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Weyl and Dirac Semimetals

A Weyl semimetal is a three-dimensional crystal whose bulk bands contain isolated, generically twofold crossings with nonzero Berry-flux charge. A Dirac semimetal contains fourfold crossings that can be viewed locally as opposite-chirality Weyl nodes superposed and stabilized by additional symmetry. Weyl nodes are momentum-space sources or sinks of Berry curvature; surface Fermi arcs and chiral magnetic-field Landau levels are consequences of that charge.

These are gapless phases. Their topology is not an invariant of a completely filled set of bands over the entire Brillouin zone, as in an insulator. Instead, it is attached to a band crossing or to a gapped two-dimensional momentum slice that avoids the crossing. The node is stable because a small perturbation can move it but cannot remove its quantized charge except by bringing it together with nodes whose total charge cancels.

The words Weyl and Dirac describe low-energy quasiparticle Hamiltonians. They do not claim that the crystal is Lorentz invariant or that its Bloch states are elementary relativistic particles. The effective spinor can combine orbitals, sublattices, Kramers partners, or physical spin; velocities are anisotropic; the spectrum has a finite bandwidth; and lattice regularization requires additional nodes.

This page owns crystalline Weyl charge, symmetry-stabilized three-dimensional Dirac nodes, Fermi arcs, chiral Landau levels, anomaly transport, and the experimental evidence ledger. Berry Curvature owns the general geometric definition; Chern Numbers in Band Theory owns occupied-projector Chern invariants and numerical methods; From SU(2) Spinors to Lorentz Spinors owns the relativistic representation-theory bridge; and Hall Effect owns the wider transport taxonomy.

Required background. Band Theory Overview supplies the crystal-band setting, Berry Curvature supplies the enclosing-surface flux, and Chern Numbers in Band Theory supplies the gapped-slice invariant.

Helpful background. Fermi Surface supplies the node, pocket, and chemical-potential geometry, while Symmetry Classification Preview supplies the constraints that distinguish Weyl from Dirac crossings.

Near an isolated crossing of two nondegenerate bands at crystal momentum kW\mathbf k_W, any smooth 2×22\times2 Hermitian Hamiltonian can be expanded as

H(kW+q)=εW+ℏw⋅q I+ℏ∑i,j=13vijqjσi+O(q2).H(\mathbf k_W+\mathbf q) = \varepsilon_W + \hbar\mathbf w\cdot\mathbf q\,I + \hbar \sum_{i,j=1}^{3} v_{ij}q_j\sigma_i + O(q^2).

The identity term tilts the spectrum, while the Pauli-vector term opens a splitting away from the crossing. If the real velocity matrix vv is nonsingular, the eigenvalues are

E±(q)=εW+ℏw⋅q±ℏqTvTv q+O(q2).E_\pm(\mathbf q) = \varepsilon_W + \hbar\mathbf w\cdot\mathbf q \pm \hbar \sqrt{ \mathbf q^T v^T v\,\mathbf q } + O(q^2).

Three independent Pauli coefficients must vanish to produce a degeneracy. In three momentum dimensions, the three components of q\mathbf q can satisfy those three conditions at isolated points without fine tuning. This codimension argument is why a two-band Weyl point is stable in three dimensions.

The same crossing in two dimensions would normally require tuning an extra parameter or imposing a symmetry. A fourfold three-dimensional Dirac point is also not generic: more matrices can gap or split it, so a crystalline or antiunitary symmetry must forbid the dangerous terms.

For every direction n^\hat{\mathbf n}, compare the tilt speed with the cone speed:

wn^=w⋅n^,vn^=n^TvTvn^.w_{\hat{\mathbf n}} = \mathbf w\cdot\hat{\mathbf n}, \qquad v_{\hat{\mathbf n}} = \sqrt{ \hat{\mathbf n}^{T}v^Tv\hat{\mathbf n} }.

A type-I node satisfies

∣wn^∣<vn^\lvert w_{\hat{\mathbf n}}\rvert < v_{\hat{\mathbf n}}

for every direction. At the node energy, its ideal Fermi surface shrinks to a point. A type-II node has at least one direction for which

∣wn^∣>vn^,\lvert w_{\hat{\mathbf n}}\rvert > v_{\hat{\mathbf n}},

so the crossing occurs where electron and hole pockets touch. The tilt changes the Fermi-surface geometry and magnetic response but not the node’s quantized Berry charge as long as the two-band crossing remains isolated.

