \boldsymbol{\Pi}^2\psi + \alpha\psi =0.

In a uniform field, the kinetic operator has Landau levels. Its lowest transverse eigenvalue is

ℏ∣q∗∣B2m∗.\frac{ \hbar|q^\ast|B }{ 2m^\ast }.

The normal state first becomes unstable when

α+ℏ∣q∗∣Bc22m∗=0.\alpha + \frac{ \hbar|q^\ast|B_{c2} }{ 2m^\ast } =0.

Therefore

Bc2=2m∗∣α∣ℏ∣q∗∣=Φ02πξ2.B_{c2} = \frac{ 2m^\ast|\alpha| }{ \hbar|q^\ast| } = \frac{ \Phi_0 }{ 2\pi\xi^2 }.

Combining results,

Bc2Bc=2κ.\frac{B_{c2}}{B_c} = \sqrt{2}\kappa.

The derivation is a direct material application of Landau Levels, but here the eigenfunction is the incipient order-parameter profile rather than a single-particle orbital.

For a strongly type-II bulk superconductor,

κ≫1,\kappa\gg1,

the lower critical induction has the asymptotic form

Bc1≃Φ04πλ2(ln⁡κ+ccore),B_{c1} \simeq \frac{ \Phi_0 }{ 4\pi\lambda^2 } \left( \ln\kappa+c_{\mathrm{core}} \right),

where the order-one constant ccorec_{\mathrm{core}} depends on the core treatment and approximation. Below Bc1B_{c1}, the equilibrium bulk state is Meissner-like. Between Bc1B_{c1} and Bc2B_{c2}, flux enters as vortices in the ideal type-II picture.

These are equilibrium bulk scales. First penetration, irreversible magnetization, and resistive onset can occur at different fields because edge barriers, defects, pinning, vortex motion, sample shape, and the measurement criterion all matter.

A vortex is possible because the phase winds while the amplitude vanishes at its core. Around a closed contour,

∮∇θ⋅dℓ=2πN,N∈Z.\oint \boldsymbol{\nabla}\theta\cdot \mathrm d\boldsymbol{\ell} = 2\pi N, \qquad N\in\mathbb Z.

For an isolated straight vortex along z^\hat{\mathbf z}, a cylindrically symmetric ansatz is

ψ(r,φ)=ψ∞fN(r)eiNφ.\psi(r,\varphi) = \psi_\infty f_N(r)e^{iN\varphi}.

Regularity requires

fN(r)∝r∣N∣f_N(r) \propto r^{|N|}

near the origin, while

fN(r)⟶1f_N(r)\longrightarrow1

far from the core. The core suppresses condensation energy over a scale of order ξ\xi; circulating current and magnetic field extend over a scale of order λ\lambda.

Far from the core, where the current is negligible on a large contour, the gauge-invariant phase gradient gives

0=2πℏN−q∗Φ.0 = 2\pi\hbar N - q^\ast\Phi.

Therefore the signed flux is

Φ=hq∗N=sgn⁡(q∗)NΦ0.\Phi = \frac{h}{q^\ast}N = \operatorname{sgn}(q^\ast)N\Phi_0.

For an ordinary Cooper-pair field with q∗=−2eq^\ast=-2e, this convention gives Φ=−NΦ0\Phi=-N\Phi_0; the flux magnitude is ∣N∣Φ0|N|\Phi_0, and reversing the winding reverses the flux orientation.

The London page states the more precise fluxoid relation. GL theory supplies the missing core where ψ=0\psi=0, so a nonzero winding cannot be continuously unwound without crossing a configuration of vanishing amplitude or changing the boundary conditions.

For κ≫1\kappa\gg1, the energy per unit length of a singly quantized vortex has the leading form

εv≃Φ024πμ0λ2ln⁡κ+εcore.\varepsilon_v \simeq \frac{ \Phi_0^2 }{ 4\pi\mu_0\lambda^2 } \ln\kappa + \varepsilon_{\mathrm{core}}.

The logarithm comes from currents between the core and magnetic screening scales. The core contribution is not determined by a London calculation.

