Angular Momentum Algebra
Formula
Section titled “Formula”Angular-momentum components satisfy
Equivalently,
Define the Casimir operator
It commutes with every component:
The standard simultaneous eigenstates obey
The allowed labels are
For fixed , the multiplet contains states.
At a Glance
Section titled “At a Glance”| Quantity | Formula |
|---|---|
| Component algebra | |
| Casimir | |
| Casimir commutator | |
| Magnitude eigenvalue | |
| Chosen-component eigenvalue | |
| Ladder definitions | |
| Ladder commutator | |
| Ladder action | |
| Multiplet dimension | |
| Rotation |
Meaning
Section titled “Meaning”The operators are generators of rotations. Their noncommutativity mirrors the noncommutativity of rotations about different axes. The same algebra is realized by:
- orbital angular momentum ;
- intrinsic spin ;
- total angular momentum ;
- sums of independent angular momenta.
Sharing the algebra does not make these realizations physically identical. Orbital angular momentum acts on spatial wavefunctions, spin acts on internal degrees of freedom, and total angular momentum combines several contributions.
Casimir and Compatible Labels
Section titled “Casimir and Compatible Labels”Because
states can be labeled simultaneously by and . In contrast,
is generally nonzero, so and cannot generally be sharp together.
The physical magnitude associated with a multiplet is
not . The projection on the chosen axis is .
The choice of is conventional. For any unit vector , the component
has eigenvalues within the same representation.
Ladder Operators
Section titled “Ladder Operators”Define
Then
With normalized basis states and the standard phase choice,
Equivalently,
At the endpoints,
The ladder operators change but preserve .
Product Identities
Section titled “Product Identities”The useful factorizations are
They give the ladder-state norms:
Positivity and termination of these norms produce the finite range .
Component Matrix Elements
Section titled “Component Matrix Elements”Recover the Cartesian components from
The nonzero matrix elements in a fixed- basis are
These formulas construct the matrices for any finite representation.
Spin-One Example
Section titled “Spin-One Example”Order the basis as
Then
The matrices satisfy
Changing the basis order changes the displayed matrices but not the algebra.
Expectations in an Angular-Momentum Eigenstate
Section titled “Expectations in an Angular-Momentum Eigenstate”In ,
Thus
while
The Robertson relation gives
For the extremal states , this bound is saturated.
Rotation Operator
Section titled “Rotation Operator”A rotation by angle about the unit vector is represented by
For a rotation about ,
The sign shown is the active-state convention. Passive coordinate rotations may be written with the opposite sign; operators, states, and coordinates must be transformed consistently.
Dimensionless Generators
Section titled “Dimensionless Generators”Some mathematical and quantum-information sources define
Then
The operators are dimensionless. Mixing their commutator with the dimensionful eigenvalue formulas introduces incorrect powers of .
Orbital Angular Momentum
Section titled “Orbital Angular Momentum”For a spinless particle in three-dimensional Cartesian space,
In position representation,
Orbital angular momentum has
with
Only integer occurs for ordinary single-valued scalar wavefunctions on three-dimensional space. Monopoles, anyonic settings, or altered configuration spaces require separate treatments.
The position-space angular functions are spherical harmonics:
Spin and Pauli Conventions
Section titled “Spin and Pauli Conventions”Intrinsic spin obeys the same algebra. For spin one-half,
so
whereas
The eigenvalues of are , while those of are . Pauli matrices are dimensionless; physical spin operators carry angular-momentum units.
Half-integer labels are representations of and projective representations of . Single-valued ordinary representations of alone have integer . This is why orbital scalar wavefunctions use integer , while spinors can carry half-integer spin.
Total Angular Momentum
Section titled “Total Angular Momentum”If two independent angular momenta commute across subsystems,
then
satisfies the same angular-momentum algebra.
The allowed total labels are
The transformation between uncoupled and coupled bases is given by Clebsch–Gordan coefficients. Their phases require a stated convention.
Symmetry and Conservation
Section titled “Symmetry and Conservation”If a Hamiltonian is fully rotationally invariant,
for all three components. Then
as well, and the energy eigenspaces can be organized into angular-momentum multiplets.