For one untilted anisotropic node with principal velocities vx,vy,vzv_x,v_y,v_z, the positive-energy density of states per volume is

ρ(E)=E22π2ℏ3∣vxvyvz∣,E>0.\rho(E) = \frac{E^2} {2\pi^2\hbar^3 \lvert v_xv_yv_z\rvert}, \qquad E>0.

The E2E^2 law follows from three-dimensional phase space and linear dispersion. It implies vanishing carrier density at an ideal type-I node when the chemical potential is tuned exactly to εW\varepsilon_W. Real materials usually have:

  • a chemical potential displaced from the nodes;
  • several symmetry-related nodes at different energies;
  • additional trivial electron or hole pockets;
  • disorder broadening and interactions;
  • nonlinear dispersion outside a limited momentum window.

Consequently, observing an approximately quadratic low-energy density of states is compatible with a Weyl cone but does not determine its topological charge.

For a nondegenerate band nn, define Berry curvature using the convention

Ωn(k)=∇k×An(k),An=i⟨unk∣∇kunk⟩.\boldsymbol\Omega_n(\mathbf k) = \nabla_{\mathbf k} \times \mathbf A_n(\mathbf k), \qquad \mathbf A_n = i \langle u_{n\mathbf k} | \nabla_{\mathbf k} u_{n\mathbf k} \rangle.

Take a small closed surface SWS_W enclosing one Weyl point and no other degeneracy. The Chern number of the lower band on that surface is

CW=12π∮SWΩ−(k)⋅dS∈Z.C_W = \frac{1}{2\pi} \oint_{S_W} \boldsymbol\Omega_-(\mathbf k) \cdot d\mathbf S \in \mathbb Z.

For a simple linear node, ∣CW∣=1\lvert C_W\rvert=1. Multiple-Weyl nodes with ∣CW∣>1\lvert C_W\rvert>1 can occur when crystal rotation symmetry forces higher-order dispersion in transverse directions.

For the untilted linear model above, an orientation convention gives

CW=−sgn⁡det⁡v.C_W = -\operatorname{sgn}\det v.

Some literature calls sgn⁡det⁡v\operatorname{sgn}\det v the chirality, while other literature calls the occupied-band Chern charge itself the chirality. Here the node charge is CWC_W; when a right- or left-handed label is used, its sign convention will be stated. Observable statements depend on relative signs and total flux, not on the naming convention.

In isotropic coordinates the lower-band curvature has the monopole form

Ω−(q)=CW2qq3.\boldsymbol\Omega_-(\mathbf q) = \frac{C_W}{2} \frac{\mathbf q}{q^3}.

Its flux is

∮Ω−⋅dS=2πCW.\oint \boldsymbol\Omega_- \cdot d\mathbf S = 2\pi C_W.

The singularity belongs to momentum-space band geometry. It is not a magnetic monopole in real space and does not violate ∇⋅B=0\nabla\cdot\mathbf B=0 for the electromagnetic field.

Let SWS_W remain gapped between the two bands while the Hamiltonian changes smoothly. Its integer CWC_W cannot vary continuously. A weak perturbation can:

  • shift the node in momentum and energy;
  • tilt or anisotropically reshape the cone;
  • change the surrounding Fermi pocket;
  • mix the eigenvectors smoothly.

It cannot gap an isolated unit-charge node by itself. Removal requires one of the following:

  • collision and annihilation with nodes whose total charge is −CW-C_W;
  • loss of translation structure so severe that the momentum-space description must be replaced;
  • transfer of charge through another degeneracy crossing the enclosing surface;
  • interaction-driven physics outside the quasiparticle-band description.

The Brillouin zone is a compact three-torus with no boundary. Applying the divergence theorem away from all degeneracies gives

∑aCW,a=0.\sum_a C_{W,a} = 0.

This is the band-geometric form of fermion doubling. A strictly three-dimensional lattice cannot contain one unpaired Weyl node. Surface states do not evade the rule; they encode how bulk nodes of opposite net charge are connected.

Symmetry further constrains the multiplicity:

  • With inversion symmetry but broken time reversal, a node at k\mathbf k is paired with one at −k-\mathbf k of opposite charge. The minimal number is two.
  • With time reversal but broken inversion, a node at k\mathbf k is paired with one at −k-\mathbf k of the same charge. Another same-charge pair of opposite total charge is required, so the minimal number is four.
  • With both inversion and spinful time reversal, bands are Kramers degenerate at every momentum under their product. An isolated nondegenerate Weyl node is forbidden unless another symmetry is broken.