In the minimal type-II theory, well-separated singly quantized vortices repel and multiply quantized vortices generally split. Near Bc2B_{c2}, the linearized GL equation produces a highly degenerate lowest-Landau-level space. The quartic term selects a periodic Abrikosov lattice; in the ideal isotropic model, the triangular lattice minimizes

βA≡⟨∣ψ∣4⟩⟨∣ψ∣2⟩2≃1.1596.\beta_A \equiv \frac{ \langle|\psi|^4\rangle }{ \langle|\psi|^2\rangle^2 } \simeq 1.1596.

Real vortex matter is shaped by crystal anisotropy, nonlocality, disorder, pinning, thermal fluctuations, finite thickness, and drive. A vortex lattice seen in one probe does not imply a perfectly ordered equilibrium lattice throughout the sample.

GL theory also captures amplitude suppression by superflow. Consider a region with uniform gauge-invariant condensate momentum

ps=ℏ∇θ−q∗A.\mathbf p_s = \hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A.

The first GL equation gives

∣ψ∣2=∣α∣−ps2/(2m∗)β|\psi|^2 = \frac{ |\alpha|-p_s^2/(2m^\ast) }{ \beta }

while the current magnitude is

js=∣q∗∣m∗∣ψ∣2ps.j_s = \frac{|q^\ast|}{m^\ast} |\psi|^2p_s.

Maximizing with respect to psp_s gives

ps2=2m∗∣α∣3.p_s^2 = \frac{ 2m^\ast|\alpha| }{ 3 }.

The ideal GL depairing current density is

jd=2233Bcμ0λ.j_d = \frac{2\sqrt{2}}{3\sqrt{3}} \frac{ B_c }{ \mu_0\lambda }.

Because

Bc∝(Tc−T),λ−1∝(Tc−T)1/2,B_c\propto(T_c-T), \qquad \lambda^{-1}\propto(T_c-T)^{1/2},

the mean-field scaling is

jd∝(Tc−T)3/2.j_d \propto (T_c-T)^{3/2}.

Measured critical current is often much smaller. Vortex entry, phase slips, constrictions, weak links, heating, defects, and current crowding can trigger dissipation before the uniform depairing limit.

Under the elementary assumptions

α=α0(T−Tc),β≈constant,m∗≈constant,\alpha=\alpha_0(T-T_c), \qquad \beta\approx\text{constant}, \qquad m^\ast\approx\text{constant},

mean-field GL theory predicts:

QuantityLeading behavior below TcT_c
∣ψ∞∣\lvert\psi_\infty\rvert(Tc−T)1/2(T_c-T)^{1/2}
∣ψ∞∣2\lvert\psi_\infty\rvert^2Tc−TT_c-T
condensation energy density(Tc−T)2(T_c-T)^2
BcB_cTc−TT_c-T
ξ\xi(Tc−T)−1/2(T_c-T)^{-1/2}
λ\lambda(Tc−T)−1/2(T_c-T)^{-1/2}
Bc2B_{c2}Tc−TT_c-T
jdj_d(Tc−T)3/2(T_c-T)^{3/2}
κ\kappaconstant to leading order

These are mean-field asymptotics. A sufficiently narrow critical region is governed by fluctuations rather than the saddle point. In two dimensions, phase fluctuations and vortex unbinding can be especially important. A fit over a wide temperature interval should not be labeled a GL prediction merely because it uses the same powers.

Ginzburg and Landau introduced the theory phenomenologically. Gor’kov later derived its form from weak-coupling BCS theory near TcT_c and showed that the covariant charge is twice the electronic charge. That derivation establishes an important logical relation:

microscopic pairing theory⟹GL coefficients in a controlled limit.\text{microscopic pairing theory} \quad\Longrightarrow\quad \text{GL coefficients in a controlled limit}.

It does not make the phenomenological coefficients universal. Band anisotropy, impurity scattering, multiple Fermi surfaces, strong coupling, and unconventional pairing change the coefficients and may require additional fields or invariants.

The order parameter transforms under a local gauge redundancy, but a redundancy is not an observable global symmetry that literally breaks. Physical statements should be phrased through gauge-invariant currents, fluxes, response functions, phase differences, and correlation functions. From Phase Symmetry to Gauge Theory owns that distinction.

This page stops at static material phenomenology. Landau–Ginzburg Theory Preview develops the regulated coarse-grained field, Gaussian fluctuations, correlation functions, interfaces, and Ginzburg criterion. Renormalization Group Preview explains scale dependence and the failure of mean-field exponents in a critical region.

