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Complete Sets of Commuting Observables

A complete set of commuting observables (CSCO) is a mutually compatible family whose joint eigenvalue labels distinguish basis states, up to phase, within a specified Hilbert space or sector.

The idea has two parts:

  1. Commuting: the observables admit simultaneous sharp alternatives and a common eigenbasis in the finite-dimensional setting.
  2. Complete: every nonzero joint eigenspace is one-dimensional, so no unexplained degeneracy label remains.

If the family is

C={A1,…,Ar},\mathcal C = \left\lbrace A_1,\ldots,A_r \right\rbrace,

a simultaneous eigenstate satisfies

Ak∣α1,…,αr⟩=αk∣α1,…,αr⟩A_k |\alpha_1,\ldots,\alpha_r\rangle = \alpha_k |\alpha_1,\ldots,\alpha_r\rangle

for every kk. Completeness means that the tuple

α=(α1,…,αr)\boldsymbol\alpha = (\alpha_1,\ldots,\alpha_r)

identifies one ray rather than a multidimensional subspace.

This page owns the label-and-degeneracy structure. The criterion for compatibility itself is developed in Compatible Observables, while dynamical labels protected by symmetry are the subject of Simultaneous Eigenstates and Good Quantum Numbers.

Let A1,…,ArA_1,\ldots,A_r be self-adjoint operators on a finite-dimensional Hilbert space H\mathcal H. Assume pairwise commutation:

[Ai,Aj]=0for every i,j.[A_i,A_j]=0 \qquad \text{for every }i,j.

Then the family can be simultaneously diagonalized. There exists an orthonormal basis whose vectors are eigenvectors of every AkA_k.

Pairwise commutation is enough for simultaneous diagonalization here because the operators are self-adjoint and the dimension is finite. It is not by itself a completeness condition. Several basis vectors may still share the same full tuple of eigenvalues.

For a candidate tuple α=(α1,…,αr)\boldsymbol\alpha=(\alpha_1,\ldots,\alpha_r), define the joint eigenspace

Hα=⋂k=1rKer⁡(Ak−αkI).\mathcal H_{\boldsymbol\alpha} = \bigcap_{k=1}^r \operatorname{Ker}(A_k-\alpha_k I).

Only tuples for which this intersection is nonzero occur. The simultaneous eigenvectors with those values are exactly the nonzero vectors in Hα\mathcal H_{\boldsymbol\alpha}.

The Hilbert space decomposes as an orthogonal direct sum,

H=⨁αHα.\mathcal H = \mathop{\bigoplus}_{\boldsymbol\alpha} \mathcal H_{\boldsymbol\alpha}.

If

gα=dim⁡Hα>1,g_{\boldsymbol\alpha} = \dim\mathcal H_{\boldsymbol\alpha}>1,

the tuple leaves a residual degeneracy. Basis vectors must still be written as

∣α,μ⟩,μ=1,…,gα.|\boldsymbol\alpha,\mu\rangle, \qquad \mu=1,\ldots,g_{\boldsymbol\alpha}.

Write the spectral decomposition of each observable as

Ak=∑αkαkPαk(k).A_k = \sum_{\alpha_k} \alpha_k P^{(k)}_{\alpha_k}.

Because the observables commute, all their spectral projectors commute in finite dimensions. The joint projector is

Pα=∏k=1rPαk(k).P_{\boldsymbol\alpha} = \prod_{k=1}^r P^{(k)}_{\alpha_k}.

Its range is the joint eigenspace:

Ran⁡Pα=Hα.\operatorname{Ran}P_{\boldsymbol\alpha} = \mathcal H_{\boldsymbol\alpha}.

The nonzero joint projectors satisfy

PαPβ=δαβPα,∑αPα=I.\begin{aligned} P_{\boldsymbol\alpha} P_{\boldsymbol\beta} &= \delta_{\boldsymbol\alpha\boldsymbol\beta} P_{\boldsymbol\alpha},\\ \sum_{\boldsymbol\alpha} P_{\boldsymbol\alpha} &=I. \end{aligned}

This projector formulation is the cleanest test of completeness because it is independent of basis choices inside degenerate subspaces.

