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alpha

The symbol α\alpha is a general-purpose Greek parameter. In elementary state notation it often denotes a probability amplitude, while in atomic and relativistic contexts α\alpha may denote the fine-structure constant.

In a two-level state, α\alpha is commonly used as one coefficient in a normalized superposition:

∣ψ⟩=α∣0⟩+β∣1⟩,∣α∣2+∣β∣2=1.\lvert\psi\rangle = \alpha\lvert0\rangle+\beta\lvert1\rangle, \qquad \lvert\alpha\rvert^2+\lvert\beta\rvert^2=1.

Here α\alpha is a complex number. Its phase matters relative to the phase of β\beta, while ∣α∣2\lvert\alpha\rvert^2 gives the Born-rule probability for the corresponding basis outcome.

In atomic physics, the same letter often denotes the fine-structure constant:

αfs=e24πϵ0ℏc\alpha_{\mathrm{fs}} = \frac{e^2}{4\pi\epsilon_0\hbar c}

in SI conventions. In oscillator and quantum-optics notation, α\alpha can also label a coherent state,

a∣α⟩=α∣α⟩.a\lvert\alpha\rangle=\alpha\lvert\alpha\rangle.

This is a different use from a two-level probability amplitude, even though both are complex dimensionless numbers in common conventions.

  • Probability amplitudes such as α\alpha are dimensionless after the basis state has been specified.
  • The fine-structure constant αfs\alpha_{\mathrm{fs}} is dimensionless.
  • A variational parameter, coupling, or angle named α\alpha has whatever units the local definition gives it.
  • α\alpha as a probability amplitude versus αfs\alpha_{\mathrm{fs}} as the fine-structure constant.
  • α\alpha as a coherent-state eigenvalue versus α\alpha as a generic variational parameter.
  • α\alpha and β\beta as coefficients versus Greek angle labels in geometry or scattering.
  • α\alpha as a coupling constant whose dimensions depend on the chosen Hamiltonian.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • D. J. Griffiths and D. F. Schroeter, Introduction to Quantum Mechanics, 3rd ed., Cambridge University Press, 2018.