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Symmetry Constraints on Hamiltonians

Symmetry is a filter on Hamiltonians. Instead of writing every operator allowed by dimension or convenience, one writes only terms compatible with the stated symmetries.

The basic criterion is:

SHS−1=H.SHS^{-1}=H.

For a unitary symmetry UU, this is UHU†=HUHU^\dagger=H. For a continuous unitary symmetry generated by GG, the infinitesimal condition is

[G,H]=0.[G,H]=0.

To constrain a Hamiltonian by symmetry:

  1. Choose the Hilbert space and degrees of freedom.
  2. State how the symmetry acts on states and operators.
  3. Write a general Hamiltonian in the relevant operator basis.
  4. Impose SHS−1=HSHS^{-1}=H for each symmetry.
  5. Remove terms whose coefficients must vanish or combine terms whose coefficients must be equal.
  6. Interpret the remaining parameters physically.

The power of the method is that it works before solving the spectrum.

Every Hermitian Hamiltonian for a two-level system can be written

H=aI+b⋅σ,H=aI+\mathbf b\cdot\boldsymbol\sigma,

with real aa and real vector b\mathbf b. If there is no external vector selecting a direction and the Hamiltonian must be invariant under all spin rotations, then the vector term is forbidden:

H=aI.H=aI.

If an external magnetic field B\mathbf B is present, a term

H=−γ B⋅SH=-\gamma\,\mathbf B\cdot\mathbf S

is allowed because B\mathbf B supplies a physical direction. If B\mathbf B is fixed along zz, the Hamiltonian no longer has full rotational symmetry; it retains rotations about the zz axis.

For

H=p22m+V(x),H=\frac{p^2}{2m}+V(x),

parity acts as

PxP−1=−x,PpP−1=−p.PxP^{-1}=-x, \qquad PpP^{-1}=-p.

The kinetic term is invariant. The potential is invariant only when

V(−x)=V(x).V(-x)=V(x).

Thus parity symmetry constrains the potential to be even.

Spatial translations are generated by momentum:

U(a)=e−iaP/ℏ.U(a)=e^{-iaP/\hbar}.

For a Hamiltonian

H=P22m+V(X),H=\frac{P^2}{2m}+V(X),

translation invariance requires

[P,H]=0.[P,H]=0.

Since

[P,V(X)]=−iℏV′(X),[P,V(X)]=-i\hbar V'(X),

the potential must be constant on the translated region. This is why the free particle is translation invariant and a generic potential is not. The focused version of this test is Translation-Invariant Hamiltonians.

For a particle in three dimensions,

H=p22m+V(r),r=∣r∣,H=\frac{\mathbf p^2}{2m}+V(r), \qquad r=\lvert\mathbf r\rvert,

the Hamiltonian is rotationally invariant. Therefore

[H,Li]=0[H,L_i]=0

for each component of orbital angular momentum. Energy eigenstates can be organized using angular momentum quantum numbers, even when the radial equation is still nontrivial.

Adding a small term can break a symmetry and split degeneracies. For example,

H=aI+bzσzH=aI+b_z\sigma_z

selects the zz direction. It commutes with σz\sigma_z but not with σx\sigma_x or σy\sigma_y. The symmetry has been reduced from full spin rotation to rotations about the zz axis.

This is not a failure of symmetry reasoning. It is one of its main uses: identifying what a perturbation breaks and which quantum numbers remain good.

  • Imposing symmetry on a state when the question is about symmetry of the Hamiltonian.
  • Forgetting to transform external fields or parameters when deciding whether a term is invariant.
  • Treating full rotational invariance and axial symmetry as the same thing.
  • Assuming a conserved quantity survives after adding a symmetry-breaking perturbation.
  • Calling a Hamiltonian “generic” while silently imposing a symmetry.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • H. F. Jones, Groups, Representations and Physics, 2nd ed., CRC Press, 1998.
  • M. Tinkham, Group Theory and Quantum Mechanics, Dover, 2003.
  1. Which terms in H=aI+bxσx+byσy+bzσzH=aI+b_x\sigma_x+b_y\sigma_y+b_z\sigma_z commute with σz\sigma_z?
Solution

The terms aIaI and bzσzb_z\sigma_z commute with σz\sigma_z. The Pauli commutators give

[σz,σx]=2iσy,[σz,σy]=−2iσx,[\sigma_z,\sigma_x]=2i\sigma_y, \qquad [\sigma_z,\sigma_y]=-2i\sigma_x,

so nonzero bxb_x or byb_y breaks the symmetry generated by σz\sigma_z.

  1. Let H=p2/(2m)+V(x)H=p^2/(2m)+V(x) and suppose [P,H]=0[P,H]=0. What does this imply about V(x)V(x) on a connected interval?
Solution

Since [P,p2/(2m)]=0[P,p^2/(2m)]=0 and [P,V(X)]=−iℏV′(X)[P,V(X)]=-i\hbar V'(X), the condition [P,H]=0[P,H]=0 implies V′(X)=0V'(X)=0 as an operator on the interval. Thus V(x)V(x) is constant there.