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Position–Momentum Uncertainty

For a particle on the real line, every normalized state with finite position and momentum variances satisfies

Δψx Δψp≥ℏ2.\Delta_\psi x\,\Delta_\psi p \ge \frac{\hbar}{2}.

This is the canonical position–momentum preparation uncertainty relation. It compares the root-mean-square widths of the position and momentum distributions assigned to the same state. It does not compare the calibration errors of two detectors, and it does not require position and momentum to be measured sequentially on one specimen.

The constant is state independent because the canonical commutator is central:

[x,p]=iℏI.[x,p]=i\hbar I.

The same theorem is also a Fourier-analysis statement. Position and momentum wavefunctions are Fourier transforms, and a square-integrable function and its transform cannot both have arbitrarily small variance. Quantum mechanics turns those two mathematical widths into observable probability spreads.

The stronger covariance-sensitive form is

(Δψx)2(Δψp)2−Cψ(x,p)2≥ℏ24,\begin{aligned} (\Delta_\psi x)^2(\Delta_\psi p)^2 &- C_\psi(x,p)^2 \\ &\ge \frac{\hbar^2}{4}, \end{aligned}

where Cψ(x,p)C_\psi(x,p) is the symmetrized position–momentum covariance. An uncorrelated Gaussian saturates the product relation. A chirped Gaussian can saturate the stronger determinant relation while having Δx Δp>ℏ/2\Delta x\,\Delta p>\hbar/2.

The standard theorem applies to one Cartesian degree of freedom on the full line. The Hilbert space is

H=L2(R,dx),\mathcal H=L^2(\mathbb R,dx),

with normalized wavefunction

∫−∞∞∣ψ(x)∣2 dx=1.\int_{-\infty}^{\infty} |\psi(x)|^2\,dx =1.

In the Schrödinger representation,

(xψ)(x)=xψ(x),(x\psi)(x)=x\psi(x),

and

(pψ)(x)=−iℏdψdx(x)(p\psi)(x) = -i\hbar\frac{d\psi}{dx}(x)

on a suitable domain. The momentum-space wavefunction is

ϕ(p)=12πℏ∫−∞∞e−ipx/ℏψ(x) dx.\phi(p) = \frac{1}{\sqrt{2\pi\hbar}} \int_{-\infty}^{\infty} e^{-ipx/\hbar}\psi(x)\,dx.

The inverse transform is

ψ(x)=12πℏ∫−∞∞eipx/ℏϕ(p) dp.\psi(x) = \frac{1}{\sqrt{2\pi\hbar}} \int_{-\infty}^{\infty} e^{ipx/\hbar}\phi(p)\,dp.

With this symmetric convention, Plancherel gives

∫−∞∞∣ϕ(p)∣2 dp=1.\int_{-\infty}^{\infty}|\phi(p)|^2\,dp=1.

Other Fourier conventions move factors of 2π2\pi between the transform and the width inequality. The physical formula remains ℏ/2\hbar/2 once momentum is identified as p=ℏkp=\hbar k. The site-wide convention is recorded in Fourier Transform Conventions.

Position outcomes have density

ρx(x)=∣ψ(x)∣2,\rho_x(x)=|\psi(x)|^2,

with mean

x0=⟨x⟩ψ=∫−∞∞x∣ψ(x)∣2 dx,x_0 = \langle x\rangle_\psi = \int_{-\infty}^{\infty} x|\psi(x)|^2\,dx,

and variance

(Δψx)2=∫−∞∞(x−x0)2∣ψ(x)∣2 dx.(\Delta_\psi x)^2 = \int_{-\infty}^{\infty} (x-x_0)^2|\psi(x)|^2\,dx.

Momentum outcomes have density

ρp(p)=∣ϕ(p)∣2,\rho_p(p)=|\phi(p)|^2,

with mean

p0=⟨p⟩ψ=∫−∞∞p∣ϕ(p)∣2 dp,p_0 = \langle p\rangle_\psi = \int_{-\infty}^{\infty} p|\phi(p)|^2\,dp,

and variance

(Δψp)2=∫−∞∞(p−p0)2∣ϕ(p)∣2 dp.(\Delta_\psi p)^2 = \int_{-\infty}^{\infty} (p-p_0)^2|\phi(p)|^2\,dp.

These are two representations of one state, not two independent probability models. The means x0x_0 and p0p_0 locate the packet in phase space; the uncertainty relation constrains its widths about those means.

