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Double-Well Splitting

This worked example follows one symmetric quartic double well through four mutually checking descriptions:

  1. a physical Hamiltonian and its dimensionless semiclassical parameter;
  2. an exact two-state representation of the lowest even–odd doublet;
  3. a WKB estimate from the energy-dependent barrier action;
  4. an instanton estimate from a finite-action Euclidean trajectory.

The calculation ends with symmetry-resolved numerical diagonalization across a range of barrier depths. That comparison matters because the tunneling exponent is robust, while order-one prefactors require more care.

Double-Well Tunneling is the canonical home for the physical model. Tunneling Splittings owns the general dictionary among localized states, Herring flux, WKB, instantons, and spectral gaps. This page owns one convention-fixed hand calculation. Double-Well Instanton Numerical Check owns the downloadable solver, full convergence sweeps, independent finite-difference check, and retained data.

Consider

Hphys=−ℏ22md2dx2+λ(x2−a2)2.\begin{aligned} H_{\mathrm{phys}} &= -\frac{\hbar^2}{2m} \frac{d^2}{dx^2} \\ &\quad+ \lambda \left( x^2-a^2 \right)^2. \end{aligned}

Here λ>0\lambda\gt0.

The minima are at x=±ax=\pm a, and the central barrier has height

V(0)=λa4.V(0)=\lambda a^4.

For the lowest doublet, determine:

  • the effective left–right Hamiltonian;
  • the even–odd splitting ΔE\Delta E;
  • the WKB barrier exponent;
  • the Euclidean instanton and its action;
  • the regime in which these semiclassical descriptions agree with the spectrum.

The observable is a closed-system energy difference,

ΔE≡Eodd−Eeven>0.\Delta E \equiv E_{\mathrm{odd}} - E_{\mathrm{even}} \gt0.

It is not a transmission probability and not a decay width.

Set

q=xa,E=2λa4 ϵ,q=\frac{x}{a}, \qquad E=2\lambda a^4\,\epsilon,

and define

g≡ℏa32mλ.g \equiv \frac{ \hbar }{ a^3\sqrt{2m\lambda} }.

The stationary Schrödinger equation becomes

Hgψ(q)=ϵψ(q),H_g\psi(q) = \epsilon\psi(q),

with

Hg=−g22d2dq2+U(q),U(q)=12(q2−1)2.\begin{aligned} H_g &= -\frac{g^2}{2} \frac{d^2}{dq^2} + U(q), \\ U(q) &= \frac12 \left( q^2-1 \right)^2. \end{aligned}

All dependence on mm, λ\lambda, aa, and ℏ\hbar is now carried by the energy scale 2λa42\lambda a^4 and the dimensionless parameter gg.

The dimensionless barrier height is 1/21/2. Near either minimum,

U′′(±1)=4,U''(\pm1)=4,

so the classical small-oscillation frequency is

ω0=2.\omega_0=2.

Because gg plays the role of an effective Planck constant, the local ground energy is

ϵloc=gω02+O(g2)=g+O(g2).\epsilon_{\mathrm{loc}} = \frac{g\omega_0}{2} + O(g^2) = g+O(g^2).

The deep-well regime is therefore

g≪1,g\ll1,

where the intrawell scale gω0=2gg\omega_0=2g is small compared with the barrier height, and the splitting is exponentially smaller still.

In physical variables, the exponent obtained below is

43g=4a32mλ3ℏ.\frac{4}{3g} = \frac{ 4a^3\sqrt{2m\lambda} }{ 3\hbar }.

It grows with barrier width, stiffness, and square root of the mass.

Write q=1+yq=1+y near the right minimum. The potential is

U(1+y)=2y2+2y3+12y4.U(1+y) = 2y^2 + 2y^3 + \frac12y^4.

The quadratic term gives ω0=2\omega_0=2. Ordinary perturbation theory about this local oscillator gives

ϵloc=g−14g2+O(g3).\epsilon_{\mathrm{loc}} = g - \frac14g^2 + O(g^3).