Continue through the publication-aware QFT.org crosswalk and the live QFT.org hub when functional measures, gauge-field fluctuations, renormalized operators, universality classes, or relativistic Abelian Higgs theory become the main subject. Similar-looking functionals do not imply identical ensembles, dynamics, observables, or universality classes.

Replace the scalar mass by a positive tensor:

fgrad=12(Πiψ)∗(M−1)ij(Πjψ).f_{\mathrm{grad}} = \frac12 \left( \Pi_i\psi \right)^\ast \left( \mathsf M^{-1} \right)_{ij} \left( \Pi_j\psi \right).

Coherence lengths, penetration depths, Bc2B_{c2}, and vortex structures then depend on orientation. A single scalar κ\kappa may be inadequate.

Several complex fields can support:

  • distinct amplitudes and healing lengths;
  • interband Josephson-like couplings;
  • relative-phase modes;
  • domain walls and fractionalized defects under special conditions;
  • competing or coexisting orders;
  • nonmonotonic intervortex forces.

The allowed terms follow from crystal symmetry, time-reversal properties, gauge covariance, and the representation carried by the order parameter. One cannot obtain an unconventional GL theory by changing only the value of m∗m^\ast.

The equilibrium field configuration obtained by minimizing FGLF_{\mathrm{GL}} is a saddle-point or mean-field description. Thermal fluctuations require the statistical weight

Z=∫Dψ DA exp⁡(−FGLkBT),Z = \int \mathcal D\psi\, \mathcal D\mathbf A\, \exp \left( - \frac{F_{\mathrm{GL}}}{ k_{\mathrm B}T } \right),

with a declared ultraviolet cutoff, gauge treatment, boundary conditions, and measure. Integrating over A\mathbf A is conceptually different from solving for a classical field profile.

Dynamics are not fixed by the static functional

Section titled “Dynamics are not fixed by the static functional”

The static GL functional does not uniquely determine time evolution. A time-dependent GL equation requires kinetic coefficients, conservation laws, noise, electromagnetic environment, and a regime of validity. Reactive condensate dynamics, relaxational critical dynamics, vortex flow, and microscopic nonequilibrium quasiparticles are different problems.

The elementary expansion can fail when:

  • TT is far below TcT_c;
  • variations occur on microscopic pair or lattice scales;
  • nonlocal response matters;
  • the gap has several components or nodes;
  • strong pair breaking changes boundary physics;
  • quantum fluctuations or nonequilibrium distributions dominate;
  • the transition is first order or strongly inhomogeneous.

GL theory can remain a useful fitted effective model outside its strict asymptotic derivation, but then its accuracy must be established against observables rather than assumed.

  1. Declare the ensemble and geometry. State applied-field orientation, sample dimensions, demagnetizing correction, and whether the observable is reversible.
  2. Identify the transition. Establish that the relevant anomaly is superconducting and determine whether a continuous near-TcT_c expansion is justified.
  3. Measure independent scales. Infer λ\lambda, ξ\xi, BcB_c, and Bc2B_{c2} from observables with explicit model assumptions rather than solving every quantity from one fit.
  4. Distinguish field criteria. Thermodynamic, magnetic-onset, torque, heat-capacity, and resistive definitions of a critical field need not coincide.
  5. Check vortex contamination. Pinning and surface barriers can make first penetration differ from equilibrium Bc1B_{c1}.
  6. Track orientation and anisotropy. Report tensor directions, not just one nominal GL parameter.
  7. Restrict temperature extrapolation. A near-TcT_c slope does not automatically determine a zero-temperature coherence length or critical field.
  8. Test single-component locality. Multiband curvature, multiple gaps, nonlocal response, and competing order can invalidate the minimal model.
  9. Propagate sample uncertainty. Surface damage, inclusions, thickness variation, current crowding, and heating can dominate inferred critical currents.
  10. Use orthogonal probes. Combine thermodynamics, penetration depth, vortex imaging or scattering, spectroscopy, and transport.
MistakeWhy it failsBetter practice
Calling ψ\psi a literal Cooper-pair wavefunctionIt is a normalized coarse-grained order parameterState its normalization and microscopic relation
Treating the phase as directly observableθ\theta is gauge dependentUse covariant gradients, closed-loop winding, or phase differences
Dropping the magnetic field energyA\mathbf A must be determined self-consistentlyVary both ψ\psi and A\mathbf A with boundary conditions
Using ∣ψ∣2=−α/β\lvert\psi\rvert^2=-\alpha/\beta inside a vortex coreGradient and magnetic terms are then essentialSolve the spatial GL equations
Calling every healing length ξ\xiOperational definitions can differ by factors such as 2\sqrt{2}State the defining equation or profile
Classifying every material by one κ\kappaAnisotropic or multicomponent systems can have several scalesReport the model and tensor or component structure
Equating first flux entry with Bc1B_{c1}Barriers and demagnetization shift entrySeparate equilibrium and irreversible criteria
Using Bc2=Φ0/(2πξ2)B_{c2}=\Phi_0/(2\pi\xi^2) at all temperaturesIt is a GL near-transition relation unless independently justifiedState the fit window and extrapolation
Calling a resistive onset the thermodynamic transitionVortex motion and inhomogeneity broaden transportCompare magnetization and thermodynamics
Assuming static GL implies a unique TDGL equationDynamics require extra constitutive informationSpecify kinetics, noise, and conservation laws
Extending mean-field exponents into the critical regionFluctuations renormalize scalingEstimate the Ginzburg region and test scaling
Treating gauge redundancy as broken global symmetryGauge-related fields describe the same physical statePhrase claims in gauge-invariant observables