A standard deviation is not a hard interval. In a non-Gaussian state, Δx\Delta x does not mean that every position outcome lies between x0−Δxx_0-\Delta x and x0+Δxx_0+\Delta x.

The Robertson relation is

ΔψA ΔψB≥12∣⟨[A,B]⟩ψ∣.\Delta_\psi A\,\Delta_\psi B \ge \frac12 \left\lvert \langle[A,B]\rangle_\psi \right\rvert.

Set A=xA=x and B=pB=p. On a domain where the canonical relation is valid,

[x,p]=iℏI.[x,p]=i\hbar I.

Normalization gives

⟨[x,p]⟩ψ=iℏ⟨I⟩ψ=iℏ.\begin{aligned} \langle[x,p]\rangle_\psi &= i\hbar\langle I\rangle_\psi \\ &=i\hbar. \end{aligned}

Therefore

Δψx Δψp≥12∣iℏ∣=ℏ2.\begin{aligned} \Delta_\psi x\,\Delta_\psi p &\ge \frac12|i\hbar| \\ &= \frac\hbar2. \end{aligned}

Unlike a generic commutator expectation, the right side cannot vanish in a normalized state. The identity operator is what makes this bound universal within the theorem’s domain.

The general Cauchy–Schwarz proof and equality criteria belong to General Uncertainty Relations. The algebraic and Weyl forms of the canonical relation belong to Canonical Commutation Relations.

The wavefunction proof exposes the analytic assumptions hidden by the short commutator argument.

Define the centered fluctuation vectors

f(x)=(x−x0)ψ(x),f(x)=(x-x_0)\psi(x),

and

g(x)=(−iℏddx−p0)ψ(x).g(x) = \left( -i\hbar\frac{d}{dx}-p_0 \right) \psi(x).

Their norms are

∥f∥2=(Δψx)2,∥g∥2=(Δψp)2.\|f\|^2=(\Delta_\psi x)^2, \qquad \|g\|^2=(\Delta_\psi p)^2.

Cauchy–Schwarz gives

(Δψx)2(Δψp)2≥∣⟨f∣g⟩∣2.(\Delta_\psi x)^2(\Delta_\psi p)^2 \ge |\langle f|g\rangle|^2.

Because

∫−∞∞(x−x0)∣ψ(x)∣2 dx=0,\int_{-\infty}^{\infty} (x-x_0)|\psi(x)|^2\,dx=0,

the p0p_0 term does not contribute, and

⟨f∣g⟩=−iℏ∫−∞∞(x−x0)ψ(x)∗ψ′(x) dx.\langle f|g\rangle = -i\hbar \int_{-\infty}^{\infty} (x-x_0)\psi(x)^*\psi'(x)\,dx.

Let

I=∫−∞∞(x−x0)ψ∗ψ′ dx.I = \int_{-\infty}^{\infty} (x-x_0)\psi^*\psi'\,dx.

Then

I+I∗=∫−∞∞(x−x0)ddx∣ψ∣2 dx=[(x−x0)∣ψ(x)∣2]−∞∞−∫−∞∞∣ψ(x)∣2 dx.\begin{aligned} I+I^* &= \int_{-\infty}^{\infty} (x-x_0) \frac{d}{dx}|\psi|^2\,dx \\ &= \left[ (x-x_0)|\psi(x)|^2 \right]_{-\infty}^{\infty} \\ &\quad- \int_{-\infty}^{\infty}|\psi(x)|^2\,dx. \end{aligned}

For a state with a vanishing boundary term, normalization gives

I+I∗=−1,I+I^*=-1,

so

Re⁡I=−12.\operatorname{Re}I=-\frac12.

Since ⟨f∣g⟩=−iℏI\langle f|g\rangle=-i\hbar I,

Im⁡⟨f∣g⟩=ℏ2.\operatorname{Im}\langle f|g\rangle = \frac\hbar2.

Therefore

∣⟨f∣g⟩∣2≥ℏ24,|\langle f|g\rangle|^2 \ge \frac{\hbar^2}{4},

and Cauchy–Schwarz yields

Δψx Δψp≥ℏ2.\Delta_\psi x\,\Delta_\psi p \ge \frac\hbar2.

The real part of ⟨f∣g⟩\langle f|g\rangle is the symmetrized covariance Cψ(x,p)C_\psi(x,p). Retaining it gives the stronger determinant relation.

