Symmetry Constraints on Hamiltonians
Symmetry is a filter on Hamiltonians. Instead of writing every operator allowed by dimension or convenience, one writes only terms compatible with the stated symmetries.
The basic criterion is:
For a unitary symmetry , this is . For a continuous unitary symmetry generated by , the infinitesimal condition is
The Working Algorithm
Section titled “The Working Algorithm”To constrain a Hamiltonian by symmetry:
- Choose the Hilbert space and degrees of freedom.
- State how the symmetry acts on states and operators.
- Write a general Hamiltonian in the relevant operator basis.
- Impose for each symmetry.
- Remove terms whose coefficients must vanish or combine terms whose coefficients must be equal.
- Interpret the remaining parameters physically.
The power of the method is that it works before solving the spectrum.
Spin-1/2 Example
Section titled “Spin-1/2 Example”Every Hermitian Hamiltonian for a two-level system can be written
with real and real vector . If there is no external vector selecting a direction and the Hamiltonian must be invariant under all spin rotations, then the vector term is forbidden:
If an external magnetic field is present, a term
is allowed because supplies a physical direction. If is fixed along , the Hamiltonian no longer has full rotational symmetry; it retains rotations about the axis.
Parity in One Dimension
Section titled “Parity in One Dimension”For
parity acts as
The kinetic term is invariant. The potential is invariant only when
Thus parity symmetry constrains the potential to be even.
Translation Invariance
Section titled “Translation Invariance”Spatial translations are generated by momentum:
For a Hamiltonian
translation invariance requires
Since
the potential must be constant on the translated region. This is why the free particle is translation invariant and a generic potential is not. The focused version of this test is Translation-Invariant Hamiltonians.
Central Potentials
Section titled “Central Potentials”For a particle in three dimensions,
the Hamiltonian is rotationally invariant. Therefore
for each component of orbital angular momentum. Energy eigenstates can be organized using angular momentum quantum numbers, even when the radial equation is still nontrivial.
Symmetry Breaking Terms
Section titled “Symmetry Breaking Terms”Adding a small term can break a symmetry and split degeneracies. For example,
selects the direction. It commutes with but not with or . The symmetry has been reduced from full spin rotation to rotations about the axis.
This is not a failure of symmetry reasoning. It is one of its main uses: identifying what a perturbation breaks and which quantum numbers remain good.
Common Mistakes
Section titled “Common Mistakes”- Imposing symmetry on a state when the question is about symmetry of the Hamiltonian.
- Forgetting to transform external fields or parameters when deciding whether a term is invariant.
- Treating full rotational invariance and axial symmetry as the same thing.
- Assuming a conserved quantity survives after adding a symmetry-breaking perturbation.
- Calling a Hamiltonian “generic” while silently imposing a symmetry.
Cross-Links
Section titled “Cross-Links”- Why Symmetry Matters
- Quantum Symmetries
- States, Observables, and Hamiltonians
- Symmetry Groups and Representations
- Translation-Invariant Hamiltonians
- Discrete Symmetries in Hamiltonians
- Degeneracy and Multiplets
- Unitary Symmetries
- Quantum Noether Principle
- Constants of Motion
- Exact Symmetry
- Explicit Symmetry Breaking
- Approximate Symmetry
- Accidental Symmetry
- Commutators
- Pauli Matrices
- Commutator Table
- Free Particle
References
Section titled “References”- J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
- R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
- H. F. Jones, Groups, Representations and Physics, 2nd ed., CRC Press, 1998.
- M. Tinkham, Group Theory and Quantum Mechanics, Dover, 2003.
Exercises
Section titled “Exercises”- Which terms in commute with ?
Solution
The terms and commute with . The Pauli commutators give
so nonzero or breaks the symmetry generated by .
- Let and suppose . What does this imply about on a connected interval?
Solution
Since and , the condition implies as an operator on the interval. Thus is constant there.