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Angular Momentum Problems

These solved problems practice angular-momentum algebra as a working tool: ladder operators, orbital eigenfunctions, central-potential labels, coupled bases, and spin–orbit shifts.

Use Angular Momentum Identity Index as the formula companion. For focused lookup, use Spherical Harmonics Quick Reference and Clebsch–Gordan Quick Reference. The canonical derivations live in Ladder Operators, Central Potentials and Rotational Symmetry, and Spin–Orbit Coupling.

The angular momentum algebra is

[Ji,Jj]=iℏ∑kϵijkJk,ϵxyz=+1.[J_i,J_j] = i\hbar\sum_k\epsilon_{ijk}J_k, \qquad \epsilon_{xyz}=+1.

The standard basis satisfies

J2∣j,m⟩=ℏ2j(j+1)∣j,m⟩,Jz∣j,m⟩=ℏm∣j,m⟩.J^2\lvert j,m\rangle = \hbar^2j(j+1)\lvert j,m\rangle, \qquad J_z\lvert j,m\rangle = \hbar m\lvert j,m\rangle.

With

J±=Jx±iJy,J_\pm=J_x\pm iJ_y,

the ladder action is

J±∣j,m⟩=ℏj(j+1)−m(m±1)∣j,m±1⟩.J_\pm\lvert j,m\rangle = \hbar \sqrt{j(j+1)-m(m\pm1)} \lvert j,m\pm1\rangle.

For orbital angular momentum, write j→ℓj\to\ell and Ji→LiJ_i\to L_i. Spherical harmonics obey

L2Yℓm=ℏ2ℓ(ℓ+1)Yℓm,LzYℓm=ℏmYℓm.L^2Y_\ell^m = \hbar^2\ell(\ell+1)Y_\ell^m, \qquad L_zY_\ell^m = \hbar mY_\ell^m.

For adding two angular momenta,

J=J1+J2,\mathbf J=\mathbf J_1+\mathbf J_2,

and the allowed total labels are

J=∣j1−j2∣,∣j1−j2∣+1,…,j1+j2.J= \lvert j_1-j_2\rvert, \lvert j_1-j_2\rvert+1, \ldots, j_1+j_2.
Problem groupSkillsPreparation
Ladder operatorsnorms, endpoints, matrix elementsLadder Operators
Orbital eigenfunctionsLzL_z, parity, spherical harmonicsSpherical Harmonics
Central potentialsgood quantum numbers, degeneracy, symmetry breakingCentral Potentials and Rotational Symmetry
Additiondimension checks, coupled and uncoupled basesClebsch–Gordan Coefficients
Spin–orbit couplingscalar products, J2J^2 identity, level shiftsSpin–Orbit Coupling

Starting from

J−J+=J2−Jz2−ℏJz,J_-J_+ = J^2-J_z^2-\hbar J_z,

derive the coefficient in

J+∣j,m⟩=Cjm(+)∣j,m+1⟩J_+\lvert j,m\rangle = C_{jm}^{(+)}\lvert j,m+1\rangle

for normalized states. Explain why the coefficient vanishes at the top of the multiplet.

Solution

Take the norm of the raised state:

∥J+∣j,m⟩∥2=⟨j,m∣J−J+∣j,m⟩.\left\lVert J_+\lvert j,m\rangle \right\rVert^2 = \langle j,m|J_-J_+|j,m\rangle.

Use the identity in the question and the eigenvalue equations:

⟨j,m∣J−J+∣j,m⟩=ℏ2j(j+1)−ℏ2m2−ℏ2m=ℏ2[j(j+1)−m(m+1)].\begin{aligned} \langle j,m|J_-J_+|j,m\rangle &= \hbar^2j(j+1) - \hbar^2m^2 - \hbar^2m \\ &= \hbar^2 \left[ j(j+1)-m(m+1) \right]. \end{aligned}

Since the states are normalized,

∣Cjm(+)∣2=ℏ2[j(j+1)−m(m+1)].\left|C_{jm}^{(+)}\right|^2 = \hbar^2 \left[ j(j+1)-m(m+1) \right].

With the standard Condon–Shortley phase convention the coefficient is chosen real and nonnegative:

Cjm(+)=ℏj(j+1)−m(m+1).C_{jm}^{(+)} = \hbar \sqrt{j(j+1)-m(m+1)}.

For m=jm=j, the expression under the square root is

j(j+1)−j(j+1)=0,j(j+1)-j(j+1)=0,

so

J+∣j,j⟩=0.J_+\lvert j,j\rangle=0.

The top state is annihilated because there is no allowed state with m=j+1m=j+1 inside the same irreducible multiplet.

2. Transverse Angular Momentum in a Fixed State

Section titled “2. Transverse Angular Momentum in a Fixed State”

For a normalized angular momentum state ∣j,m⟩\lvert j,m\rangle, compute

⟨Jx2+Jy2⟩.\langle J_x^2+J_y^2\rangle.