Under the chosen transform, multiplication by xx in position space corresponds to differentiation in momentum space, while differentiation in position space corresponds to multiplication by pp:

xψ⟷iℏdϕdp,x\psi \quad\longleftrightarrow\quad i\hbar\frac{d\phi}{dp},

and

−iℏdψdx⟷pϕ.-i\hbar\frac{d\psi}{dx} \quad\longleftrightarrow\quad p\phi.

Localization of ψ\psi requires a broad superposition of Fourier components. Conversely, concentrating ϕ\phi near one momentum makes the position-space phase vary almost like a plane wave over a long region.

This is not merely a qualitative analogy. If the wave-number transform is written using k=p/ℏk=p/\hbar, the variance theorem is

Δx Δk≥12.\Delta x\,\Delta k \ge \frac12.

Multiplying by ℏ\hbar gives the physical momentum relation.

Reciprocal Gaussian widths in position and momentum space

Two Gaussian states illustrate Fourier scaling. The solid state is narrower in position and broader in momentum; the dashed state has the reciprocal pattern. Translating either curve changes its mean but not its width.

The general transform machinery is developed in Fourier Transform and Wave Packets.

Let a>0a>0 and define a rescaled normalized state

ψa(x)=1aψ ⁣(xa).\psi_a(x) = \frac1{\sqrt a} \psi\!\left(\frac{x}{a}\right).

Its momentum wavefunction is

ϕa(p)=a ϕ(ap).\phi_a(p) = \sqrt a\,\phi(ap).

If the original means vanish, direct substitution gives

Δpsiax=a Δψx,\Delta_{psi_a}x = a\,\Delta_\psi x,

and

Δpsiap=1a Δψp.\Delta_{psi_a}p = \frac1a\,\Delta_\psi p.

Thus

Δpsiax Δpsiap=Δψx Δψp.\Delta_{psi_a}x\, \Delta_{psi_a}p = \Delta_\psi x\, \Delta_\psi p.

Narrowing the position profile by a factor a<1a<1 broadens the momentum profile by exactly 1/a1/a. Scaling alone does not guarantee saturation; it preserves whatever uncertainty product the original shape had.

For nonzero variances, Robertson equality requires the centered fluctuation vectors to be proportional with a purely imaginary coefficient. Write

(x−x0)ψ=−iλ(p−p0)ψ,λ>0.(x-x_0)\psi = -i\lambda (p-p_0)\psi, \qquad \lambda>0.

Using p=−iℏd/dxp=-i\hbar d/dx gives the first-order equation

dψdx=[−x−x0λℏ+ip0ℏ]ψ.\frac{d\psi}{dx} = \left[ -\frac{x-x_0}{\lambda\hbar} + \frac{ip_0}{\hbar} \right] \psi.

Its normalizable solutions are Gaussians. Writing

λ=2σx2ℏ,\lambda = \frac{2\sigma_x^2}{\hbar},

one obtains

ψ(x)=eiχ(2πσx2)1/4×exp⁡ ⁣[−(x−x0)24σx2]×exp⁡ ⁣[ip0(x−x0)ℏ],\begin{aligned} \psi(x) &= \frac{e^{i\chi}} {(2\pi\sigma_x^2)^{1/4}} \\ &\quad\times \exp\!\left[ -\frac{(x-x_0)^2}{4\sigma_x^2} \right] \\ &\quad\times \exp\!\left[ \frac{ip_0(x-x_0)}{\hbar} \right], \end{aligned}

where χ\chi is an irrelevant global phase.

The probability density is

∣ψ(x)∣2=12πσx2exp⁡ ⁣[−(x−x0)22σx2],|\psi(x)|^2 = \frac1{\sqrt{2\pi\sigma_x^2}} \exp\!\left[ -\frac{(x-x_0)^2}{2\sigma_x^2} \right],

so

Δx=σx.\Delta x=\sigma_x.

Fourier transformation gives a Gaussian centered at p0p_0 with

Δp=ℏ2σx.\Delta p = \frac\hbar{2\sigma_x}.

Hence

Δx Δp=ℏ2.\Delta x\,\Delta p = \frac\hbar2.

Translations x0x_0, boosts p0p_0, and a global phase do not affect the uncertainty product. Up to those changes and the width parameter, the uncorrelated Gaussian is the normalized equality state on the line.

The packet’s free evolution and its relation to coherent states belong to Minimum-Uncertainty Wave Packets and Gaussian Wave Packets.