The commuting family {A1,…,Ar}\{A_1,\ldots,A_r\} is complete on H\mathcal H when every nonzero joint eigenspace is one-dimensional:

dim⁡Hα=1for every occurring α.\dim\mathcal H_{\boldsymbol\alpha}=1 \qquad \text{for every occurring }\boldsymbol\alpha.

Equivalently,

rank⁡Pα=1\operatorname{rank}P_{\boldsymbol\alpha}=1

for every nonzero joint projector. One may then write

Pα=∣α⟩⟨α∣,P_{\boldsymbol\alpha} = |\boldsymbol\alpha\rangle \langle\boldsymbol\alpha|,

and the resolution of identity becomes

I=∑α∣α⟩⟨α∣.I = \sum_{\boldsymbol\alpha} |\boldsymbol\alpha\rangle \langle\boldsymbol\alpha|.

The tuple identifies a normalized basis vector up to multiplication by a global phase. A CSCO labels rays, not phase conventions.

The constructive way to build a CSCO is to refine only the degeneracies that remain.

Start with A1A_1. Its eigenspaces may have dimensions greater than one. Because A2A_2 commutes with A1A_1, it preserves each eigenspace of A1A_1. Diagonalize the restriction of A2A_2 inside every degenerate block. This replaces each A1A_1 block by smaller joint eigenspaces.

If some joint blocks are still multidimensional, restrict A3A_3 to those blocks and diagonalize again. Continue until all nonzero joint eigenspaces have dimension one.

Successive commuting observables refining degenerate eigenspaces into rank-one joint sectors

Each added commuting observable acts within the blocks already selected by the earlier labels. The family becomes complete when every surviving joint projector has rank one.

The process is local to each degenerate block. An added observable need not split every block; it is useful if the full family eventually resolves all of them.

Consider

A=(a000a000c),a≠c.A = \begin{pmatrix} a&0&0\\ 0&a&0\\ 0&0&c \end{pmatrix}, \qquad a\neq c.

The eigenvalue aa has a two-dimensional eigenspace, so AA alone is not complete. Now let

B=(b1000b2000b3),b1≠b2.B = \begin{pmatrix} b_1&0&0\\ 0&b_2&0\\ 0&0&b_3 \end{pmatrix}, \qquad b_1\neq b_2.

The operators commute. Their joint labels are

(a,b1),(a,b2),(c,b3).(a,b_1), \qquad (a,b_2), \qquad (c,b_3).

If these three tuples are distinct, every joint eigenspace is one-dimensional, and {A,B}\{A,B\} is complete. The value of BB on the cc eigenspace does not need to differ from both b1b_1 and b2b_2 unless doing so is required to keep the full tuples distinct. It is the tuple, not any one entry, that labels a state.

A CSCO need not contain several operators. A single nondegenerate self-adjoint observable has one-dimensional eigenspaces, so

{A}\{A\}

is already complete.

Conversely, a family can contain many commuting observables and still fail to be complete if a multidimensional joint eigenspace remains. Cardinality alone says nothing.

In a finite-dimensional space, any fixed orthonormal basis can be labeled by a single self-adjoint operator with distinct assigned eigenvalues:

C=∑ncn∣n⟩⟨n∣,cn≠cm for n≠m.C = \sum_n c_n|n\rangle\langle n|, \qquad c_n\neq c_m \text{ for }n\neq m.

This artificial operator shows that a one-element CSCO always exists once a basis is chosen. Physically useful CSCOs are preferred because their operators have dynamical, symmetry, geometric, or experimental meaning.

Minimal, Redundant, and Independent Labels

Section titled “Minimal, Redundant, and Independent Labels”

Completeness does not imply minimality. If {A,B}\{A,B\} is complete and C=f(A,B)C=f(A,B), then

{A,B,C}\{A,B,C\}

is still complete, but CC is redundant. It adds no refinement because its value is determined by the existing tuple.