Then show that

⟨Jx⟩=⟨Jy⟩=0.\langle J_x\rangle=\langle J_y\rangle=0.
Solution

Use

J2=Jx2+Jy2+Jz2.J^2=J_x^2+J_y^2+J_z^2.

Therefore

⟨Jx2+Jy2⟩=⟨J2−Jz2⟩=ℏ2j(j+1)−ℏ2m2=ℏ2[j(j+1)−m2].\begin{aligned} \langle J_x^2+J_y^2\rangle &= \langle J^2-J_z^2\rangle \\ &= \hbar^2j(j+1)-\hbar^2m^2 \\ &= \hbar^2 \left[ j(j+1)-m^2 \right]. \end{aligned}

For the first moments, write

Jx=12(J++J−),Jy=12i(J+−J−).J_x=\frac12(J_++J_-), \qquad J_y=\frac{1}{2i}(J_+-J_-).

The ladder operators map ∣j,m⟩\lvert j,m\rangle to states with m±1m\pm1, which are orthogonal to ∣j,m⟩\lvert j,m\rangle. Hence

⟨j,m∣J±∣j,m⟩=0,\langle j,m|J_\pm|j,m\rangle=0,

and therefore

⟨Jx⟩=⟨Jy⟩=0.\langle J_x\rangle=\langle J_y\rangle=0.

The result does not mean the transverse components have no fluctuations. Their squared sum is nonzero unless the state is the trivial j=0j=0 representation.

The normalized spherical harmonic Y21Y_2^1 is proportional to

sin⁡θcos⁡θ eiϕ.\sin\theta\cos\theta\,e^{i\phi}.

Use

Lz=−iℏ∂∂ϕL_z=-i\hbar\frac{\partial}{\partial\phi}

to identify its mm label. Then determine its parity.

Solution

Acting with LzL_z gives

LzY21=−iℏ∂∂ϕ[constant⋅sin⁡θcos⁡θ eiϕ]=−iℏ[i constant⋅sin⁡θcos⁡θ eiϕ]=ℏY21.\begin{aligned} L_zY_2^1 &= -i\hbar \frac{\partial}{\partial\phi} \left[ \text{constant}\cdot \sin\theta\cos\theta\,e^{i\phi} \right] \\ &= -i\hbar \left[ i\, \text{constant}\cdot \sin\theta\cos\theta\,e^{i\phi} \right] \\ &= \hbar Y_2^1. \end{aligned}

Thus m=1m=1. The ℓ\ell label is already given by the subscript ℓ=2\ell=2, so

L2Y21=ℏ2 2(2+1)Y21=6ℏ2Y21.L^2Y_2^1 = \hbar^2\,2(2+1)Y_2^1 = 6\hbar^2Y_2^1.

The parity of a scalar spherical harmonic is

(−1)ℓ.(-1)^\ell.

For ℓ=2\ell=2, the parity is even:

Y21(π−θ,ϕ+π)=Y21(θ,ϕ).Y_2^1(\pi-\theta,\phi+\pi) = Y_2^1(\theta,\phi).

The sign convention in the overall normalization does not affect the eigenvalue or parity conclusions.

4. Central-Potential Labels and Degeneracy

Section titled “4. Central-Potential Labels and Degeneracy”

A spinless particle in a generic central potential has a bound-state sector labeled by

∣nr,ℓ,m⟩.\lvert n_r,\ell,m\rangle.

For fixed nrn_r and ℓ=3\ell=3, how many states are related by rotational symmetry? Which operators form a natural commuting set? If a spin-1/21/2 degree of freedom is added but the Hamiltonian remains spin independent, what is the degeneracy before spin–orbit coupling?

Solution

For fixed ℓ\ell, the magnetic label is

m=−ℓ,−ℓ+1,…,ℓ.m=-\ell,-\ell+1,\ldots,\ell.

For ℓ=3\ell=3, this gives

m=−3,−2,−1,0,1,2,3,m=-3,-2,-1,0,1,2,3,

so there are

2ℓ+1=72\ell+1=7

states in the orbital multiplet.

For a spinless central Hamiltonian, a natural commuting set is

H,L2,Lz.H,\quad L^2,\quad L_z.

The choice of LzL_z is a basis convention inside the rotational multiplet; no physical zz direction is selected by a pure central potential.

If a spin-1/21/2 degree of freedom is added without spin-dependent terms, the Hilbert space is the orbital multiplet tensored with a two-dimensional spin space. The degeneracy becomes

(2ℓ+1)(2s+1)=7⋅2=14.(2\ell+1)(2s+1) = 7\cdot2 = 14.