Correlated Gaussians and the Stronger Relation

Section titled “Correlated Gaussians and the Stronger Relation”

Consider the chirped Gaussian

ψη(x)=1(2πσx2)1/4×exp⁡ ⁣[−1−iη4σx2(x−x0)2+ip0(x−x0)ℏ],\begin{aligned} \psi_\eta(x) &= \frac1{(2\pi\sigma_x^2)^{1/4}} \\ &\quad\times \exp\!\left[ \begin{aligned} &-\frac{1-i\eta}{4\sigma_x^2}(x-x_0)^2 \\ &+\frac{ip_0(x-x_0)}{\hbar} \end{aligned} \right], \end{aligned}

where η∈R\eta\in\mathbb R. Its position density is unchanged, but the quadratic phase correlates position and momentum. Direct differentiation gives

(p−p0)ψη=ℏ(η+i)2σx2(x−x0)ψη.(p-p_0)\psi_\eta = \frac{\hbar(\eta+i)}{2\sigma_x^2} (x-x_0)\psi_\eta.

Therefore

(Δx)2=σx2,(\Delta x)^2=\sigma_x^2, (Δp)2=ℏ24σx2(1+η2),(\Delta p)^2 = \frac{\hbar^2}{4\sigma_x^2} (1+\eta^2),

and

C(x,p)=ηℏ2.C(x,p)=\frac{\eta\hbar}{2}.

These quantities satisfy

(Δx)2(Δp)2−C(x,p)2=ℏ24.(\Delta x)^2(\Delta p)^2 - C(x,p)^2 = \frac{\hbar^2}{4}.

Thus every ψη\psi_\eta saturates Robertson–Schrödinger, while only η=0\eta=0 saturates the simpler product relation. A state can be a minimum uncertainty state for the determinant bound without minimizing Δx Δp\Delta x\,\Delta p itself.

A small Δx\Delta x means that repeated ideal position measurements on identically prepared systems have a distribution concentrated near x0x_0 in the root-mean-square sense. It does not mean that the wavefunction has compact support or that every outcome lies in an interval of width 2Δx2\Delta x.

The inequality gives

Δp≥ℏ2Δx.\Delta p \ge \frac\hbar{2\Delta x}.

This concerns spread about p0p_0, not the size of p0p_0. A packet can have a large mean momentum and a small momentum spread, or zero mean momentum and a large spread.

For a free particle of mass mm,

⟨T⟩=⟨p2⟩2m=p02+(Δp)22m.\langle T\rangle = \frac{\langle p^2\rangle}{2m} = \frac{p_0^2+(\Delta p)^2}{2m}.

Consequently,

⟨T⟩≥p022m+ℏ28m(Δx)2.\langle T\rangle \ge \frac{p_0^2}{2m} + \frac{\hbar^2}{8m(\Delta x)^2}.

Localization therefore carries a kinetic-energy cost. For an electron with p0=0p_0=0 and Δx=1 A˚\Delta x=1\,\text{Å}, the lower-bound contribution is about 0.95 eV0.95\,\mathrm{eV}.

Idealized Sharp States Are Not Counterexamples

Section titled “Idealized Sharp States Are Not Counterexamples”

An ideal plane wave

ψp(x)∝eipx/ℏ\psi_p(x) \propto e^{ipx/\hbar}

has a sharp generalized momentum but is not square integrable on R\mathbb R. It has no finite position variance. Normalized packets can approach a sharp momentum distribution only by spreading farther in position.

An ideal position eigenket has wavefunction proportional to

δ(x−x0).\delta(x-x_0).

It is a distribution rather than a vector in L2(R)L^2(\mathbb R). Its Fourier amplitude has constant magnitude, so it does not define a normalizable finite-variance momentum distribution.

Some normalized states have heavy tails and infinite Δx\Delta x or Δp\Delta p. The variance product is then not a useful finite diagnostic. This does not violate the theorem; it lies outside the finite-moment setting in which the numerical product is defined.

For Cartesian components,

[xi,pj]=iℏδijI.[x_i,p_j] = i\hbar\delta_{ij}I.

Therefore

Δxi Δpi≥ℏ2\Delta x_i\,\Delta p_i \ge \frac\hbar2

for each matched component. Distinct components commute:

[xi,pj]=0(i≠j),[x_i,p_j]=0 \qquad(i\ne j),

so this commutator supplies no positive lower bound for their product.

For real vectors u\mathbf u and v\mathbf v, define

Xu=u⋅x,Pv=v⋅p.X_{\mathbf u} = \mathbf u\cdot\mathbf x, \qquad P_{\mathbf v} = \mathbf v\cdot\mathbf p.