These statements assume ordinary symmorphic momentum mapping and isolated simple nodes. Nonsymmorphic symmetries and nodes pinned to special momenta can enlarge the minimal multiplets.

Weyl cone Berry flux, surface Fermi arc, and chiral Landau levels

A Weyl point is an isolated linear crossing with quantized Berry flux 2πCW2\pi C_W. On a surface, the projections of nodes with opposite net charge are joined by a Fermi arc, understood as the family of edge modes of two-dimensional Chern slices. A magnetic field produces oppositely propagating zeroth Landau levels; parallel electric and magnetic fields pump carriers between the two chiral sectors while conserving total charge.

Suppose two simple Weyl nodes lie at different values of kzk_z. For each fixed kzk_z that avoids a node, the remaining (kx,ky)(k_x,k_y) subsystem is a gapped two-dimensional band structure with Chern number

C(kz)=12π∑n∈occ∫BZ2DΩn,xy(kx,ky;kz) dkx dky.C(k_z) = \frac{1}{2\pi} \sum_{n\in\mathrm{occ}} \int_{\mathrm{BZ}_{2D}} \Omega_{n,xy} (k_x,k_y;k_z) \,dk_x\,dk_y.

As kzk_z passes through a Weyl node, the slice Chern number jumps by that node’s charge:

C(kz+)−C(kz−)=CW.C(k_z^+)-C(k_z^-) = C_W.

Between a pair of opposite-charge nodes, the slices can therefore be Chern insulators. At a physical surface, each nontrivial slice contributes a chiral boundary state. At a fixed surface energy, the collection of these states over the interval of kzk_z forms an open contour: a Fermi arc.

This construction is the cleanest explanation of bulk–boundary correspondence in a Weyl semimetal. The arc must terminate where the surface state merges into the projected bulk continuum. Its endpoints are the surface projections of bulk nodes, counted with projected net charge.

The exact shape of a Fermi arc is not universal. Surface potentials can bend it, reconnect arcs among several projected nodes, or mix it with trivial surface bands. Topology constrains:

  • the net number of chiral surface crossings along a closed momentum-space loop;
  • the change of that count when the loop encloses projected Weyl charge;
  • termination in the projected bulk continuum;
  • the impossibility of realizing an isolated open Fermi contour in a strictly two-dimensional band structure.

If opposite-charge nodes project to the same surface momentum, their net projected charge is zero and an arc need not be visible on that face. If the chemical potential is far from the node energy, surface arcs can join bulk electron and hole pockets and appear as parts of closed contours. Calling every surface feature that looks open a Fermi arc is therefore unsafe.

Angle-Resolved Photoemission Spectroscopy can distinguish surface-localized states from bulk states by varying photon energy and thus the sampled out-of-plane momentum, subject to final-state and escape-depth limits. A strong arc diagnosis combines:

  1. bulk crossings at the predicted three-dimensional momenta;
  2. a validated crystal structure and chemical potential;
  3. surface contours with negligible bulk kzk_z dispersion;
  4. endpoint consistency with projected bulk nodes;
  5. an odd net chiral crossing count on a loop enclosing projected charge;
  6. slab calculations that include the actual surface termination.

The closed-loop crossing count is more robust than tracing one visually appealing contour through regions where surface and bulk intensity overlap.

A three-dimensional Dirac point contains two Weyl sectors of opposite charge at the same momentum and energy. A schematic low-energy Hamiltonian is

HD(q)=(H+(q)00H−(q)),H_D(\mathbf q) = \begin{pmatrix} H_+(\mathbf q) & 0 \\ 0 & H_-(\mathbf q) \end{pmatrix},

where

CW[H+]=−CW[H−].C_W[H_+] = -C_W[H_-].

The total Berry charge through a surface enclosing the fourfold point is zero. Unlike a single Weyl node, topology alone therefore does not prevent the two sectors from mixing and gapping. A stable Dirac semimetal requires symmetry that forbids the mixing mass.

In Na3Bi\mathrm{Na_3Bi} and Cd3As2\mathrm{Cd_3As_2}-type models, band inversion occurs along a crystal rotation axis. Conduction and valence Kramers doublets with different rotation eigenvalues cannot hybridize on that axis. Their crossing produces a pair of symmetry-protected bulk Dirac points.