Likewise, adding the identity or a constant observable changes no joint eigenspace. A minimal CSCO is a complete family from which no observable can be removed without losing completeness. Minimal CSCOs need not be unique and need not have the same number of members when observables with different spectral structures are allowed.

The word independent is often used informally for nonredundant labels, but it should not be confused with statistical independence. CSCO eigenvalues can be functionally constrained or correlated while still labeling basis states.

Completeness Is Relative to a Space or Sector

Section titled “Completeness Is Relative to a Space or Sector”

The phrase “complete” is incomplete unless the space being labeled is stated. An observable can be complete on one sector and incomplete on a larger Hilbert space.

Suppose

H=Hmathrmorb⊗Hmathrmspin.\mathcal H = \mathcal H_{mathrm{orb}} \otimes \mathcal H_{mathrm{spin}}.

An orbital CSCO labels only Hmathrmorb\mathcal H_{mathrm{orb}}. On the full tensor product, every orbital tuple is repeated once for each unresolved spin state. One must add spin labels or explicitly declare that a spin sector has been fixed.

The same issue occurs with:

  • repeated copies of an angular-momentum irreducible representation;
  • particle number, charge, parity, or other superselection sectors;
  • center-of-mass and internal degrees of freedom;
  • boundary-condition sectors;
  • radial, flavor, band, lattice, and internal labels.

Throughout a calculation, the declared sector is part of the CSCO statement.

For a particle whose Hilbert space is only the two-dimensional spin-1/21/2 space, SzS_z has two nondegenerate values:

Sz∣±z⟩=±ℏ2∣±z⟩.S_z|\pm z\rangle = \pm\frac{\hbar}{2}|\pm z\rangle.

Thus {Sz}\{S_z\} is complete on this fixed spin space.

The Casimir operator is constant:

S2=34ℏ2I.S^2 = \frac34\hbar^2 I.

It does not distinguish the two states. The conventional pair

{S2,Sz}\{S^2,S_z\}

is complete but not minimal when the spin-1/21/2 sector is already fixed. S2S^2 becomes useful when the Hilbert space contains several possible total spin values.

Any spin component SnS_{\boldsymbol n} also has a nondegenerate spectrum, so {Sn}\{S_{\boldsymbol n}\} is another CSCO. Different choices define different orthonormal bases; completeness does not make the choice unique.

The angular-momentum components do not commute pairwise:

[Li,Lj]=iℏϵijkLk.[L_i,L_j] = i\hbar\epsilon_{ijk}L_k.

The conventional commuting pair is

{L2,Lz}.\{L^2,L_z\}.

Its simultaneous eigenvectors satisfy

L2∣ℓ,m⟩=ℏ2ℓ(ℓ+1)∣ℓ,m⟩,Lz∣ℓ,m⟩=ℏm∣ℓ,m⟩.\begin{aligned} L^2|\ell,m\rangle &= \hbar^2\ell(\ell+1)|\ell,m\rangle,\\ L_z|\ell,m\rangle &= \hbar m|\ell,m\rangle. \end{aligned}

On the standard angular Hilbert space L2(S2)L^2(S^2), each pair (ℓ,m)(\ell,m) occurs once, so {L2,Lz}\{L^2,L_z\} is complete for angular wavefunctions.

On a three-dimensional particle Hilbert space, the same pair does not resolve the radial degree of freedom. One needs a radial or energy label appropriate to the Hamiltonian. This is a direct example of sector-relative completeness.

The operator algebra is developed in Angular Momentum Algebra.

For two fixed angular momenta j1j_1 and j2j_2, the uncoupled basis is labeled by

{J12,J1z,J22,J2z}.\{J_1^2,J_{1z},J_2^2,J_{2z}\}.

If j1j_1 and j2j_2 have already been fixed as sector data, the nonconstant labels J1zJ_{1z} and J2zJ_{2z} suffice for that tensor-product basis.