Then

[Xu,Pv]=iℏ(u⋅v)I,[X_{\mathbf u},P_{\mathbf v}] = i\hbar (\mathbf u\cdot\mathbf v)I,

and

ΔXu ΔPv≥ℏ2∣u⋅v∣.\Delta X_{\mathbf u}\, \Delta P_{\mathbf v} \ge \frac\hbar2 |\mathbf u\cdot\mathbf v|.

The bound depends only on the overlap of the two directions.

Preparation Uncertainty Is Not Error–Disturbance

Section titled “Preparation Uncertainty Is Not Error–Disturbance”

The theorem can be tested by preparing many copies of ρ\rho. Position can be measured on one subensemble and momentum on another. Their empirical widths, after correcting for known detector effects, estimate Δx\Delta x and Δp\Delta p.

No first measurement is required to disturb a second measurement in this protocol. A sequential error–disturbance experiment asks different questions about an apparatus, its resolution, and its state-update map.

Heisenberg’s microscope was historically important for motivating operational limits, but the Kennard–Robertson variance inequality is a theorem about prepared-state distributions. The historical development belongs to Uncertainty: Historical Origin.

Position and momentum are unbounded. A sufficient whole-line setting for the vector proof requires

xψ∈L2(R),x\psi\in L^2(\mathbb R), ψ′∈L2(R),\psi'\in L^2(\mathbb R),

and a representative for which the integration-by-parts boundary term

[(x−x0)∣ψ(x)∣2]−∞∞\left[ (x-x_0)|\psi(x)|^2 \right]_{-\infty}^{\infty}

vanishes. Schwartz wavefunctions satisfy these conditions comfortably.

The direct vector proof needs ψ\psi in the common form domain of xx and pp. Writing

⟨ψ∣[x,p]∣ψ⟩\langle\psi|[x,p]|\psi\rangle

as an ordinary operator expectation can require stronger product-domain conditions. The weak overlap proof avoids assuming that both xpψxp\psi and pxψpx\psi exist as Hilbert-space vectors.

Boundary conditions can alter the story:

  • on a finite interval, self-adjoint momentum realizations depend on boundary conditions, and multiplication by xx may not preserve their domains;
  • on a circle, a globally defined angle observable is not an ordinary Cartesian position operator;
  • on a lattice or finite cyclic space, position and quasimomentum have discrete or periodic spectra and obey modified uncertainty relations;
  • with gauge fields, canonical momentum and kinetic momentum are different observables.

The formula Δx Δp≥ℏ/2\Delta x\,\Delta p\ge\hbar/2 should therefore be attached to the canonical pair on the line, not exported unchanged to every coordinate called “position.”

When using the relation:

  1. Confirm that xx and pp are the canonical operators for the stated configuration space.
  2. Normalize the state and verify that both second moments are finite.
  3. Keep the means x0x_0 and p0p_0 separate from the spreads.
  4. Use one Fourier convention consistently.
  5. Check the dimensions: Δx Δp\Delta x\,\Delta p has units of action.
  6. Inspect boundary terms or use the domain-safe weak form.
  7. Include covariance when discussing equality or chirped states.
  8. Do not infer detector error or sequential disturbance without a measurement model.
  9. Test limiting cases such as broad packets, narrow packets, and Gaussian saturation.
  • “The particle has exact xx and pp, but observation hides them.” The variance theorem itself concerns state-assigned outcome distributions and makes no such hidden-value assertion.
  • “Uncertainty is caused only by the observer disturbing the particle.” The preparation inequality exists before a measurement sequence is chosen.
  • “Δx\Delta x is the resolution of the position detector.” It is the ideal Born-distribution standard deviation.
  • “Small Δx\Delta x means large ⟨p⟩\langle p\rangle.” It requires a large momentum spread, not a large mean.
  • “All Gaussians satisfy Δx Δp=ℏ/2\Delta x\,\Delta p=\hbar/2.” Quadratic-phase Gaussians generally have a larger product while saturating the covariance determinant bound.
  • “Every state saturates the relation.” Most wavefunctions lie strictly above the bound.
  • “A plane wave violates the theorem because Δp=0\Delta p=0.” It is not a normalized finite-Δx\Delta x state on the line.
  • “The theorem says the particle is somewhere inside x0±Δxx_0\pm\Delta x.” A standard deviation is not a compact support interval.
  • “The same formula applies unchanged to angle and angular momentum.” Periodic coordinates require separate domain-aware relations.
  • “Energy–time uncertainty follows by replacing xx with tt.” Time is not a universal position-like operator in ordinary quantum mechanics.

