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Eigenvalues of J² and Jz

The angular momentum algebra forces the simultaneous eigenvalues of J2J^2 and JzJ_z to have the form

J2∣j,m⟩=ℏ2j(j+1)∣j,m⟩,J^2|j,m\rangle = \hbar^2j(j+1)|j,m\rangle,

and

Jz∣j,m⟩=ℏm∣j,m⟩,J_z|j,m\rangle = \hbar m|j,m\rangle,

with

j=0,12,1,32,…,m=−j,−j+1,…,j.j=0,\frac12,1,\frac32,\ldots, \qquad m=-j,-j+1,\ldots,j.

The derivation uses only the commutation relations, ladder operators, and positivity of norms. Orbital angular momentum then adds an extra condition: ordinary single-valued spatial wavefunctions allow only integer orbital labels ℓ=0,1,2,…\ell=0,1,2,\ldots. Spin and total angular momentum can have half-integer jj.

The angular momentum components obey

[Ji,Jj]=iℏ∑kϵijkJk.[J_i,J_j] = i\hbar\sum_k\epsilon_{ijk}J_k.

Define

J2=Jx2+Jy2+Jz2,J^2=J_x^2+J_y^2+J_z^2,

and

J±=Jx±iJy.J_\pm=J_x\pm iJ_y.

Since

[J2,Jz]=0,[J^2,J_z]=0,

we choose simultaneous eigenstates. Before knowing the allowed eigenvalues, write them as

J2∣λ,m⟩=ℏ2λ∣λ,m⟩,J^2|\lambda,m\rangle = \hbar^2\lambda|\lambda,m\rangle,

and

Jz∣λ,m⟩=ℏm∣λ,m⟩.J_z|\lambda,m\rangle = \hbar m|\lambda,m\rangle.

Here λ\lambda and mm are dimensionless labels. The goal is to show that λ=j(j+1)\lambda=j(j+1) and that the allowed mm values form a finite ladder from −j-j to jj.

The ladder commutators are

[Jz,J±]=±ℏJ±,[J_z,J_\pm]=\pm\hbar J_\pm,

and

[J2,J±]=0.[J^2,J_\pm]=0.

If ∣λ,m⟩|\lambda,m\rangle is a simultaneous eigenstate, then

Jz(J±∣λ,m⟩)=ℏ(m±1)(J±∣λ,m⟩),J_z(J_\pm|\lambda,m\rangle) = \hbar(m\pm1)(J_\pm|\lambda,m\rangle),

while

J2(J±∣λ,m⟩)=ℏ2λ(J±∣λ,m⟩).J^2(J_\pm|\lambda,m\rangle) = \hbar^2\lambda(J_\pm|\lambda,m\rangle).

Thus J+J_+ and J−J_- move the mm label by one unit while keeping the same J2J^2 eigenvalue.

For a normalized simultaneous eigenstate,

⟨J2−Jz2⟩=⟨Jx2+Jy2⟩≥0.\langle J^2-J_z^2\rangle = \langle J_x^2+J_y^2\rangle \geq0.

Using the eigenvalues gives

ℏ2(λ−m2)≥0,\hbar^2(\lambda-m^2)\geq0,

so

m2≤λ.m^2\leq\lambda.

The mm ladder is bounded. Since ladder operations change mm in integer steps, repeated raising and lowering must stop.

Let m+m_+ be the highest mm value in a fixed ladder and m−m_- the lowest. Then

J+∣λ,m+⟩=0,J−∣λ,m−⟩=0.J_+|\lambda,m_+\rangle=0, \qquad J_-|\lambda,m_-\rangle=0.

Use the operator identities

J−J+=J2−Jz2−ℏJz,J_-J_+ = J^2-J_z^2-\hbar J_z,

and

J+J−=J2−Jz2+ℏJz.J_+J_- = J^2-J_z^2+\hbar J_z.