The coupled basis instead uses

{J12,J22,J2,Jz},J=J1+J2.\{J_1^2,J_2^2,J^2,J_z\}, \qquad \mathbf J=\mathbf J_1+\mathbf J_2.

For fixed j1,j2j_1,j_2, the labels (j,m)(j,m) distinguish the coupled basis states. These two CSCOs describe different bases of the same Hilbert space, related by Clebsch–Gordan coefficients. See Coupled and Uncoupled Bases.

For three or more angular momenta, the same total jj can occur with multiplicity. Intermediate operators such as

J122=(J1+J2)2J_{12}^2 = (\mathbf J_1+\mathbf J_2)^2

can provide the extra commuting label. The chosen coupling tree is part of the basis convention.

For the nonrelativistic spinless Coulomb Hamiltonian, the bound states are conventionally labeled

∣n,ℓ,m⟩.|n,\ell,m\rangle.

The commuting family

{H,L2,Lz}\{H,L^2,L_z\}

has eigenvalue equations

H∣n,ℓ,m⟩=En∣n,ℓ,m⟩,L2∣n,ℓ,m⟩=ℏ2ℓ(ℓ+1)∣n,ℓ,m⟩,Lz∣n,ℓ,m⟩=ℏm∣n,ℓ,m⟩.\begin{aligned} H|n,\ell,m\rangle &= E_n|n,\ell,m\rangle,\\ L^2|n,\ell,m\rangle &= \hbar^2\ell(\ell+1)|n,\ell,m\rangle,\\ L_z|n,\ell,m\rangle &= \hbar m|n,\ell,m\rangle. \end{aligned}

On the ideal spinless bound-state Hilbert space, the tuple (En,ℓ,m)(E_n,\ell,m) identifies one state up to phase. The energy alone is highly degenerate; L2L^2 and LzL_z refine that degeneracy.

Several qualifications matter:

  • this statement is for the bound sector;
  • spin adds another degree of freedom;
  • relativistic, fine-structure, hyperfine, and external-field terms change which operators commute with the Hamiltonian;
  • the Coulomb problem has an enlarged dynamical symmetry, so alternative complete label systems can be constructed.

The model-specific spectrum and degeneracy are developed in Hydrogen Atom.

A Hilbert space generally admits many CSCOs. Choosing one is choosing an orthonormal basis with physically meaningful labels.

For an isotropic problem, one may prefer angular-momentum labels. In a Cartesian separable problem, number operators or component energies may be more convenient. In a coupled-spin problem, either coupled or uncoupled labels may be useful depending on the Hamiltonian and the interaction being treated.

Two different CSCOs need not commute with each other as families. Their bases can be incompatible, just as the SzS_z and SxS_x bases are incompatible even though each single observable is complete on a spin-1/21/2 space.

Completeness therefore does not select one privileged basis. The Hamiltonian, symmetries, boundary conditions, observables of interest, and experimental arrangement guide the choice.

For a complete finite-dimensional family, the rank-one joint projectors

Pα=∣α⟩⟨α∣P_{\boldsymbol\alpha} = |\boldsymbol\alpha\rangle \langle\boldsymbol\alpha|

define a projective measurement in the joint eigenbasis. For a normalized pure state,

p(α)=⟨ψ∣Pα∣ψ⟩.p(\boldsymbol\alpha) = \langle\psi| P_{\boldsymbol\alpha} |\psi\rangle.

Because the individual spectral projectors commute, ideal measurements can be refined to these joint alternatives. Under the standard Lüders model, the joint projector is independent of the order in which the compatible labels are filtered.

This formal statement does not guarantee that every member of a convenient CSCO corresponds to an equally practical laboratory measurement. Nor does one joint outcome reconstruct an arbitrary unknown state. It only distinguishes the simultaneous eigenstates of that basis.

The state-update and ordering questions belong to Sequential Measurements.

A CSCO is basis complete: its eigenvalue tuples label the rays in one orthonormal basis. It is not an informationally complete measurement for state tomography.

For example, measuring SzS_z is a CSCO measurement on a spin-1/21/2 Hilbert space. Its probabilities determine the populations in the SzS_z basis but not the relative phase between those components. Many different density operators have the same SzS_z statistics.