This page owns the canonical variance theorem, its Fourier and wavefunction derivations, Gaussian equality condition, covariance refinement, and line-domain caveats. Nearby pages own specialized developments:

  • Every normalized whole-line state with finite canonical variances obeys Δx Δp≥ℏ/2\Delta x\,\Delta p\ge\hbar/2.
  • The bound is state independent because [x,p]=iℏI[x,p]=i\hbar I.
  • The theorem is simultaneously an operator inequality and a Fourier width theorem.
  • Translation and boost change the means but not the variances.
  • Rescaling position by aa rescales momentum width by 1/a1/a.
  • Uncorrelated Gaussians are the normalized equality states for the product relation on the line.
  • Chirped Gaussians saturate Robertson–Schrödinger but generally not the simpler product bound.
  • Plane waves and position eigenkets are distributional idealizations, not finite-variance counterexamples.
  • Preparation spread, detector error, and measurement disturbance are distinct notions.
  • Unbounded operators, boundaries, periodic coordinates, and gauge fields require explicit domain and observable choices.
  • W. Heisenberg, “Über den anschaulichen Inhalt der quantentheoretischen Kinematik und Mechanik,” Zeitschrift für Physik 43, 172–198, 1927, doi:10.1007/BF01397280.
  • E. H. Kennard, “Zur Quantenmechanik einfacher Bewegungstypen,” Zeitschrift für Physik 44, 326–352, 1927, doi:10.1007/BF01391200.
  • H. P. Robertson, “The Uncertainty Principle,” Physical Review 34, 163–164, 1929, doi:10.1103/PhysRev.34.163.
  • E. Schrödinger, “Zum Heisenbergschen Unschärfeprinzip,” Sitzungsberichte der Preußischen Akademie der Wissenschaften, Physikalisch-mathematische Klasse, 296–303, 1930.
  • G. B. Folland and A. Sitaram, “The Uncertainty Principle: A Mathematical Survey,” Journal of Fourier Analysis and Applications 3, 207–238, 1997.
  • L. E. Ballentine, Quantum Mechanics: A Modern Development, 2nd ed., World Scientific, 2014.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • B. C. Hall, Quantum Theory for Mathematicians, Springer, 2013.
  • M. Reed and B. Simon, Methods of Modern Mathematical Physics, Vol. I: Functional Analysis, rev. ed., Academic Press, 1980.
  • P. Busch, P. Lahti, J.-P. Pellonpää, and K. Ylinen, Quantum Measurement, Springer, 2016.

Exercise 1: State-independent Robertson bound

Section titled “Exercise 1: State-independent Robertson bound”

Starting from Robertson and [x,p]=iℏI[x,p]=i\hbar I, derive the position–momentum uncertainty relation. Identify exactly where normalization is used.

Solution

Robertson gives

Δψx Δψp≥12∣⟨[x,p]⟩ψ∣.\Delta_\psi x\,\Delta_\psi p \ge \frac12 \left\lvert \langle[x,p]\rangle_\psi \right\rvert.

The canonical relation implies

⟨[x,p]⟩ψ=iℏ⟨I⟩ψ.\langle[x,p]\rangle_\psi = i\hbar\langle I\rangle_\psi.

Normalization is used in

⟨I⟩ψ=⟨ψ∣ψ⟩=1.\langle I\rangle_\psi = \langle\psi|\psi\rangle =1.

Hence

Δψx Δψp≥12∣iℏ∣=ℏ2.\Delta_\psi x\,\Delta_\psi p \ge \frac12|i\hbar| = \frac\hbar2.

Exercise 2: The integration-by-parts constant

Section titled “Exercise 2: The integration-by-parts constant”

Assume ψ\psi is normalized, differentiable, and decays sufficiently rapidly. Show that

Re⁡∫−∞∞(x−x0)ψ∗(x)ψ′(x) dx=−12.\operatorname{Re} \int_{-\infty}^{\infty} (x-x_0)\psi^*(x)\psi'(x)\,dx = -\frac12.

Explain how this fixes the constant ℏ/2\hbar/2.