The protection ledger includes:

  • spinful time reversal;
  • inversion, giving double degeneracy at each momentum;
  • a crystal rotation or nonsymmorphic symmetry distinguishing the crossing bands;
  • translation symmetry and a momentum location where those labels apply.

Breaking the protecting rotation while preserving inversion and time reversal generally allows a mass and gaps the node. Depending on the mass sign and band inversion, the resulting phase can be a topological or trivial insulator. Breaking inversion or time reversal can split a Dirac point into separated Weyl nodes if the remaining terms do not simply gap it.

This makes a Dirac semimetal a useful parent phase at the boundary among several gapped and Weyl phases. It also makes it less generic than a Weyl semimetal: the fourfold node has no nonzero total Chern charge once its crystalline protection is removed. Topological Phase Transitions uses codimension to explain when a direct critical point expands into an intervening Weyl interval.

Not every three-dimensional Dirac crossing defines an extended semimetal phase. At a topological-insulator transition, tuning a mass through zero can produce a Dirac point only at one critical parameter value:

H(q,m)=∑i=13viqiΓi+mΓ4.H(\mathbf q,m) = \sum_{i=1}^{3} v_iq_i\Gamma_i + m\Gamma_4.

The spectrum

E±=±∑ivi2qi2+m2E_\pm = \pm \sqrt{ \sum_i v_i^2q_i^2+m^2 }

is gapless only at m=0m=0. A symmetry-protected Dirac semimetal instead forbids the relevant mass over a finite parameter region and pins crossings along a symmetry line. Experimental language should distinguish a stable phase from a tuned critical point.

Apply a magnetic field along z^\hat{\mathbf z} to an ideal isotropic Weyl cone. The transverse motion forms Landau levels. For n≥1n\geq1, the levels are paired:

En,±(kz)=±vℏ2kz2+2nℏe∣B∣.E_{n,\pm}(k_z) = \pm v \sqrt{ \hbar^2k_z^2 + 2n\hbar e\lvert B\rvert }.

The zeroth level is different:

E0,χ(kz)=sBχℏvkz,E_{0,\chi}(k_z) = s_B\chi\hbar vk_z,

where χ=±1\chi=\pm1 labels the two node chiralities and the sign sBs_B depends on the charge and magnetic-field conventions. The invariant statement is that opposite-chirality nodes have oppositely directed zeroth Landau levels.

An electric field parallel to B\mathbf B accelerates crystal momentum along these one-dimensional branches. States are pumped from one node to the other. For one simple pair, a standard continuum convention gives

∂n5∂t+∇⋅j5=e22π2ℏ2E⋅B−n5τv,\frac{\partial n_5}{\partial t} + \nabla\cdot\mathbf j_5 = \frac{e^2} {2\pi^2\hbar^2} \mathbf E\cdot\mathbf B - \frac{n_5}{\tau_v},

where

n5=nR−nLn_5=n_R-n_L

is the chiral population imbalance and τv\tau_v is an intervalley relaxation time. Total electric charge remains conserved:

∂n∂t+∇⋅j=0.\frac{\partial n}{\partial t} + \nabla\cdot\mathbf j = 0.

The anomaly is the failure of separate right- and left-node number conservation in parallel fields, not creation of net electric charge.

In the steady state,

n5=τve22π2ℏ2E⋅B.n_5 = \tau_v \frac{e^2} {2\pi^2\hbar^2} \mathbf E\cdot\mathbf B.

The resulting nonequilibrium chemical-potential imbalance can add a conductivity along the field. In an ideal weak-field semiclassical regime,

Δσ∥∝τvB2,\Delta\sigma_\parallel \propto \tau_v B^2,

with coefficients that depend on chemical potential, velocities, temperature, disorder, and the number of nodes.

Why negative magnetoresistance is not enough

Section titled “Why negative magnetoresistance is not enough”

A decrease of longitudinal resistance for nominally parallel current and magnetic field is compatible with anomaly transport, but several effects can imitate it:

  • current jetting: large transverse magnetoresistance focuses current through an inhomogeneous path, making a four-probe voltage geometry appear less resistive;
  • weak localization, magnetic scattering, or field-dependent mobility;
  • conductivity from trivial pockets;
  • contact placement and sample-shape errors;
  • small angular misalignment mixed with a large transverse response;
  • field-induced changes of magnetic order or band structure;
  • entry into the quantum limit with mechanisms unrelated to a clean semiclassical anomaly.

