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Common Hamiltonians

This table is a navigation layer for standard wave-mechanics Hamiltonians. It records the usual idealized form, the natural coordinates, the spectrum type, the main physical scale, and the canonical page where the model is actually derived.

The entries suppress some domain details to stay readable. Boundary conditions, self-adjoint domains, normalization conventions, and approximation assumptions belong on the linked canonical pages.

SystemHamiltonianCoordinatesSpectrum typeKey scaleCanonical page
Free particlep^2/(2m)\hat p^2/(2m)line or R3\mathbb R^3continuousmomentum pp, wavenumber kkFree Particle
Infinite square wellp^2/(2m)\hat p^2/(2m) with ψ=0\psi=0 at wallsinterval 0<x<L0\lt x\lt LdiscreteLL, ℏ2/(2mL2)\hbar^2/(2mL^2)Infinite Square Well
Finite square wellp^2/(2m)+V(x)\hat p^2/(2m)+V(x) with finite depthone-dimensional regionsdiscrete bound states plus continuumwell width, depth, decay lengthFinite Square Well
Delta potentialp^2/(2m)−gδ(x)\hat p^2/(2m)-g\delta(x)line with matching conditionone bound state plus continuum for g>0g\gt0ℏ2/(mg)\hbar^2/(mg)Delta Function Potential
Potential stepp^2/(2m)+V0Θ(x)\hat p^2/(2m)+V_0\Theta(x)two half-linescontinuous scatteringincident energy, step heightPotential Step
Rectangular barrierp^2/(2m)+V(x)\hat p^2/(2m)+V(x) with finite barrier regionthree one-dimensional regionscontinuous scattering, resonant structurebarrier width, height, decay constantRectangular Barrier Tunneling
Harmonic oscillatorp^2/(2m)+mω2x2/2\hat p^2/(2m)+m\omega^2x^2/2linediscrete equally spacedℓ=ℏ/(mω)\ell=\sqrt{\hbar/(m\omega)}, ℏω\hbar\omegaQuantum Harmonic Oscillator
Coupled oscillatorsquadratic form in coordinates and momentanormal coordinatesdiscrete normal-mode laddersnormal-mode frequenciesCoupled Oscillators
Two-level systema0I+b⋅σa_0I+\mathbf b\cdot\boldsymbol\sigmatwo-dimensional Hilbert spacetwo discrete levels∣b∣\lvert\mathbf b\rvertTwo-Level Systems
Three-dimensional boxp^2/(2m)\hat{\mathbf p}^2/(2m) with Dirichlet wallsrectangular boxdiscreteside lengths, ℏ2/(2mL2)\hbar^2/(2mL^2)Three-Dimensional Box
Central potentialp^2/(2m)+V(r)\hat{\mathbf p}^2/(2m)+V(r)spherical coordinatesmodel dependentradial scale, angular momentum barrierRadial Schrödinger Equation
Hydrogen atomp^2/(2μ)−e2/(4πϵ0r)\hat p^2/(2\mu)-e^2/(4\pi\epsilon_0r)spherical coordinatesdiscrete bound states plus continuuma0a_0, Hartree scaleHydrogen Atom
Rigid rotorL^2/(2I)\hat L^2/(2I)sphere S2S^2discrete rotational levelsII, ℏ2/(2I)\hbar^2/(2I)Rigid Rotor
Minimal electromagnetic coupling(p^−qA)2/(2m)+qΦ(\hat{\mathbf p}-q\mathbf A)^2/(2m)+q\Phichosen gauge and coordinatesfield dependentkinetic momentum, gauge-invariant fieldsMinimal Coupling
Landau levels(p^−qA)2/(2m)(\hat{\mathbf p}-q\mathbf A)^2/(2m) in uniform B\mathbf BLandau or symmetric gaugediscrete transverse levels with degeneracyℓB\ell_B, ℏωc\hbar\omega_cLandau Levels
Charged oscillator in magnetic field(p^−qA)2/(2m)+mω02r2/2(\hat{\mathbf p}-q\mathbf A)^2/(2m)+m\omega_0^2r^2/2symmetric gauge, polar coordinatesdiscrete Fock–Darwin levelsΩ\Omega, ωc\omega_cCharged Harmonic Oscillator in a Magnetic Field

The Hamiltonian alone is not the full quantum problem. The same differential expression can define different physics when the domain, boundary conditions, coordinates, or gauge choice changes. For example, p^2/(2m)\hat p^2/(2m) describes a free particle on the line, a particle in a box after boundary conditions are imposed, or angular kinetic energy after a constraint has been applied.

The spectrum column is also idealized. A finite well has discrete bound states below the continuum; a barrier has continuum scattering states but can show resonant structure; a three-dimensional Landau problem has discrete transverse Landau levels plus continuous longitudinal motion.

Use the key scale column as a first diagnostic. If a calculation has no visible length, energy, or frequency scale matching the table, check whether a parameter, boundary condition, or unit convention has been lost.

  • Treating the displayed Hamiltonian expression as complete without specifying its domain.
  • Reusing a spectrum after changing boundary conditions.
  • Confusing canonical momentum with kinetic momentum in electromagnetic fields.
  • Forgetting reduced mass in two-body problems such as hydrogen.
  • Treating a reference table as a derivation substitute.
  • Comparing formulas from different unit systems without checking which constants have been set to one.
  • D. J. Griffiths and D. F. Schroeter, Introduction to Quantum Mechanics, 3rd ed., Cambridge University Press, 2018.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • C. Cohen-Tannoudji, B. Diu, and F. Laloë, Quantum Mechanics, Wiley, 1977.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.