Solution

Let the integral be II. Then

2Re⁡I=I+I∗=∫−∞∞(x−x0)ddx∣ψ(x)∣2 dx.\begin{aligned} 2\operatorname{Re}I &= I+I^*\\ &= \int_{-\infty}^{\infty} (x-x_0) \frac{d}{dx}|\psi(x)|^2\,dx. \end{aligned}

Integration by parts gives

2Re⁡I=[(x−x0)∣ψ(x)∣2]−∞∞−∫−∞∞∣ψ(x)∣2 dx=−1.\begin{aligned} 2\operatorname{Re}I &= \left[ (x-x_0)|\psi(x)|^2 \right]_{-\infty}^{\infty} \\ &\quad- \int_{-\infty}^{\infty}|\psi(x)|^2\,dx \\ &=-1. \end{aligned}

Thus Re⁡I=−1/2\operatorname{Re}I=-1/2. The centered position–momentum overlap is −iℏI-i\hbar I, whose imaginary part is ℏ/2\hbar/2. Cauchy–Schwarz must therefore bound its modulus by at least ℏ/2\hbar/2.

For

ψ(x)=1(2πσ2)1/4exp⁡ ⁣[−(x−x0)24σ2]×exp⁡ ⁣[ip0(x−x0)ℏ],\begin{aligned} \psi(x) &= \frac1{(2\pi\sigma^2)^{1/4}} \exp\!\left[ -\frac{(x-x_0)^2}{4\sigma^2} \right] \\ &\quad\times \exp\!\left[ \frac{ip_0(x-x_0)}{\hbar} \right], \end{aligned}

compute Δx\Delta x and Δp\Delta p without performing the full Fourier transform.

Solution

The density is a normal distribution of variance σ2\sigma^2, so

Δx=σ.\Delta x=\sigma.

Differentiate the wavefunction:

ψ′=[−x−x02σ2+ip0ℏ]ψ.\psi' = \left[ -\frac{x-x_0}{2\sigma^2} + \frac{ip_0}{\hbar} \right]\psi.

Therefore

(p−p0)ψ=iℏ(x−x0)2σ2ψ.(p-p_0)\psi = \frac{i\hbar(x-x_0)}{2\sigma^2}\psi.

Taking the norm gives

(Δp)2=ℏ24σ4⟨(x−x0)2⟩=ℏ24σ2.\begin{aligned} (\Delta p)^2 &= \frac{\hbar^2}{4\sigma^4} \langle(x-x_0)^2\rangle \\ &= \frac{\hbar^2}{4\sigma^2}. \end{aligned}

Thus Δp=ℏ/(2σ)\Delta p=\hbar/(2\sigma) and the product is ℏ/2\hbar/2.

For a>0a>0, let

ψa(x)=a−1/2ψ(x/a).\psi_a(x) = a^{-1/2}\psi(x/a).

Derive ϕa(p)=a1/2ϕ(ap)\phi_a(p)=a^{1/2}\phi(ap) and show how the two variances scale.

Solution

Substitute x=ayx=ay into the Fourier transform:

ϕa(p)=12πℏ×∫e−ipx/ℏa−1/2ψ(x/a) dx=a1/212πℏ×∫e−i(ap)y/ℏψ(y) dy=a1/2ϕ(ap).\begin{aligned} \phi_a(p) &= \frac1{\sqrt{2\pi\hbar}} \\ &\quad\times \int e^{-ipx/\hbar} a^{-1/2}\psi(x/a)\,dx \\ &= a^{1/2} \frac1{\sqrt{2\pi\hbar}} \\ &\quad\times \int e^{-i(ap)y/\hbar}\psi(y)\,dy \\ &= a^{1/2}\phi(ap). \end{aligned}

Changing variables in the second moments gives

Δpsiax=aΔψx,\Delta_{psi_a}x=a\Delta_\psi x,

and

Δpsiap=1aΔψp.\Delta_{psi_a}p=\frac1a\Delta_\psi p.

Their product is unchanged.

For the state ψη\psi_\eta defined in the text, verify

(p−p0)ψη=ℏ(η+i)2σx2(x−x0)ψη,(p-p_0)\psi_\eta = \frac{\hbar(\eta+i)}{2\sigma_x^2} (x-x_0)\psi_\eta,

then compute Δp\Delta p and C(x,p)C(x,p).

Solution

Differentiation gives

ψη′=[−1−iη2σx2(x−x0)+ip0ℏ]ψη.\psi_\eta' = \left[ -\frac{1-i\eta}{2\sigma_x^2}(x-x_0) + \frac{ip_0}{\hbar} \right] \psi_\eta.