Then

∥J+∣λ,m⟩∥2=⟨λ,m∣J−J+∣λ,m⟩=ℏ2[λ−m(m+1)],\begin{aligned} \|J_+|\lambda,m\rangle\|^2 &= \langle\lambda,m|J_-J_+|\lambda,m\rangle \\ &= \hbar^2\left[ \lambda-m(m+1) \right], \end{aligned}

and

∥J−∣λ,m⟩∥2=⟨λ,m∣J+J−∣λ,m⟩=ℏ2[λ−m(m−1)].\begin{aligned} \|J_-|\lambda,m\rangle\|^2 &= \langle\lambda,m|J_+J_-|\lambda,m\rangle \\ &= \hbar^2\left[ \lambda-m(m-1) \right]. \end{aligned}

At the top,

∥J+∣λ,m+⟩∥2=0,\|J_+|\lambda,m_+\rangle\|^2=0,

so

λ=m+(m++1).\lambda=m_+(m_+ +1).

At the bottom,

∥J−∣λ,m−⟩∥2=0,\|J_-|\lambda,m_-\rangle\|^2=0,

so

λ=m−(m−−1).\lambda=m_-(m_- -1).

Equating the two endpoint expressions gives

m+(m++1)=m−(m−−1).m_+(m_+ +1) = m_-(m_- -1).

Rearrange:

(m++m−)(m+−m−+1)=0.(m_+ +m_-)(m_+-m_-+1)=0.

The second factor is positive because m+≥m−m_+\geq m_-. Therefore

m−=−m+.m_-=-m_+.

Define

j=m+.j=m_+.

Then

m−=−j,m_-=-j,

and

λ=j(j+1).\lambda=j(j+1).

This gives the standard eigenvalue

J2∣j,m⟩=ℏ2j(j+1)∣j,m⟩.J^2|j,m\rangle = \hbar^2j(j+1)|j,m\rangle.

The ladder runs in unit steps from −j-j to jj:

m=−j,−j+1,…,j−1,j.m=-j,-j+1,\ldots,j-1,j.

Since the number of steps from −j-j to jj is 2j2j, this number must be a nonnegative integer. Therefore

2j=0,1,2,…,2j=0,1,2,\ldots,

or

j=0,12,1,32,….j=0,\frac12,1,\frac32,\ldots.

For fixed jj, the number of allowed mm values is

2j+1.2j+1.

This is the dimension of the irreducible angular momentum multiplet.

After relabeling λ=j(j+1)\lambda=j(j+1), the norm formulas give the standard action

J±∣j,m⟩=ℏj(j+1)−m(m±1) ∣j,m±1⟩,J_\pm|j,m\rangle = \hbar \sqrt{j(j+1)-m(m\pm1)} \,|j,m\pm1\rangle,

up to phase conventions for the basis states. With the usual Condon-Shortley convention, the square-root coefficient is chosen real and nonnegative.

The coefficient vanishes at the endpoints:

J+∣j,j⟩=0,J−∣j,−j⟩=0.J_+|j,j\rangle=0, \qquad J_-|j,-j\rangle=0.
jjallowed mm valuesmultiplet dimension
000011
1/21/2−1/2,1/2-1/2,1/222
11−1,0,1-1,0,133
3/23/2−3/2,−1/2,1/2,3/2-3/2,-1/2,1/2,3/244
22−2,−1,0,1,2-2,-1,0,1,255

For j=1/2j=1/2, the ladder has only two states. For j=1j=1, it has three states. The formula 2j+12j+1 is not a mnemonic; it is the length of the finite ladder forced by the algebra.

The algebraic derivation permits both integer and half-integer jj. Which values occur depends on the physical representation of rotations.

For orbital angular momentum of an ordinary scalar wavefunction, rotations act on spatial coordinates. In spherical coordinates,

Lz=−iℏ∂∂ϕ.L_z=-i\hbar\frac{\partial}{\partial\phi}.

An LzL_z eigenfunction has angular dependence

eimϕ.e^{im\phi}.

Single-valuedness under

ϕ↦ϕ+2π\phi\mapsto\phi+2\pi

requires

ei2πm=1,e^{i2\pi m}=1,

so

m∈Z.m\in\mathbb Z.

Since mm runs from −ℓ-\ell to ℓ\ell, orbital angular momentum has

ℓ=0,1,2,….\ell=0,1,2,\ldots.

Spin is different. Spin states transform under representations of SU(2)SU(2), the double cover of SO(3)SO(3). Half-integer spinors can change sign under a 2π2\pi rotation while representing the same physical ray. This is why spin-1/21/2 is allowed even though scalar orbital wavefunctions have integer ℓ\ell.

The magnitude associated with J2J^2 is not ℏj\hbar j but

j(j+1) ℏ.\sqrt{j(j+1)}\,\hbar.