An informationally complete POVM has enough outcomes across noncommuting directions to reconstruct an arbitrary density operator. That is a different use of the word “complete.”

An observable need not commute with the Hamiltonian merely to belong to some CSCO. A CSCO defines a basis at a given time; a good quantum number is a label preserved by the dynamics or useful for stationary states.

To label energy eigenstates, one normally includes HH and chooses additional operators QkQ_k satisfying

[H,Qk]=0,[Qj,Qk]=0.[H,Q_k]=0, \qquad [Q_j,Q_k]=0.

Their eigenvalues can then label stationary states. If a perturbation changes the Hamiltonian so that a commutator becomes nonzero, the old quantum number may cease to be exact even though it remains a useful basis label or approximation.

The exact, approximate, and symmetry-protected meanings are developed in Simultaneous Eigenstates and Good Quantum Numbers.

Textbooks sometimes use complete commuting set and maximal commuting set almost interchangeably. In finite dimensions, the clean operator-algebra statement is:

A commuting self-adjoint family has one-dimensional joint eigenspaces if and only if the unital star-algebra it generates is the full maximal abelian algebra of operators diagonal in its joint eigenbasis.

This does not mean that no further observable can be appended. Every operator diagonal in the same basis commutes with the family, and many are functions of the existing labels. What is maximal is the generated abelian algebra, not a literal finite list with no possible additions.

A listed CSCO may therefore be redundant while still generating, through functions and combinations, the full diagonal algebra associated with its basis.

Continuous and Infinite-Dimensional Caveat

Section titled “Continuous and Infinite-Dimensional Caveat”

In infinite dimensions, the textbook phrase “[Ai,Aj]=0[A_i,A_j]=0” can be too weak for unbounded operators. Algebraic commutation on a small common domain does not automatically imply commuting spectral measures or a common spectral representation.

The appropriate robust condition is strong commutation: the spectral projectors of the self-adjoint operators commute. Joint spectral theory then replaces a discrete basis by a direct-integral representation with discrete and continuous labels.

In that setting, completeness is associated with spectral multiplicity one: the full joint spectral label should leave no unresolved multiplicity space in the representation being used. Generalized eigenvectors may be delta-normalized rather than Hilbert-space vectors, and continuous labels do not correspond to ordinary rank-one projectors at individual points.

These issues require the machinery of Spectral Theorem, Practical Version and the domain cautions in Hermitian vs Self-Adjoint Operators.

For a proposed finite-dimensional label family:

  1. State the space or sector. Include all degrees of freedom that are being labeled.
  2. Check self-adjointness. Each proposed label operator must represent a sharp observable on the intended space.
  3. Check pairwise commutation. Verify [Ai,Aj]=0[A_i,A_j]=0.
  4. Find the joint projectors. Form products of the commuting spectral projectors.
  5. Discard zero tuples. Not every Cartesian combination of eigenvalues occurs.
  6. Compute joint ranks. Completeness requires every nonzero rank to be one.
  7. Add a refining observable if needed. Diagonalize its restriction inside the remaining degenerate blocks.
  8. Identify redundancy. Remove labels that are functions of the others if a minimal set is desired.
  9. Check dynamics separately. To call the labels good quantum numbers, verify commutation with HH.
  10. Reassess after changing the model. Couplings, fields, boundaries, and symmetry breaking can alter the useful CSCO.
  • Equating commutation with completeness. Commuting observables can leave large joint degeneracies.
  • Counting operators instead of joint ranks. One nondegenerate observable can be complete; many commuting observables can be incomplete.
  • Omitting the space or sector. SzS_z is complete on a fixed spin-1/21/2 space but not on a larger orbital-spin Hilbert space.
  • Adding only functions of existing labels. Such observables do not refine joint eigenspaces.
  • Assuming a CSCO is unique. Different complete families define different bases of the same Hilbert space.
  • Using noncommuting labels together. JxJ_x and JzJ_z do not form a joint sharp label system.
  • Forgetting multiplicity copies. The same j,mj,m values can occur more than once in composite or many-body systems.
  • Calling every CSCO label a conserved quantum number. Conservation also requires the relevant commutator with the Hamiltonian.
  • Confusing CSCO completeness with tomography. One complete eigenbasis measurement does not determine an arbitrary quantum state.
  • Using ordinary commutators carelessly for unbounded operators. Strong commutation is a spectral condition.