The TaP case is especially instructive: negative longitudinal magnetoresistance was observed even when the Fermi surface enclosed opposite-chirality nodes together, so chirality was not separately well defined, and modeled current redistribution strongly affected the signal. A credible anomaly experiment needs multiple voltage-contact configurations, homogeneous current injection, angular maps, sample-shape scaling, independent Fermi-surface characterization, and evidence that intervalley pumping is meaningful.

There is also no generic persistent bulk equilibrium current proportional to a static magnetic field in a lattice ground state. The transport anomaly described here is a nonequilibrium response involving electric-field pumping and relaxation.

For an ideal time-reversal-breaking Weyl semimetal with a single pair separated by 2b2\mathbf b in momentum space, the intrinsic Hall response contains

σH=e22π2ℏb,\boldsymbol\sigma_H = \frac{e^2} {2\pi^2\hbar} \mathbf b,

up to sign convention, filled-band contributions, and reciprocal-lattice ambiguities associated with adding three-dimensional quantum Hall layers. The slice picture explains the result: every momentum slice between the nodes contributes a two-dimensional Chern response.

In a real magnetic metal, conventional Berry curvature from all occupied bands also contributes to the anomalous Hall effect. A large Hall conductivity is therefore not a node counter. A validated band structure and chemical-potential dependence are needed.

For a clean, neutral, type-I three-dimensional Weyl cone, interband phase space gives a low-frequency optical conductivity linear in frequency:

Re⁡σ(ω)∝ω.\operatorname{Re}\sigma(\omega) \propto \omega.

Finite chemical potential Pauli-blocks low-frequency interband absorption and adds a Drude response. Anisotropy, tilt, several nodes, phonons, disorder, interactions, and trivial bands modify the slope and threshold. Linear optical conductivity supports a linearly dispersing three-dimensional spectrum but does not by itself measure CWC_W.

Bulk quantum oscillations determine extremal Fermi-surface areas through

F=ℏ2πeAext.F = \frac{\hbar}{2\pi e} A_{\mathrm{ext}}.

A phase offset influenced by Berry phase can be suggestive, but extracting a topological π\pi phase from a Landau fan requires care with:

  • whether conductivity or resistivity extrema are indexed;
  • three-dimensional curvature corrections;
  • Zeeman splitting;
  • multiple frequencies;
  • chemical-potential motion in field;
  • the quantum-limit regime.

In a thin slab, a proposed Weyl orbit combines a surface arc on one face, a chiral bulk Landau level, the opposite surface arc, and a return bulk channel. Thickness-dependent oscillation phase can test this picture, but surface and bulk paths, magnetic breakdown, and ordinary closed orbits must be modeled together.

ProbeTopological-semimetal informationMain limitation
Bulk ARPESNode position, dispersion, tilt, and chemical potentialFinite resolution, matrix elements, and incomplete out-of-plane momentum mapping
Surface ARPESArc connectivity and chiral crossing countSurface termination, trivial bands, overlapping bulk projection
First-principles and tight-binding calculationsCandidate nodes, charges, symmetry labels, surface spectrumDepend on structure, correlation treatment, and chemical potential; prediction is not measurement
Quantum oscillationsFermi-pocket geometry, mobility, effective mass, possible Weyl orbitsBerry-phase intercepts and surface assignments are not unique
Longitudinal magnetotransportPossible intervalley anomaly pumpingCurrent jetting and several ordinary mechanisms can mimic negative resistance
Anomalous Hall effectIntegrated Berry curvature and node-separation contributionOther occupied bands and magnetic textures also contribute
Optical and terahertz responseLinear dispersion, Drude weight, interband threshold, Landau transitionsUsually sums over topological and trivial carriers
STM and quasiparticle interferenceSurface-state dispersion and scattering constraintsArc termination can be hidden by matrix elements and bulk continuum

The strongest identification closes a loop:

  1. determine crystal and magnetic symmetry;
  2. locate bulk crossings and their energy;
  3. compute the Berry charge in a validated Hamiltonian;
  4. observe the corresponding surface connectivity;
  5. test response while controlling trivial carriers and geometry;
  6. track a symmetry-breaking or annihilation transition when possible.

The noncentrosymmetric TaAs family TaAs\mathrm{TaAs}, TaP\mathrm{TaP}, NbAs\mathrm{NbAs}, and NbP\mathrm{NbP} supplied the first widely accepted material Weyl-semimetal realizations. Time reversal is preserved, so nodes occur in same-charge pairs at opposite momenta and the full set contains additional opposite-charge pairs. In TaAs, spectroscopy and first-principles calculations jointly resolved bulk cones and surface arcs.

