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Particle on a Ring

A particle on a ring is the canonical quantum system with one periodic angular coordinate. The configuration space is the circle S1S^1, not an interval with two separate ends. That single geometric fact forces integer angular momentum, periodic boundary conditions, and a spectrum symmetric under clockwise and counterclockwise circulation.

This page is the angular-systems treatment. For a more introductory route from one-dimensional boxes to periodic motion, see Particle on a Ring: First Encounter.

Let a particle of mass MM be constrained to a circle of fixed radius RR. Its position is specified by one angle,

0≤θ<2π,0\le\theta\lt2\pi,

with the identification

θ∼θ+2π.\theta\sim\theta+2\pi.

The Hilbert space is L2(S1,dθ)L^2(S^1,d\theta), with inner product

⟨ϕ∣ψ⟩=∫02πϕ∗(θ)ψ(θ) dθ.\langle \phi\vert\psi\rangle = \int_0^{2\pi} \phi^*(\theta)\psi(\theta)\,d\theta.

A scalar wavefunction must be single-valued on the circle:

ψ(θ+2π)=ψ(θ).\psi(\theta+2\pi)=\psi(\theta).

For the free second-derivative Hamiltonian, the derivative is periodic as part of the same self-adjoint domain:

ψ′(θ+2π)=ψ′(θ).\psi'(\theta+2\pi)=\psi'(\theta).

The probability density ∣ψ(θ)∣2\lvert\psi(\theta)\rvert^2 is density per unit angle. Density per unit arc length s=Rθs=R\theta differs by the factor ds=R dθds=R\,d\theta.

The moment of inertia is

I=MR2.I=MR^2.

Classically, the kinetic energy is

T=Lz22I.T=\frac{L_z^2}{2I}.

In the angle representation,

L^z=−iℏddθ,\hat L_z = -i\hbar\frac{d}{d\theta},

so the free-ring Hamiltonian is

H^=L^z22I=−ℏ22Id2dθ2.\hat H = \frac{\hat L_z^2}{2I} = - \frac{\hbar^2}{2I} \frac{d^2}{d\theta^2}.

Thus the ring is a free particle with a compact coordinate. The differential expression resembles a particle in a box, but the boundary condition is periodic rather than Dirichlet or Neumann.

Particle on a ring coordinate and quadratic angular momentum spectrum

The ring has one periodic coordinate θ\theta, and the free spectrum is quadratic in the integer angular-momentum label: Em=Bm2E_m=Bm^2 with B=ℏ2/(2I)B=\hbar^2/(2I). The states mm and −m-m are degenerate when no flux or external field selects an orientation.

The angular-momentum eigenvalue equation is

L^zu(θ)=λu(θ).\hat L_z u(\theta)=\lambda u(\theta).

Solving gives

u(θ)=Ceiλθ/ℏ.u(\theta)=Ce^{i\lambda\theta/\hbar}.

Single-valuedness requires

u(θ+2π)=u(θ),u(\theta+2\pi)=u(\theta),

so

ei2πλ/ℏ=1.e^{i2\pi\lambda/\hbar}=1.

Therefore

λ=ℏm,m∈Z.\lambda=\hbar m, \qquad m\in\mathbb Z.

The normalized eigenfunctions are

um(θ)=12πeimθ,m∈Z.u_m(\theta) = \frac{1}{\sqrt{2\pi}} e^{im\theta}, \qquad m\in\mathbb Z.

The integer mm can be positive, negative, or zero. Positive and negative values represent opposite orientations of angular momentum around the ring.

Acting with the Hamiltonian gives

H^um=ℏ2m22Ium.\hat H u_m = \frac{\hbar^2m^2}{2I}u_m.

Define

B=ℏ22I.B=\frac{\hbar^2}{2I}.

Then

Em=Bm2,m∈Z.E_m=Bm^2, \qquad m\in\mathbb Z.

