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Ehrenfest Theorem Formulas

ddt⟨A⟩=iℏ⟨[H,A]⟩+⟨∂A∂t⟩.\frac{d}{dt}\langle A\rangle =\frac{i}{\hbar}\langle[H,A]\rangle +\left\langle\frac{\partial A}{\partial t}\right\rangle.

For H=p2/(2m)+V(x)H=p^2/(2m)+V(x),

ddt⟨x⟩=⟨p⟩m,ddt⟨p⟩=−⟨V′(x)⟩,\frac{d}{dt}\langle x\rangle=\frac{\langle p\rangle}{m}, \qquad \frac{d}{dt}\langle p\rangle=-\langle V'(x)\rangle,

so

md2dt2⟨x⟩=−⟨V′(x)⟩.m\frac{d^2}{dt^2}\langle x\rangle=-\langle V'(x)\rangle.

For q=⟨x⟩q=\langle x\rangle and variance σx2\sigma_x^2,

⟨V′(x)⟩=V′(q)+12V′′′(q)σx2+⋯ .\langle V'(x)\rangle =V'(q)+\frac12V'''(q)\sigma_x^2+\cdots.
  • Schrödinger and Heisenberg pictures give the same expectation-value law.
  • The explicit partial derivative is included when AA depends on time.
  • States and operator products must lie in domains that justify the commutator and differentiation steps.
SymbolMeaning
qqmean position
σx2\sigma_x^2position variance
V′(x)V'(x)force-gradient expression; force is −V′(x)-V'(x)
[H,A][H,A]commutator HA−AHHA-AH
  • In general ⟨V′(x)⟩≠V′(⟨x⟩)\langle V'(x)\rangle\ne V'(\langle x\rangle).
  • Exact closure of the first moments occurs for potentials at most quadratic.
  • Correct mean motion does not prevent wave-packet spreading or splitting.
  • Ehrenfest’s theorem does not by itself derive definite trajectories, decoherence, or the full classical limit.
  • A broad or multimodal state can make its mean a poor description of any likely measurement result.

The derivation, closure conditions, finite-width expansion, moment hierarchy, examples, exercises, and references are at Ehrenfest Theorem.