These materials also illustrate why the ideal two-node cartoon is only a local model. Several inequivalent nodes and trivial pockets can coexist near the Fermi level, and projected nodes can overlap on a chosen surface.

Breaking time reversal permits a minimal pair and an intrinsic anomalous Hall response related to node separation. Candidate and realized magnetic Weyl systems include kagome magnets, noncollinear antiferromagnets, and correlated semimetals. In them, determining the magnetic space group is part of determining whether a Weyl node is allowed. Domains, field-driven spin reorientation, and many-body renormalization can change the measured response without a simple rigid-band interpretation.

Na3Bi\mathrm{Na_3Bi} and Cd3As2\mathrm{Cd_3As_2} are canonical three-dimensional Dirac-semimetal platforms. Their inverted bands cross along a rotation axis, and photoemission has observed three-dimensional Dirac-like dispersions. High mobility and small effective masses make them useful for magnetotransport, but those properties alone do not establish crystalline protection.

Surface states of a Dirac semimetal are subtler than those of an isolated Weyl pair because the coincident opposite charges can mix at a surface that breaks the protecting crystal symmetry. Arc-like states may reconnect or become ordinary closed contours depending on termination and symmetry.

Strongly tilted crossings have been proposed and observed in materials including transition-metal dichalcogenides. Because the node sits at the contact of electron and hole pockets, the chemical potential, lattice constants, structural phase, and computational details can control whether the crossing exists. The correct claim is material- and phase-specific, not “large nonsaturating magnetoresistance proves a type-II Weyl node.”

Calling any linear band crossing a Weyl node. A Weyl node is isolated in three dimensions and carries nonzero Berry-flux charge. A nodal line, an avoided crossing, and a trivial accidental cone are different objects.

Treating the Pauli matrices as literal electron spin. They act in the two-band subspace and may represent orbitals, sublattices, Kramers sectors, or mixed spin–orbital states.

Forgetting lattice doubling. A single Weyl Hamiltonian is a valid local continuum theory, not a complete periodic band structure. The total node charge in the Brillouin zone vanishes.

Calling a Dirac point two independently protected Weyl nodes. Their net charge is zero at the same momentum. A crystalline symmetry must prevent mixing; once it is relaxed, a mass is generally allowed.

Drawing a Fermi arc without projected bulk states. The arc terminates by merging into the bulk continuum. Surface potential changes its shape, and opposite charges can project onto one point.

Using negative longitudinal magnetoresistance as a stand-alone anomaly proof. Current jetting, magnetic scattering, geometry, and trivial carriers require explicit controls.

Identifying a Landau-fan intercept with a universal Berry phase. Three-dimensional curvature, Zeeman energy, indexing convention, and chemical-potential motion alter the intercept.

Equating condensed-matter chirality with exact Lorentz chirality. The low-energy algebra is analogous, while the lattice, preferred frame, finite bandwidth, and node multiplicity remain essential.

Consider

H(q)=ℏ(vxqxσx+vyqyσy+vzqzσz).H(\mathbf q) = \hbar \left( v_xq_x\sigma_x + v_yq_y\sigma_y + v_zq_z\sigma_z \right).

Find the spectrum and the occupied-band node charge in the convention of this page.

Solution

The Pauli matrices anticommute, so

H2=ℏ2(vx2qx2+vy2qy2+vz2qz2)I.H^2 = \hbar^2 \left( v_x^2q_x^2 + v_y^2q_y^2 + v_z^2q_z^2 \right)I.

Therefore

E±=±ℏvx2qx2+vy2qy2+vz2qz2.E_\pm = \pm\hbar \sqrt{ v_x^2q_x^2 + v_y^2q_y^2 + v_z^2q_z^2 }.

The velocity matrix is diagonal, with

det⁡v=vxvyvz.\det v = v_xv_yv_z.

Using the occupied-band convention

CW=−sgn⁡det⁡v,C_W = -\operatorname{sgn}\det v,

the charge is

CW=−sgn⁡(vxvyvz).C_W = -\operatorname{sgn} \left( v_xv_yv_z \right).

Changing the sign of one principal velocity reverses the node charge. Changing two preserves it.

For an isotropic untilted node with E=ℏvqE=\hbar vq, derive the number of positive-energy states per volume below EE and hence ρ(E)\rho(E) for one nondegenerate cone.