The m=0m=0 level is nondegenerate. Every nonzero level is twofold degenerate:

Em=E−m,m≠0.E_m=E_{-m}, \qquad m\ne0.

This degeneracy is a time-reversal and orientation symmetry of the free ring. The two states have equal kinetic energy but opposite angular momentum:

L^zum=ℏmum,L^zu−m=−ℏmu−m.\hat L_z u_m=\hbar m u_m, \qquad \hat L_z u_{-m}=-\hbar m u_{-m}.

The ground state has E0=0E_0=0 because the constant wavefunction has no angular variation and therefore no kinetic energy. This does not contradict the harmonic oscillator’s zero-point energy; the ring has no confining angular potential with a finite-width minimum.

For the angular Schrödinger equation,

iℏ∂ψ∂t=−ℏ22I∂2ψ∂θ2,i\hbar\frac{\partial\psi}{\partial t} = - \frac{\hbar^2}{2I} \frac{\partial^2\psi}{\partial\theta^2},

the angular probability density ρ=∣ψ∣2\rho=\lvert\psi\rvert^2 obeys

∂ρ∂t+∂Jθ∂θ=0.\frac{\partial\rho}{\partial t} + \frac{\partial J_\theta}{\partial\theta} =0.

The angular probability current is

Jθ=ℏIIm⁡(ψ∗∂ψ∂θ).J_\theta = \frac{\hbar}{I} \operatorname{Im} \left( \psi^* \frac{\partial\psi}{\partial\theta} \right).

For the eigenstate umu_m,

Jθ,m=ℏm2πI.J_{\theta,m} = \frac{\hbar m}{2\pi I}.

The density of umu_m is constant, but the current is not zero unless m=0m=0. This is a useful warning: a stationary probability density does not imply the absence of probability flow.

Relation to Translations on a Compact Space

Section titled “Relation to Translations on a Compact Space”

The ring is also the periodic-box basis written geometrically. If s=Rθs=R\theta is arc length and L=2πRL=2\pi R is the circumference, then periodicity gives

km=2πmL=mR.k_m = \frac{2\pi m}{L} = \frac{m}{R}.

The tangential momentum is

pm=ℏkm=ℏmR,p_m=\hbar k_m=\frac{\hbar m}{R},

and the angular momentum is

Lz=Rpm=ℏm.L_z=Rp_m=\hbar m.

The energy

pm22M=ℏ2m22MR2=ℏ2m22I\frac{p_m^2}{2M} = \frac{\hbar^2m^2}{2MR^2} = \frac{\hbar^2m^2}{2I}

is the same spectrum written in linear or angular language. This is the simplest example of how compact configuration spaces quantize generator eigenvalues.

If the particle has charge qq, magnetic flux Φ\Phi through the ring shifts the spectrum even when the magnetic field vanishes on the ring itself. This is the ring version of the Aharonov–Bohm effect.

With a tangential vector potential representing flux Φ\Phi, minimal coupling gives

H^(Φ)=12I(−iℏddθ−qΦ2π)2.\hat H(\Phi) = \frac{1}{2I} \left( -i\hbar\frac{d}{d\theta} - \frac{q\Phi}{2\pi} \right)^2.

Define the dimensionless flux

α=qΦh.\alpha = \frac{q\Phi}{h}.

The single-valued basis umu_m remains convenient, and the energies become

Em(Φ)=ℏ22I(m−α)2.E_m(\Phi) = \frac{\hbar^2}{2I} \left( m-\alpha \right)^2.

The sign of α\alpha depends on the sign of the charge and on the chosen orientation for Φ\Phi. The invariant lesson is that flux shifts the parabola in mm and can split the m,−mm,-m degeneracy.

Equivalently, one may remove the vector potential locally and impose a twisted boundary condition. The two descriptions are related by a gauge transformation. The general rule behind this preview is Minimal Coupling in Wave Mechanics, and the full wave-mechanics phase discussion is Aharonov–Bohm Effect: First Encounter.