This degeneracy is not all protected in the same way. The mm degeneracy follows from spatial rotations, while the spin degeneracy follows from the absence of spin-dependent interactions.

Add angular momenta j1=2j_1=2 and j2=3/2j_2=3/2. List the allowed total JJ values and verify the dimension count.

Solution

The allowed total angular momenta are

J=∣2−32∣,∣2−32∣+1,…,2+32.J= \left|2-\frac32\right|, \left|2-\frac32\right|+1, \ldots, 2+\frac32.

Thus

J=12,32,52,72.J=\frac12,\frac32,\frac52,\frac72.

The uncoupled product space has dimension

(2j1+1)(2j2+1)=(5)(4)=20.(2j_1+1)(2j_2+1) = (5)(4) = 20.

The coupled decomposition has dimension

∑J(2J+1)=(2⋅12+1)+(2⋅32+1)+(2⋅52+1)+(2⋅72+1).\sum_J(2J+1) = \left(2\cdot\frac12+1\right) + \left(2\cdot\frac32+1\right) + \left(2\cdot\frac52+1\right) + \left(2\cdot\frac72+1\right).

Therefore

∑J(2J+1)=2+4+6+8=20.\sum_J(2J+1) = 2+4+6+8 = 20.

The dimension check confirms that the coupled basis is a reorganization of the same Hilbert space, not a new Hilbert space.

Couple j1=1j_1=1 and j2=1/2j_2=1/2. Starting from

∣32,32⟩=∣1,1⟩∣12,12⟩,\left|\frac32,\frac32\right\rangle = \lvert 1,1\rangle \left|\frac12,\frac12\right\rangle,

use the total lowering operator J−=J1−+J2−J_-=J_{1-}+J_{2-} to find the total-J=3/2J=3/2, M=1/2M=1/2 state. Then find the orthogonal total-J=1/2J=1/2, M=1/2M=1/2 state in the same subspace.

Solution

On the left side of a coupled-state equation, the labels are total J,MJ,M labels. In product states, the two kets carry the separate j1,m1j_1,m_1 and j2,m2j_2,m_2 labels.

On the coupled state,

J−∣32,32⟩=ℏ32(32+1)−32(32−1)∣32,12⟩.J_-\left|\frac32,\frac32\right\rangle = \hbar \sqrt{ \frac32\left(\frac32+1\right) - \frac32\left(\frac32-1\right) } \left|\frac32,\frac12\right\rangle.

The square root is

3,\sqrt{3},

so

J−∣32,32⟩=ℏ3∣32,12⟩.J_-\left|\frac32,\frac32\right\rangle = \hbar\sqrt3 \left|\frac32,\frac12\right\rangle.

Now act on the product state:

J− ∣1,1⟩∣12,12⟩=(J1−+J2−)∣1,1⟩∣12,12⟩=ℏ2∣1,0⟩∣12,12⟩+ℏ∣1,1⟩∣12,−12⟩.\begin{aligned} J_-\, \lvert1,1\rangle \left|\frac12,\frac12\right\rangle &= (J_{1-}+J_{2-}) \lvert1,1\rangle \left|\frac12,\frac12\right\rangle \\ &= \hbar\sqrt2 \lvert1,0\rangle \left|\frac12,\frac12\right\rangle + \hbar \lvert1,1\rangle \left|\frac12,-\frac12\right\rangle. \end{aligned}

Equating the two expressions and dividing by ℏ3\hbar\sqrt3 gives

∣32,12⟩=23∣1,0⟩∣12,12⟩+13∣1,1⟩∣12,−12⟩.\left|\frac32,\frac12\right\rangle = \sqrt{\frac23} \lvert1,0\rangle \left|\frac12,\frac12\right\rangle + \frac{1}{\sqrt3} \lvert1,1\rangle \left|\frac12,-\frac12\right\rangle.

The M=1/2M=1/2 uncoupled subspace is spanned by

∣1,0⟩∣12,12⟩,∣1,1⟩∣12,−12⟩.\lvert1,0\rangle \left|\frac12,\frac12\right\rangle, \qquad \lvert1,1\rangle \left|\frac12,-\frac12\right\rangle.

The normalized state orthogonal to ∣32,12⟩\left|\frac32,\frac12\right\rangle is, up to an overall phase,

∣12,12⟩=13∣1,0⟩∣12,12⟩−23∣1,1⟩∣12,−12⟩.\left|\frac12,\frac12\right\rangle = \frac{1}{\sqrt3} \lvert1,0\rangle \left|\frac12,\frac12\right\rangle - \sqrt{\frac23} \lvert1,1\rangle \left|\frac12,-\frac12\right\rangle.

The overall sign is conventional, but once a Condon–Shortley convention is chosen it must be used consistently with the tables.

