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Parity Operator

For a spinless wavefunction, parity acts by spatial inversion:

(Pψ)(r)=ψ(−r).(\mathsf P\psi)(\mathbf r) = \psi(-\mathbf r).

It satisfies

P2=I,P†=P,\mathsf P^2=I, \qquad \mathsf P^\dagger=\mathsf P,

so its eigenvalues are

π=±1.\pi=\pm1.

On position and momentum operators,

PrP−1=−r,PpP−1=−p.\mathsf P\mathbf r\mathsf P^{-1} = -\mathbf r, \qquad \mathsf P\mathbf p\mathsf P^{-1} = -\mathbf p.
  • The displayed action is for spinless scalar wavefunctions.
  • Internal degrees of freedom may carry additional parity action.
  • Parity is conserved only when [P,H]=0[\mathsf P,H]=0.
  • The spatial inversion operation is meaningful for the system’s configuration space.
  • Assuming every Hamiltonian has parity symmetry.
  • Confusing parity eigenvalue with energy sign.
  • Forgetting internal parity factors for spinor, molecular, or field-like systems.
  • Using parity language in a coordinate system where inversion has not been defined.
  • E. P. Wigner, Group Theory and Its Application to the Quantum Mechanics of Atomic Spectra, Academic Press, 1959.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.