  • Treating θ=0\theta=0 and θ=2π\theta=2\pi as independent endpoints.
  • Allowing arbitrary real mm for an ordinary single-valued scalar wavefunction.
  • Forgetting the negative angular-momentum states.
  • Confusing the particle mass MM with the angular quantum number mm.
  • Thinking the constant m=0m=0 ground state contradicts oscillator zero-point energy.
  • Inferring zero current from a time-independent density.
  • Ignoring charge and orientation conventions when writing the flux-shifted spectrum.
  1. Normalize um(θ)=Ceimθu_m(\theta)=Ce^{im\theta} on the ring.
Solution

The normalization condition is

1=∫02π∣C∣2 dθ=2π∣C∣2.1= \int_0^{2\pi} \lvert C\rvert^2\,d\theta = 2\pi\lvert C\rvert^2.

Thus

∣C∣=12π.\lvert C\rvert=\frac{1}{\sqrt{2\pi}}.

Choosing the overall phase to be 11 gives

um(θ)=12πeimθ.u_m(\theta) = \frac{1}{\sqrt{2\pi}}e^{im\theta}.
  1. Show that periodicity forces mm to be an integer.
Solution

The eigenfunction has the form

u(θ)=Ceiλθ/ℏ.u(\theta)=Ce^{i\lambda\theta/\hbar}.

Periodic single-valuedness gives

eiλ(θ+2π)/ℏ=eiλθ/ℏ.e^{i\lambda(\theta+2\pi)/\hbar} = e^{i\lambda\theta/\hbar}.

After canceling the common factor,

ei2πλ/ℏ=1.e^{i2\pi\lambda/\hbar}=1.

Therefore λ/ℏ\lambda/\hbar is an integer. Writing λ=ℏm\lambda=\hbar m gives

m∈Z.m\in\mathbb Z.
  1. Compute the angular current in the state umu_m.
Solution

For

um(θ)=12πeimθ,u_m(\theta)=\frac{1}{\sqrt{2\pi}}e^{im\theta},

we have

∂um∂θ=imum.\frac{\partial u_m}{\partial\theta} = imu_m.

Thus

um∗∂um∂θ=im∣um∣2=im2π.u_m^* \frac{\partial u_m}{\partial\theta} = i m\lvert u_m\rvert^2 = \frac{im}{2\pi}.

The imaginary part is m/(2π)m/(2\pi), so

Jθ,m=ℏIm2π=ℏm2πI.J_{\theta,m} = \frac{\hbar}{I} \frac{m}{2\pi} = \frac{\hbar m}{2\pi I}.
  1. Which free-ring levels are degenerate?
Solution

The energy is

Em=Bm2.E_m=Bm^2.

Therefore

Em=E−m.E_m=E_{-m}.

For m≠0m\ne0, the pair mm and −m-m is twofold degenerate. The m=0m=0 level is nondegenerate because 0=−00=-0.

  1. At what dimensionless flux α\alpha are the m=0m=0 and m=1m=1 states degenerate?
Solution

The flux-shifted energies are

Em(Φ)=B(m−α)2.E_m(\Phi) = B(m-\alpha)^2.

Set E0=E1E_0=E_1:

α2=(1−α)2.\alpha^2=(1-\alpha)^2.

Expanding gives

α2=1−2α+α2,\alpha^2=1-2\alpha+\alpha^2,

so

α=12.\alpha=\frac{1}{2}.

Thus the degeneracy occurs at half a flux quantum in the chosen orientation convention.

  • D. J. Griffiths and D. F. Schroeter, Introduction to Quantum Mechanics, 3rd ed., Cambridge University Press, 2018.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • Y. Aharonov and D. Bohm, “Significance of Electromagnetic Potentials in the Quantum Theory,” Physical Review 115, 485-491, 1959.