1. Uniform minimum and condensation energy

Section titled “1. Uniform minimum and condensation energy”

For

f(u)=αu+β2u2,u=∣ψ∣2,f(u) = \alpha u + \frac{\beta}{2}u^2, \qquad u=|\psi|^2,

find the stable uniform state for α>0\alpha>0 and α<0\alpha<0, assuming β>0\beta>0. Compute the condensation energy below TcT_c.

Solution

Differentiate with respect to the nonnegative variable uu:

dfdu=α+βu.\frac{\mathrm df}{\mathrm du} = \alpha+\beta u.

For α>0\alpha>0, the formal stationary point is negative and inaccessible, so the minimum is

u=0.u=0.

For α<0\alpha<0,

u∞=−αβ>0.u_\infty = - \frac{\alpha}{\beta}>0.

Substitution gives

f(u∞)=α(−αβ)+β2(α2β2)=−α22β.\begin{aligned} f(u_\infty) &= \alpha \left( - \frac{\alpha}{\beta} \right) + \frac{\beta}{2} \left( \frac{\alpha^2}{\beta^2} \right) \\ &= - \frac{\alpha^2}{2\beta}. \end{aligned}

Taking the normal reference as zero, the condensation free-energy density is −α2/(2β)-\alpha^2/(2\beta).

Vary the functional with respect to ψ∗\psi^\ast and recover the first GL equation. Assume boundary terms vanish.

Solution

The local terms vary as

δψ∗(α∣ψ∣2+β2∣ψ∣4)=(αψ+β∣ψ∣2ψ)δψ∗.\delta_{\psi^\ast} \left( \alpha|\psi|^2 + \frac{\beta}{2}|\psi|^4 \right) = \left( \alpha\psi + \beta|\psi|^2\psi \right) \delta\psi^\ast.

For the gradient term, covariant integration by parts gives

δψ∗∫∣Πψ∣22m∗d3r=∫δψ∗Π2ψ2m∗d3r.\delta_{\psi^\ast} \int \frac{ |\boldsymbol{\Pi}\psi|^2 }{ 2m^\ast } \mathrm d^3r = \int \delta\psi^\ast \frac{ \boldsymbol{\Pi}^2\psi }{ 2m^\ast } \mathrm d^3r.

Because δψ∗\delta\psi^\ast is arbitrary,

Π22m∗ψ+αψ+β∣ψ∣2ψ=0.\frac{ \boldsymbol{\Pi}^2 }{ 2m^\ast } \psi + \alpha\psi + \beta|\psi|^2\psi =0.

Set ψ=ψ∞eiθ\psi=\psi_\infty e^{i\theta} with constant amplitude. Derive the supercurrent and penetration depth.

Solution

Acting with the covariant momentum,

Πψ=eiθψ∞(ℏ∇θ−q∗A).\boldsymbol{\Pi}\psi = e^{i\theta}\psi_\infty \left( \hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A \right).

The current is

js=q∗m∗∣ψ∞∣2(ℏ∇θ−q∗A).\mathbf j_s = \frac{q^\ast}{m^\ast} |\psi_\infty|^2 \left( \hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A \right).