Axial symmetry may preserve only one component, commonly
It does not imply full rotational invariance or degeneracy across all values.
Symbols
Section titled “Symbols”| Symbol | Meaning | Units or range |
|---|---|---|
| Angular-momentum operator vector | angular momentum | |
| Casimir operator | angular momentum squared | |
| Total-angular-momentum quantum number | ||
| Projection quantum number | ||
| Raising and lowering operators | angular momentum | |
| Levi-Civita symbol | dimensionless | |
| Orbital angular momentum | angular momentum | |
| Spin angular momentum | angular momentum | |
| Pauli matrix | dimensionless | |
| Rotation operator | dimensionless unitary |
The letter can denote either a quantum number or, in unrelated contexts, a current density. The bra–ket label and angular-momentum context distinguish the uses.
Units and Dimensions
Section titled “Units and Dimensions”Each has angular-momentum units:
Consequently,
The labels , , Levi-Civita symbol, Pauli matrices, and rotation angle are dimensionless.
Assumptions
Section titled “Assumptions”- The operators generate rotations and obey the standard dimensionful algebra.
- The representation is unitary and the angular-momentum operators are self-adjoint.
- States are normalized simultaneous eigenstates of and the chosen component.
- Ladder-state phases use the standard Condon–Shortley-compatible convention.
- Tensor-product angular momenta act on independent factors when the addition formulas are used.
- Orbital integer restrictions assume ordinary scalar wavefunctions and standard spatial topology.
Validity and Limitations
Section titled “Validity and Limitations”The algebra applies to orbital, spin, and total angular momentum, but specific realization-dependent statements do not automatically transfer:
- describes orbital, not intrinsic, angular momentum.
- Integer for ordinary orbital motion does not prohibit half-integer spin.
- Pauli matrices are normalized differently from physical spin operators.
- Full degeneracy requires rotational invariance of the Hamiltonian, not merely the algebra.
- Coupling coefficients and spherical harmonics depend on phase conventions.
- Effective pseudospin may obey the algebra without representing literal mechanical angular momentum.
Calculation Checks
Section titled “Calculation Checks”- The number of states in a multiplet must be .
- changes in integer steps and never exceeds .
- must annihilate the top state and the bottom state.
- in an orthonormal basis.
- The Casimir matrix must equal within one irreducible multiplet.
- Component matrices must satisfy the defining commutators.
- and are dimensionless; operator eigenvalues carry .
- Spin-one-half matrices must distinguish from .
- A rotation about should give phase under the displayed active convention.
Minimal Ladder Check
Section titled “Minimal Ladder Check”For and ,
Therefore
Applying once more gives zero because the state has reached .
Derivation and Canonical Home
Section titled “Derivation and Canonical Home”Angular Momentum Algebra owns the rotation-generator interpretation and Casimir structure. Eigenvalues of J² and Jz derives the allowed labels, and Ladder Operators derives the normalized actions.
SU(2) owns the group-theoretic representation structure.
Worked Examples
Section titled “Worked Examples”- Orbital Angular Momentum
- Spin as Intrinsic Angular Momentum
- Total Angular Momentum
- Spherical Harmonics
- Angular-Momentum Problems
Common Mistakes
Section titled “Common Mistakes”- Using instead of for the magnitude.
- Confusing the quantum numbers and .
- Assuming , , and can all be sharp.
- Forgetting the factor of in ladder actions.
- Reversing the signs in .
- Applying a ladder operator outside the allowed range.
- Assuming changes rather than .
- Confusing with .
- Applying integer orbital restrictions to intrinsic spin.
- Mixing basis order or phase conventions when copying matrices or Clebsch–Gordan coefficients.
- Inferring full rotational symmetry from conservation of only .
Related Formulas
Section titled “Related Formulas”- Ladder-Operator Action
- Spin-Half Matrices
- Addition of Angular Momentum
- Wigner–Eckart Theorem
- Pauli-Matrix Table
- Spin and Pauli-Matrix Conventions
- Commutator Table
References
Section titled “References”- A. R. Edmonds, Angular Momentum in Quantum Mechanics, Princeton University Press, 1957.
- J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020, chs. 3 and 4.
- R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994, chs. 12 and 14.
- D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum, World Scientific, 1988.