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Amplitude

An amplitude is a complex number whose squared modulus gives, or contributes to, a quantum probability after the measurement context has been specified. In a normalized pure state, the amplitude for outcome state ∣a⟩\lvert a\rangle is usually written

αa=⟨a∣ψ⟩,P(a)=∣αa∣2.\alpha_a=\langle a\rvert\psi\rangle, \qquad P(a)=\lvert\alpha_a\rvert^2.

Amplitudes are not probabilities. Their phases and relative signs matter because amplitudes for indistinguishable alternatives add before probabilities are formed.

For a transition under a unitary evolution operator,

αψ→ϕ(t)=⟨ϕ∣U(t,t0)∣ψ⟩,Pψ→ϕ(t)=∣αψ→ϕ(t)∣2.\alpha_{\psi\to\phi}(t) = \langle\phi\rvert U(t,t_0)\lvert\psi\rangle, \qquad P_{\psi\to\phi}(t) = \lvert\alpha_{\psi\to\phi}(t)\rvert^2.

If two alternatives contribute amplitudes α1\alpha_1 and α2\alpha_2 to the same outcome, then

P=∣α1+α2∣2,P = \lvert\alpha_1+\alpha_2\rvert^2,

so the cross term encodes interference.

See Probability Amplitudes for the teaching page, Born Rule for the probability rule, and Transition Probabilities for time-evolution language.

  • A complex amplitude is not directly observed; probabilities and expectation values are.
  • An expansion coefficient is an amplitude only relative to a specified basis and measurement context.
  • Global phase has no observable effect, but relative phase can change interference.
  • A probability density such as ∣ψ(x)∣2\lvert\psi(x)\rvert^2 must be integrated over a region to produce a probability.
  • M. Born, “Zur Quantenmechanik der Stossvorgaenge,” Zeitschrift fuer Physik 37, 863-867, 1926.
  • P. A. M. Dirac, The Principles of Quantum Mechanics, 4th ed., Oxford University Press, 1958.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.