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Spin Operator

The spin operator is written S\mathbf S or by components Sx,Sy,SzS_x,S_y,S_z. It represents intrinsic angular momentum, not literal rotation of a small extended body.

Spin components obey the same angular momentum algebra as other rotation generators:

[Si,Sj]=iℏ∑kϵijkSk.[S_i,S_j] = i\hbar\sum_k\epsilon_{ijk}S_k.

For spin-1/21/2 systems, the physical spin operators are related to Pauli matrices by

Si=ℏ2σi.S_i=\frac{\hbar}{2}\sigma_i.

Thus the SzS_z eigenvalues for a spin-1/21/2 particle are ±ℏ/2\pm\hbar/2, while the corresponding σz\sigma_z eigenvalues are ±1\pm1.

Spin operators act on an internal finite-dimensional Hilbert space for a fixed spin. A spin-ss irreducible representation has dimension 2s+12s+1 and basis states usually written ∣s,m⟩\lvert s,m\rangle.

The operator S\mathbf S has units of angular momentum. Pauli matrices σi\sigma_i are dimensionless, so the factor ℏ/2\hbar/2 is not optional when the physical spin observable is meant.

  • SiS_i: spin component operator.
  • S±=Sx±iSyS_\pm=S_x\pm iS_y: spin raising and lowering operators.
  • σ\boldsymbol\sigma: Pauli-matrix vector for spin-1/21/2 or two-level notation.
  • J=L+S\mathbf J=\mathbf L+\mathbf S: total angular momentum when orbital and spin parts are both present.
  • Do not use σi\sigma_i and SiS_i interchangeably without the factor ℏ/2\hbar/2.
  • The SzS_z basis is a spin basis, not automatically the Hamiltonian eigenbasis.
  • SS may also mean action, entropy, or scattering matrix; typography and context decide.
  • Spin and orbital angular momentum share an algebra but have different physical origins.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • J. J. Sakurai, Advanced Quantum Mechanics, Addison-Wesley, 1967.