Away from singular phase winding,

∇×js=−(q∗)2∣ψ∞∣2m∗B.\boldsymbol{\nabla}\times\mathbf j_s = - \frac{ (q^\ast)^2|\psi_\infty|^2 }{ m^\ast } \mathbf B.

Comparing with the second London equation gives

λ2=m∗μ0(q∗)2∣ψ∞∣2.\lambda^2 = \frac{ m^\ast }{ \mu_0(q^\ast)^2|\psi_\infty|^2 }.

Using ∣ψ∞∣2=∣α∣/β|\psi_\infty|^2=|\alpha|/\beta gives the GL expression in the text.

Show that

f(x)=tanh⁡(x2ξ)f(x) = \tanh \left( \frac{x}{ \sqrt{2}\xi } \right)

solves

−ξ2f′′−f+f3=0.- \xi^2f'' - f + f^3 =0.
Solution

Let

y=x2ξ.y = \frac{x}{ \sqrt{2}\xi }.

Then

f=tanh⁡y,dfdy=sech⁡2y,f=\tanh y, \qquad \frac{\mathrm df}{\mathrm dy} = \operatorname{sech}^2y,

and

d2fdy2=−2tanh⁡y sech⁡2y.\frac{\mathrm d^2f}{\mathrm dy^2} = - 2\tanh y\, \operatorname{sech}^2y.

Because

ξ2f′′=12d2fdy2=−tanh⁡y sech⁡2y,\xi^2f'' = \frac12 \frac{\mathrm d^2f}{\mathrm dy^2} = - \tanh y\, \operatorname{sech}^2y,

the differential equation becomes

tanh⁡y sech⁡2y−tanh⁡y+tanh⁡3y.\tanh y\, \operatorname{sech}^2y - \tanh y + \tanh^3y.

Using

sech⁡2y=1−tanh⁡2y,\operatorname{sech}^2y = 1-\tanh^2y,

the expression vanishes. The boundary values are f(0)=0f(0)=0 and f(∞)=1f(\infty)=1.

5. Upper critical field from the lowest Landau level

Section titled “5. Upper critical field from the lowest Landau level”

Use the lowest eigenvalue of Π2/(2m∗)\boldsymbol{\Pi}^2/(2m^\ast) in a uniform magnetic field to derive Bc2B_{c2}.

Solution

Near Bc2B_{c2}, the cubic term is negligible:

[Π22m∗+α]ψ=0.\left[ \frac{ \boldsymbol{\Pi}^2 }{ 2m^\ast } + \alpha \right] \psi =0.

The lowest transverse Landau energy is

E0=ℏ∣q∗∣B2m∗.E_0 = \frac{ \hbar|q^\ast|B }{ 2m^\ast }.

A nonzero solution first appears when

E0+α=0.E_0+\alpha=0.

Since α<0\alpha<0 below TcT_c,

Bc2=2m∗∣α∣ℏ∣q∗∣.B_{c2} = \frac{ 2m^\ast|\alpha| }{ \hbar|q^\ast| }.

With

ξ2=ℏ22m∗∣α∣,Φ0=2πℏ∣q∗∣,\xi^2 = \frac{ \hbar^2 }{ 2m^\ast|\alpha| }, \qquad \Phi_0 = \frac{ 2\pi\hbar }{ |q^\ast| },

this becomes

Bc2=Φ02πξ2.B_{c2} = \frac{ \Phi_0 }{ 2\pi\xi^2 }.

Show that

Bc2Bc=2κ.\frac{B_{c2}}{B_c} = \sqrt{2}\kappa.

What does this imply at κ=1/2\kappa=1/\sqrt{2}?

Solution

Use

Bc2=Φ02πξ2B_{c2} = \frac{\Phi_0}{2\pi\xi^2}

and

Bc=Φ022πλξ.B_c = \frac{ \Phi_0 }{ 2\sqrt{2}\pi\lambda\xi }.

Their ratio is

Bc2Bc=Φ0/(2πξ2)Φ0/(22πλξ)=2λξ=2κ.\frac{B_{c2}}{B_c} = \frac{ \Phi_0/(2\pi\xi^2) }{ \Phi_0/(2\sqrt{2}\pi\lambda\xi) } = \sqrt{2} \frac{\lambda}{\xi} = \sqrt{2}\kappa.