This page owns completeness of joint eigenvalue labels. Nearby pages own the ingredients and applications:

  • A finite-dimensional CSCO is a pairwise commuting self-adjoint family whose nonzero joint eigenspaces are all one-dimensional.
  • Joint projectors are products of the commuting individual spectral projectors.
  • Degeneracy is refined by diagonalizing each new observable inside the blocks preserved by the earlier observables.
  • A single nondegenerate observable can be complete.
  • Completeness does not imply minimality, independence, conservation, or informational completeness.
  • A CSCO is always relative to a declared Hilbert space or sector.
  • Spin, angular momentum, composite systems, and hydrogen illustrate how additional labels resolve different kinds of degeneracy.
  • Different CSCOs define different complete bases for the same system.
  • Good quantum numbers require dynamical compatibility with the Hamiltonian in addition to mutual commutation.
  • In infinite dimensions, strong commutation and joint spectral multiplicity replace the simple finite-dimensional rank-one criterion.
  • P. A. M. Dirac, The Principles of Quantum Mechanics, 4th ed., Oxford University Press, 1958.
  • J. von Neumann, Mathematical Foundations of Quantum Mechanics, Princeton University Press, 1955.
  • L. D. Landau and E. M. Lifshitz, Quantum Mechanics: Non-Relativistic Theory, 3rd ed., Pergamon, 1977.
  • A. Messiah, Quantum Mechanics, Dover, 1999.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • C. Cohen-Tannoudji, B. Diu, and F. Laloë, Quantum Mechanics, Wiley, 1977.
  • B. C. Hall, Quantum Theory for Mathematicians, Springer, 2013.

Let

A=∑aaPa,B=∑bbQbA=\sum_a aP_a, \qquad B=\sum_b bQ_b

be commuting finite-dimensional self-adjoint operators. Show that PaQbP_aQ_b is the orthogonal projector onto the joint eigenspace with values (a,b)(a,b).

Solution

Commutation of AA and BB implies commutation of their spectral projectors:

PaQb=QbPa.P_aQ_b=Q_bP_a.

Therefore

(PaQb)2=Pa2Qb2=PaQb,\begin{aligned} (P_aQ_b)^2 &= P_a^2Q_b^2\\ &= P_aQ_b, \end{aligned}

and

(PaQb)†=QbPa=PaQb.(P_aQ_b)^\dagger = Q_bP_a = P_aQ_b.

Its range lies in both Ran⁡Pa\operatorname{Ran}P_a and Ran⁡Qb\operatorname{Ran}Q_b. Conversely, any vector in their intersection is fixed by both projectors and therefore by their product. The range is exactly the joint eigenspace.

Let

A=diag⁡(1,1,2,2),B=diag⁡(0,1,0,1).\begin{aligned} A &= \operatorname{diag}(1,1,2,2),\\ B &= \operatorname{diag}(0,1,0,1). \end{aligned}

Determine whether {A}\{A\} and {A,B}\{A,B\} are complete on C4\mathbb C^4.

Solution

The operator AA has two eigenspaces, each of dimension two, so {A}\{A\} is not complete.

The joint tuples for {A,B}\{A,B\} are

(1,0),(1,1),(2,0),(2,1).(1,0), \quad (1,1), \quad (2,0), \quad (2,1).

Each tuple occurs on exactly one standard basis vector. Every nonzero joint projector therefore has rank one, so {A,B}\{A,B\} is complete.

Suppose {A,B}\{A,B\} is a CSCO and define

C=A2+3B.C=A^2+3B.