Applying −iℏd/dx−p0-i\hbar d/dx-p_0 yields the stated relation. Its squared norm is

(Δp)2=ℏ2∣η+i∣24σx4⟨(x−x0)2⟩=ℏ2(1+η2)4σx2.\begin{aligned} (\Delta p)^2 &= \frac{\hbar^2|\eta+i|^2}{4\sigma_x^4} \langle(x-x_0)^2\rangle \\ &= \frac{\hbar^2(1+\eta^2)}{4\sigma_x^2}. \end{aligned}

The centered overlap is

⟨(x−x0)(p−p0)⟩=ℏ(η+i)2σx2×⟨(x−x0)2⟩=ℏ2(η+i).\begin{aligned} \langle(x-x_0)(p-p_0)\rangle &= \frac{\hbar(\eta+i)}{2\sigma_x^2} \\ &\quad\times \langle(x-x_0)^2\rangle \\ &= \frac\hbar2(\eta+i). \end{aligned}

Its real part is the symmetrized covariance:

C(x,p)=ηℏ2.C(x,p)=\frac{\eta\hbar}{2}.

Substitution verifies saturation of the determinant relation.

For a free particle with p0=0p_0=0, show that

⟨T⟩≥ℏ28m(Δx)2.\langle T\rangle \ge \frac{\hbar^2}{8m(\Delta x)^2}.

Estimate the bound for an electron localized to Δx=1 A˚\Delta x=1\,\text{Å}.

Solution

Since p0=0p_0=0,

⟨T⟩=(Δp)22m.\langle T\rangle = \frac{(\Delta p)^2}{2m}.

The uncertainty relation gives

(Δp)2≥ℏ24(Δx)2,(\Delta p)^2 \ge \frac{\hbar^2}{4(\Delta x)^2},

so

⟨T⟩≥ℏ28m(Δx)2.\langle T\rangle \ge \frac{\hbar^2}{8m(\Delta x)^2}.

Using me≃9.11×10−31 kgm_e\simeq9.11\times10^{-31}\,\mathrm{kg} and Δx=10−10 m\Delta x=10^{-10}\,\mathrm m gives

⟨T⟩≳1.53×10−19 J≃0.95 eV.\langle T\rangle \gtrsim 1.53\times10^{-19}\,\mathrm J \simeq0.95\,\mathrm{eV}.

Exercise 7: Directional uncertainty in three dimensions

Section titled “Exercise 7: Directional uncertainty in three dimensions”

Let u\mathbf u and v\mathbf v be unit vectors. Derive

Δ(u⋅x) Δ(v⋅p)≥ℏ2∣u⋅v∣.\Delta(\mathbf u\cdot\mathbf x)\, \Delta(\mathbf v\cdot\mathbf p) \ge \frac\hbar2|\mathbf u\cdot\mathbf v|.

What does Robertson give when the directions are orthogonal?

Solution

Using [xi,pj]=iℏδijI[x_i,p_j]=i\hbar\delta_{ij}I,

[u⋅x,v⋅p]=∑i,juivj[xi,pj]=iℏ∑iuiviI=iℏ(u⋅v)I.\begin{aligned} [\mathbf u\cdot\mathbf x, \mathbf v\cdot\mathbf p] &= \sum_{i,j}u_iv_j[x_i,p_j] \\ &= i\hbar \sum_i u_iv_i I \\ &= i\hbar(\mathbf u\cdot\mathbf v)I. \end{aligned}

Robertson gives the stated bound. If the directions are orthogonal, the commutator vanishes and this particular relation gives only the trivial lower bound zero. It does not require either variance to vanish.

Repeat the integration-by-parts step on an interval [0,L][0,L]. Show that

2Re⁡I=[(x−x0)∣ψ(x)∣2]0L−1.\begin{aligned} 2\operatorname{Re}I &= \left[ (x-x_0)|\psi(x)|^2 \right]_{0}^{L} -1. \end{aligned}

Explain why the whole-line proof cannot simply be copied to arbitrary boundary conditions.

Solution

The calculation is identical except that the endpoints are finite:

I+I∗=∫0L(x−x0)ddx∣ψ(x)∣2 dx=[(x−x0)∣ψ(x)∣2]0L−∫0L∣ψ(x)∣2 dx.\begin{aligned} I+I^* &= \int_0^L (x-x_0) \frac{d}{dx}|\psi(x)|^2\,dx \\ &= \left[ (x-x_0)|\psi(x)|^2 \right]_0^L \\ &\quad- \int_0^L|\psi(x)|^2\,dx. \end{aligned}

Normalization makes the last integral one, yielding the stated result. The endpoint contribution need not vanish for periodic or other self-adjoint boundary conditions. In addition, multiplication by xx may not preserve the domain of the chosen momentum operator. The observable domains and boundary conditions must therefore be analyzed before asserting the whole-line constant.