At κ=1/2\kappa=1/\sqrt{2},

Bc2=Bc.B_{c2}=B_c.

This coincides with the sign change of the normal–superconducting interface energy in the ideal model.

For a contour far from a vortex core, show that one unit of phase winding carries flux h/∣q∗∣h/|q^\ast| when the contour current is negligible.

Solution

Negligible current implies

ℏ∇θ−q∗A≃0.\hbar\boldsymbol{\nabla}\theta - q^\ast\mathbf A \simeq0.

Integrate around the contour:

ℏ∮∇θ⋅dℓ−q∗∮A⋅dℓ=0.\hbar \oint \boldsymbol{\nabla}\theta\cdot \mathrm d\boldsymbol{\ell} - q^\ast \oint \mathbf A\cdot \mathrm d\boldsymbol{\ell} =0.

For winding N=1N=1,

∮∇θ⋅dℓ=2π,\oint \boldsymbol{\nabla}\theta\cdot \mathrm d\boldsymbol{\ell} = 2\pi,

and the second integral is the magnetic flux Φ\Phi. Thus

q∗Φ=2πℏ=h.q^\ast\Phi = 2\pi\hbar =h.

The orientation carries the sign, while the magnitude is

∣Φ∣=h∣q∗∣=Φ0.|\Phi| = \frac{h}{|q^\ast|} = \Phi_0.

Use the GL temperature scalings to determine the leading behavior of jdj_d near TcT_c.

Solution

The ideal depairing current is

jd=2233Bcμ0λ.j_d = \frac{2\sqrt{2}}{3\sqrt{3}} \frac{ B_c }{ \mu_0\lambda }.

Near TcT_c,

Bc∝Tc−T,B_c \propto T_c-T,

and

λ−1∝(Tc−T)1/2.\lambda^{-1} \propto (T_c-T)^{1/2}.

Therefore

jd∝(Tc−T)3/2.j_d \propto (T_c-T)^{3/2}.

This is the uniform mean-field depairing scale, not necessarily the transport critical current of a finite or disordered sample.

  • Unconventional Superconductivity applies crystalline symmetry to multicomponent zero-momentum pairing representations and evidence for broken time reversal or nematicity; this page retains the spatial free-energy functional and its validity limits.
  • London Theory owns local fixed-amplitude electrodynamics, penetration-depth geometry, fluxoid quantization, and nonlocality limits.
  • Vortex Matter, Pinning, and Flux Flow takes the static core and Abrikosov solution developed here into collective elasticity, pinning, creep, melting or glass qualifications, and driven transport.
  • Order Parameters owns source selection, thermodynamic limits, and the distinction between diagnostic fields and microscopic observables.
  • Competing Orders extends local free-energy reasoning to coupled superconducting, magnetic, density-wave, and nematic orders, with coexistence and phase-topology tests.
  • Pair-Density Waves and Exotic Orders extends superconducting order to finite momentum, composite charge-4e fields, and half-vortex–dislocation defects.
  • Landau–Ginzburg Theory Preview owns the generic spatial functional, Gaussian response, interfaces, fluctuations, and Ginzburg criterion.
  • BCS Theory owns the microscopic superconducting scales, observables, and weak-coupling limits that reduce to GL phenomenology near TcT_c.
  • Superconducting Proximity Effect owns spatial anomalous propagation, inverse proximity, and Eilenberger–Usadel reductions outside the narrow near-TcT_c local window in which this page’s boundary conditions apply.
  • Moiré Superconductivity uses stiffness, vortex, critical-field, and BKT observables to test phase coherence in two-dimensional tunable condensates.
  • Josephson Effect owns weak-link phase coupling, junction energy, interference, driven locking, and environmental phase dynamics.
  • BCS Mean-Field Theory owns the microscopic paired saddle, gap equation, and quasiparticle spectrum from which GL coefficients can be derived near TcT_c.
  • Off-Diagonal Long-Range Order distinguishes pair coherence from stiffness, spectral gaps, and electromagnetic response.
  • Minimal Coupling in Wave Mechanics supplies the gauge-covariant momentum operator.
  • Landau Levels supply the eigenvalue structure used in the Bc2B_{c2} derivation.
  • From Phase Symmetry to Gauge Theory explains global phase symmetry, local gauge covariance, and gauge redundancy.
  • Susceptibilities owns response kernels, longitudinal and transverse limits, and internal-field corrections.
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