The zz-component is

ℏm.\hbar m.

For fixed jj, the different mm states are different projections of the same total angular momentum multiplet along the chosen quantization axis. Choosing zz is a convention; another axis could be chosen, but one cannot generally assign sharp values to JxJ_x, JyJ_y, and JzJ_z simultaneously.

  • Writing the J2J^2 eigenvalue as ℏ2j2\hbar^2j^2 instead of ℏ2j(j+1)\hbar^2j(j+1).
  • Forgetting that mm changes by integer steps even when jj is half-integer.
  • Treating jj and mm as operator eigenvalues rather than dimensionless labels.
  • Assuming the algebra alone makes orbital angular momentum integer-valued; the orbital integer condition comes from the spatial representation.
  • Applying J+J_+ or J−J_- outside the allowed ladder endpoints.
  • Confusing the number of states, 2j+12j+1, with the largest mm value, jj.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • A. R. Edmonds, Angular Momentum in Quantum Mechanics, Princeton University Press, 1957.
  • D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum, World Scientific, 1988.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  1. Starting from J−J+=J2−Jz2−ℏJzJ_-J_+=J^2-J_z^2-\hbar J_z, derive the norm of J+∣j,m⟩J_+|j,m\rangle.
Solution

For normalized ∣j,m⟩|j,m\rangle,

∥J+∣j,m⟩∥2=⟨j,m∣J−J+∣j,m⟩.\|J_+|j,m\rangle\|^2 = \langle j,m|J_-J_+|j,m\rangle.

Substitute the identity:

∥J+∣j,m⟩∥2=⟨j,m∣J2−Jz2−ℏJz∣j,m⟩.\|J_+|j,m\rangle\|^2 = \langle j,m| J^2-J_z^2-\hbar J_z |j,m\rangle.

Using

J2∣j,m⟩=ℏ2j(j+1)∣j,m⟩,J^2|j,m\rangle = \hbar^2j(j+1)|j,m\rangle,

and

Jz∣j,m⟩=ℏm∣j,m⟩,J_z|j,m\rangle = \hbar m|j,m\rangle,

gives

∥J+∣j,m⟩∥2=ℏ2[j(j+1)−m(m+1)].\|J_+|j,m\rangle\|^2 = \hbar^2\left[ j(j+1)-m(m+1) \right].
  1. List the allowed mm values for j=5/2j=5/2 and count the states.
Solution

The values are

m=−52,−32,−12,12,32,52.m=-\frac52,-\frac32,-\frac12,\frac12,\frac32,\frac52.

There are

2j+1=2⋅52+1=62j+1=2\cdot\frac52+1=6

states.

  1. Explain why the algebra permits j=1/2j=1/2 but orbital angular momentum of a scalar wavefunction does not have ℓ=1/2\ell=1/2.
Solution

The algebra only requires 2j2j to be a nonnegative integer, so half-integer representations are allowed. Orbital angular momentum acts on spatial wavefunctions. Since Lz=−iℏ ∂/∂ϕL_z=-i\hbar\,\partial/\partial\phi, an LzL_z eigenfunction contains eimϕe^{im\phi}. Single-valuedness under ϕ↦ϕ+2π\phi\mapsto\phi+2\pi requires ei2πm=1e^{i2\pi m}=1, so mm must be integer. Therefore orbital labels ℓ\ell are integers. Half-integer spin instead comes from spinor representations of SU(2)SU(2).

  1. Show that J+∣j,j⟩=0J_+|j,j\rangle=0 and J−∣j,−j⟩=0J_-|j,-j\rangle=0 using the normalized ladder coefficient.
Solution

For the top state,

J+∣j,j⟩=ℏj(j+1)−j(j+1) ∣j,j+1⟩=0.J_+|j,j\rangle = \hbar \sqrt{j(j+1)-j(j+1)} \,|j,j+1\rangle = 0.

For the bottom state,

J−∣j,−j⟩=ℏj(j+1)−(−j)(−j−1) ∣j,−j−1⟩=0.J_-|j,-j\rangle = \hbar \sqrt{j(j+1)-(-j)(-j-1)} \,|j,-j-1\rangle = 0.

The formal outside-ladder kets do not represent physical states in the multiplet because the coefficient already vanishes.