Solution

The occupied momentum volume inside radius

qE=Eℏvq_E = \frac{E}{\hbar v}

is 4πqE3/34\pi q_E^3/3. One state per real-space volume occupies momentum volume (2π)3(2\pi)^3, so

N(E)V=1(2π)34π3(Eℏv)3=E36π2ℏ3v3.\frac{N(E)}{V} = \frac{1}{(2\pi)^3} \frac{4\pi}{3} \left( \frac{E}{\hbar v} \right)^3 = \frac{E^3} {6\pi^2\hbar^3v^3}.

Differentiating gives

ρ(E)=1VdNdE=E22π2ℏ3v3.\rho(E) = \frac{1}{V} \frac{dN}{dE} = \frac{E^2} {2\pi^2\hbar^3v^3}.

Node, spin, and valley multiplicities must be inserted explicitly rather than hidden in this one-cone result.

Given

Ω−(q)=CW2qq3,\boldsymbol\Omega_-(\mathbf q) = \frac{C_W}{2} \frac{\mathbf q}{q^3},

evaluate the flux through a sphere of radius RR and recover the Chern number.

Solution

On the sphere,

q=Rn^,dS=R2n^ dΩ.\mathbf q = R\hat{\mathbf n}, \qquad d\mathbf S = R^2\hat{\mathbf n}\,d\Omega.

Hence

Ω−⋅dS=CW2dΩ.\boldsymbol\Omega_-\cdot d\mathbf S = \frac{C_W}{2} d\Omega.

Integrating over solid angle gives

∮Ω−⋅dS=CW2∫dΩ=2πCW.\oint \boldsymbol\Omega_-\cdot d\mathbf S = \frac{C_W}{2} \int d\Omega = 2\pi C_W.

Therefore

12π∮Ω−⋅dS=CW.\frac{1}{2\pi} \oint \boldsymbol\Omega_-\cdot d\mathbf S = C_W.

The radius cancels, so any enclosing surface that remains gapped gives the same integer.

Explain why a time-reversal-invariant, inversion-breaking Weyl semimetal needs at least four simple nodes, whereas an inversion-symmetric, time-reversal-breaking one can have two.

Solution

Under time reversal,

Ω(k)↦−Ω(−k).\boldsymbol\Omega(\mathbf k) \mapsto -\boldsymbol\Omega(-\mathbf k).

The orientation of a small sphere also reverses when k\mathbf k is mapped to −k-\mathbf k. The two sign reversals cancel, so time reversal maps a node to one of the same charge. Charge neutrality then requires another time-reversal-related pair with the opposite charge. The minimum is four.

Under inversion,

Ω(k)↦Ω(−k)\boldsymbol\Omega(\mathbf k) \mapsto \boldsymbol\Omega(-\mathbf k)

because Berry curvature is an axial vector. The enclosing-surface orientation still reverses, so the node at −k-\mathbf k has the opposite charge. One inversion-related pair can satisfy

∑aCW,a=0,\sum_a C_{W,a}=0,

giving a minimum of two when time reversal is broken.

Two Weyl nodes lie at kz=−k0k_z=-k_0 and kz=+k0k_z=+k_0 with charges +1+1 and −1-1. Assume C(kz)=0C(k_z)=0 for kz<−k0k_z<-k_0. Find C(kz)C(k_z) in all three intervals and explain the surface consequence.

Solution

Crossing the first node changes the slice Chern number by +1+1:

C(kz)={0,kz<−k0,1,−k0<kz<k0,0,kz>k0.C(k_z) = \begin{cases} 0, & k_z<-k_0, \\ 1, & -k_0<k_z<k_0, \\ 0, & k_z>k_0. \end{cases}

The second node returns the value to zero because its charge is −1-1. Every intermediate slice is a Chern insulator and carries one chiral edge mode at a surface. At fixed energy, the family of edge states over

−k0<kz<k0-k_0<k_z<k_0

forms a surface contour ending at the projected nodes: the Fermi arc.

For anticommuting matrices Γ1,Γ2,Γ3,Γ4\Gamma_1,\Gamma_2,\Gamma_3,\Gamma_4, consider

H=∑i=13viqiΓi+mΓ4.H = \sum_{i=1}^{3} v_iq_i\Gamma_i + m\Gamma_4.

Show that mm gaps the Dirac point. Why must a stable Dirac semimetal forbid this term?

Solution

Anticommutation eliminates cross terms:

H2=(∑ivi2qi2+m2)I.H^2 = \left( \sum_i v_i^2q_i^2 + m^2 \right)I.