Does adding CC refine the joint eigenspaces? Is {A,B,C}\{A,B,C\} still complete?

Solution

On a joint eigenstate with labels (a,b)(a,b),

C∣a,b⟩=(a2+3b)∣a,b⟩.C|a,b\rangle = (a^2+3b)|a,b\rangle.

The value of CC is already determined by (a,b)(a,b), so it cannot split any joint eigenspace of AA and BB. It is redundant. The enlarged family is still complete because adding a commuting observable cannot merge the existing rank-one joint spaces, but it is not a more informative label system.

Explain why SzS_z is complete on a fixed spin-1/21/2 Hilbert space but not on

Hmathrmorb⊗C2\mathcal H_{mathrm{orb}} \otimes \mathbb C^2

when dim⁡Hmathrmorb>1\dim\mathcal H_{mathrm{orb}}>1.

Solution

On C2\mathbb C^2, the two values ±ℏ/2\pm\hbar/2 each have a one-dimensional eigenspace. Thus SzS_z is nondegenerate and complete.

On the tensor product, the operator is really Iorb⊗SzI_{\mathrm{orb}}\otimes S_z. For either spin value, every orbital vector is allowed. Each eigenspace has dimension dim⁡Horb\dim\mathcal H_{\mathrm{orb}}, so the spin label leaves the orbital degree of freedom unresolved.

On the angular Hilbert space L2(S2)L^2(S^2), explain why L2L^2 alone is not complete and why {L2,Lz}\{L^2,L_z\} is complete.

Solution

For fixed ℓ\ell, the value

ℏ2ℓ(ℓ+1)\hbar^2\ell(\ell+1)

is shared by the 2ℓ+12\ell+1 states with m=−ℓ,…,ℓm=-\ell,\ldots,\ell. Thus L2L^2 leaves an angular degeneracy.

Adding LzL_z supplies the value ℏm\hbar m. Each pair (ℓ,m)(\ell,m) corresponds to one spherical harmonic YℓmY_{\ell m} up to phase, so every joint eigenspace is one-dimensional on L2(S2)L^2(S^2).

For three spin-1/21/2 particles, the total-spin labels (j,m)(j,m) do not always identify a unique coupled basis state. What additional commuting label can be used in the coupling scheme where particles 1 and 2 are combined first?

Solution

The tensor product contains two independent copies of the total j=1/2j=1/2 representation. In the coupling scheme where particles 1 and 2 are combined first, use

J122=(J1+J2)2.J_{12}^2 = (\mathbf J_1+\mathbf J_2)^2.

Its label j12=0j_{12}=0 or 11 distinguishes the two ways to obtain total j=1/2j=1/2. For fixed individual spins, the family

{J122,J2,Jz}\{J_{12}^2,J^2,J_z\}

is complete for this coupled basis.

Why does the CSCO measurement SzS_z not determine an arbitrary spin-1/21/2 density operator?

Solution

The two SzS_z probabilities determine only the diagonal entries of ρ\rho in the SzS_z basis. They do not determine the off-diagonal coherence, or equivalently the xx and yy components of the Bloch vector. States with different relative phases can have identical SzS_z statistics. A tomographic measurement must probe additional, incompatible directions or use an informationally complete POVM.

Let {A,B}\{A,B\} be a finite-dimensional CSCO with rank-one joint projectors Pa,bP_{a,b}. Show that the AA-outcome probability is the marginal

p(a)=∑bp(a,b).p(a)=\sum_b p(a,b).
Solution

The AA eigenspace is the orthogonal sum of all joint eigenspaces with the same aa, so

Pa=∑bPa,b.P_a = \sum_bP_{a,b}.

For a normalized pure state,

p(a)=⟨ψ∣Pa∣ψ⟩=∑b⟨ψ∣Pa,b∣ψ⟩=∑bp(a,b).\begin{aligned} p(a) &= \langle\psi|P_a|\psi\rangle\\ &= \sum_b \langle\psi|P_{a,b}|\psi\rangle\\ &= \sum_b p(a,b). \end{aligned}