Consider the effective Hamiltonian

HSO=A L⋅Sℏ2H_{\mathrm{SO}} = A\,\frac{\mathbf L\cdot\mathbf S}{\hbar^2}

on a fixed orbital multiplet with ℓ=1\ell=1 and spin s=1/2s=1/2. Find the possible energy shifts and their degeneracies.

Solution

The total angular momenta are

j=ℓ+12=32,j=ℓ−12=12.j=\ell+\frac12=\frac32, \qquad j=\ell-\frac12=\frac12.

Use

L⋅S=12(J2−L2−S2).\mathbf L\cdot\mathbf S = \frac12 \left( J^2-L^2-S^2 \right).

On a coupled state,

L⋅Sℏ2=12[j(j+1)−ℓ(ℓ+1)−s(s+1)].\frac{\mathbf L\cdot\mathbf S}{\hbar^2} = \frac12 \left[ j(j+1)-\ell(\ell+1)-s(s+1) \right].

For ℓ=1\ell=1, s=1/2s=1/2, and j=3/2j=3/2,

L⋅Sℏ2=12[3252−2−1232]=12.\begin{aligned} \frac{\mathbf L\cdot\mathbf S}{\hbar^2} &= \frac12 \left[ \frac32\frac52 -2 -\frac12\frac32 \right] \\ &= \frac12. \end{aligned}

For j=1/2j=1/2,

L⋅Sℏ2=12[1232−2−1232]=−1.\begin{aligned} \frac{\mathbf L\cdot\mathbf S}{\hbar^2} &= \frac12 \left[ \frac12\frac32 -2 -\frac12\frac32 \right] \\ &= -1. \end{aligned}

Thus the shifts are

ΔEj=3/2=A2,ΔEj=1/2=−A.\Delta E_{j=3/2}=\frac{A}{2}, \qquad \Delta E_{j=1/2}=-A.

Their degeneracies are

2j+1=4and2j+1=2.2j+1=4 \quad \text{and} \quad 2j+1=2.

The original product space has dimension

(2ℓ+1)(2s+1)=3⋅2=6,(2\ell+1)(2s+1)=3\cdot2=6,

which is exactly 4+24+2.

Let two angular momenta J1\mathbf J_1 and J2\mathbf J_2 have fixed quantum numbers j1j_1 and j2j_2. Consider

H=E0+A J1⋅J2ℏ2.H=E_0+A\,\frac{\mathbf J_1\cdot\mathbf J_2}{\hbar^2}.

Which basis diagonalizes the interaction? Give the energy shift for a sector of total angular momentum JJ.

Solution

The interaction is a scalar product of the two angular momenta. It is not generally diagonal in the uncoupled basis

∣j1,m1⟩∣j2,m2⟩,\lvert j_1,m_1\rangle \lvert j_2,m_2\rangle,

because terms such as J1+J2−J_{1+}J_{2-} and J1−J2+J_{1-}J_{2+} can mix product states with the same total M=m1+m2M=m_1+m_2.

The coupled basis

∣j1,j2;J,M⟩\lvert j_1,j_2;J,M\rangle

is the natural basis. With

J=J1+J2,\mathbf J=\mathbf J_1+\mathbf J_2,

one has

J1⋅J2=12(J2−J12−J22).\mathbf J_1\cdot\mathbf J_2 = \frac12 \left( J^2-J_1^2-J_2^2 \right).

Therefore

J1⋅J2ℏ2=12[J(J+1)−j1(j1+1)−j2(j2+1)]\frac{\mathbf J_1\cdot\mathbf J_2}{\hbar^2} = \frac12 \left[ J(J+1)-j_1(j_1+1)-j_2(j_2+1) \right]

on the sector with total angular momentum JJ. The energy shift is

ΔEJ=A2[J(J+1)−j1(j1+1)−j2(j2+1)].\Delta E_J = \frac{A}{2} \left[ J(J+1)-j_1(j_1+1)-j_2(j_2+1) \right].

Rotational symmetry leaves the MM states inside a fixed JJ multiplet degenerate unless another term breaks the symmetry.

  • Treating mm as an angular momentum rather than the dimensionless label whose eigenvalue is ℏm\hbar m.
  • Forgetting that J±J_\pm changes mm but not jj.
  • Using Lz=−iℏ∂ϕL_z=-i\hbar\partial_\phi with the wrong sign convention for eimϕe^{im\phi}.
  • Counting only allowed JJ values instead of their multiplicities 2J+12J+1.
  • Assuming every central-potential degeneracy is caused by ordinary rotational symmetry.
  • Using the uncoupled basis after a scalar coupling has made the coupled basis diagonal.
  • Reading a spin–orbit energy ordering from jj alone without the sign and radial coefficient of the Hamiltonian.
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  • D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum, World Scientific, 1988.
  • D. M. Brink and G. R. Satchler, Angular Momentum, 3rd ed., Oxford University Press, 1993.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.