Thus

E±=±∑ivi2qi2+m2.E_\pm = \pm \sqrt{ \sum_i v_i^2q_i^2 + m^2 }.

At q=0\mathbf q=0, the conduction and valence energies are separated by

Δ=2∣m∣.\Delta = 2\lvert m\rvert.

Because the coincident Weyl sectors have zero total charge, topology does not forbid this mixing mass. A stable Dirac semimetal needs a crystal or other symmetry under which Γ4\Gamma_4 is not allowed; otherwise the gapless point occurs only at the tuned value m=0m=0.

For uniform parallel fields and no spatial gradient, let

n˙5=A E⋅B−n5τv,A=e22π2ℏ2.\dot n_5 = \mathcal A\,\mathbf E\cdot\mathbf B - \frac{n_5}{\tau_v}, \qquad \mathcal A = \frac{e^2}{2\pi^2\hbar^2}.

Find n5(t)n_5(t) for n5(0)=0n_5(0)=0 and its steady value.

Solution

The first-order linear equation has solution

n5(t)=τvA E⋅B(1−e−t/τv).n_5(t) = \tau_v \mathcal A\, \mathbf E\cdot\mathbf B \left( 1-e^{-t/\tau_v} \right).

At long times,

n5ss=τve22π2ℏ2E⋅B.n_5^{\mathrm{ss}} = \tau_v \frac{e^2} {2\pi^2\hbar^2} \mathbf E\cdot\mathbf B.

The buildup time is the intervalley relaxation time. Fast intervalley scattering suppresses the imbalance even though the microscopic Landau-level pumping remains. The equation transfers population between nodes and leaves total charge unchanged.

A high-mobility crystal shows a large decrease in resistance for one nominally parallel field–current geometry. The voltage changes strongly when contacts are moved, no ARPES or quantum-oscillation Fermi surface is available, and the transverse magnetoresistance is enormous. The result is announced as “unambiguous chiral anomaly.” Evaluate the claim and design four controls.

Solution

The strong contact dependence and large transverse magnetoresistance make current jetting a leading alternative. Without a known Fermi surface, it is also unclear whether separate chiral pockets exist or whether trivial carriers dominate. The observation is a candidate negative longitudinal magnetoresistance, not an unambiguous anomaly.

Useful controls include:

  • map the internal voltage distribution with several longitudinal and transverse contact pairs;
  • repeat with homogeneous full-width current contacts and several aspect ratios;
  • rotate B\mathbf B through fine angular steps while modeling tensor conductivity and misalignment;
  • determine the Fermi pockets, chemical potential, and node separations by quantum oscillations or spectroscopy;
  • compare samples with different residual resistivity and intervalley disorder;
  • test whether the inferred B2B^2, temperature, and chemical-potential trends are consistent across the semiclassical regime;
  • measure complementary node or surface evidence rather than relying on transport alone.

A robust conclusion must survive the same geometry analysis that explains current focusing in an ordinary anisotropic conductor.

  • Graphene and Dirac Materials provides the two-dimensional honeycomb benchmark and shows why sublattice pseudospin, valley doubling, and a zero Landau level do not by themselves imply a three-dimensional Weyl charge.
  • Band Theory Overview supplies the effective one-electron framework and the limits of a quasiparticle-band interpretation.
  • Fermi Surface owns pocket topology, carrier counting, velocity orientation, and quantum-oscillation geometry.
  • Chern Numbers in Band Theory develops gauge-covariant projectors, Wilson loops, discretized computation, and Hall response for gapped slices.
  • Topological Insulators gives the gapped class-AII comparison and explains how symmetry breaking can pass through a Weyl phase.
  • Edge and Surface States places Fermi arcs within a broader boundary-state taxonomy and distinguishes their open-contour evidence from gapped-bulk edge and surface modes.
  • Bulk–Boundary Correspondence states the gapped theorem and explains why a Weyl semimetal must instead apply it slice by slice between bulk nodes.
  • Spin–Orbit Coupling in Solids owns the microscopic and crystal-symmetry mechanisms that split or invert spin–orbital bands.
  • Angular Momentum to Helicity distinguishes helicity from Lorentz chirality before those terms are borrowed for crystal quasiparticles.
  • Dirac Equation Formula Card records the relativistic equation and conventions; the crystal Hamiltonians here are low-energy analogues, not exact Lorentz theories.
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