The O(g2)O(g^2) coefficient combines the first-order quartic correction and the second-order cubic correction. This is an intrawell expansion: every finite order is the same in the left and right wells and therefore cannot by itself produce their exponentially small difference.

That distinction is central:

  • finite powers of gg contribute to the common intrawell energy;
  • the nonanalytic factor e−4/(3g)e^{-4/(3g)} produces the even–odd splitting.

Perturbation theory around one minimum and tunneling semiclassics answer different parts of the spectrum.

Let ∣e⟩\lvert e\rangle and ∣o⟩\lvert o\rangle denote the exact lowest even and odd eigenstates, with energies ϵe\epsilon_e and ϵo\epsilon_o. Define orthonormal left- and right-localized combinations by

∣L⟩=∣e⟩+∣o⟩2,∣R⟩=∣e⟩−∣o⟩2.\begin{aligned} \lvert L\rangle &= \frac{ \lvert e\rangle+\lvert o\rangle }{ \sqrt2 }, \\ \lvert R\rangle &= \frac{ \lvert e\rangle-\lvert o\rangle }{ \sqrt2 }. \end{aligned}

Within this exact two-dimensional spectral subspace,

Heff=(ϵˉ−J−Jϵˉ)=ϵˉI−Jσx,H_{\mathrm{eff}} = \begin{pmatrix} \bar\epsilon & -J\\ -J & \bar\epsilon \end{pmatrix} = \bar\epsilon I - J\sigma_x,

where

ϵˉ=ϵe+ϵo2,J=ϵo−ϵe2>0.\bar\epsilon = \frac{ \epsilon_e+\epsilon_o }{2}, \qquad J = \frac{ \epsilon_o-\epsilon_e }{2} \gt0.

The sign convention J>0J\gt0 makes the nodeless even state the lower state:

ϵe=ϵˉ−J,ϵo=ϵˉ+J.\begin{aligned} \epsilon_e &= \bar\epsilon-J, \\ \epsilon_o &= \bar\epsilon+J. \end{aligned}

Therefore

Δϵ≡ϵo−ϵe=2J.\Delta\epsilon \equiv \epsilon_o-\epsilon_e = 2J.

The matrix identity is exact after the doublet has been selected. Calling ∣L⟩\lvert L\rangle and ∣R⟩\lvert R\rangle spatially localized is accurate only when the doublet is well isolated and gg is small enough that the two lobes overlap weakly.

In dimensionless real time ss, the Schrödinger equation is

igdds∣ψ(s)⟩=Heff∣ψ(s)⟩.ig \frac{d}{ds} \lvert\psi(s)\rangle = H_{\mathrm{eff}} \lvert\psi(s)\rangle.

Starting in ∣L⟩\lvert L\rangle,

PR(s)=∣⟨R∣ψ(s)⟩∣2=sin⁡2(Jsg).P_R(s) = \left| \langle R\vert\psi(s)\rangle \right|^2 = \sin^2 \left( \frac{Js}{g} \right).

The first complete transfer occurs at

stransfer=πg2J=πgΔϵ.s_{\mathrm{transfer}} = \frac{\pi g}{2J} = \frac{\pi g}{\Delta\epsilon}.

An exponentially small spectral splitting therefore means an exponentially long coherent transfer time. This oscillation is a closed-system consequence of the doublet; it should not be interpreted as a sequence of stochastic barrier crossings.

Quartic double well, its Euclidean instanton, and the numerical approach to the instanton action

Top: at g=0.15g=0.15, the local ground energy lies below the barrier and the one-way WKB action spans the inner turning points. Middle: the finite-action Euclidean solution qI(s)=tanh⁡(s−s0)q_I(s)=\tanh(s-s_0) connects the two minima. Bottom: the scaled logarithm extracted from numerical gaps tends toward the instanton action S0=4/3S_0=4/3 as g→0g\to0.

For a local level at energy ϵloc<1/2\epsilon_{\mathrm{loc}}\lt1/2, the two inner turning points solve

U(qt)=ϵloc.U(q_t)=\epsilon_{\mathrm{loc}}.

Using the leading local energy ϵloc=g\epsilon_{\mathrm{loc}}=g gives

qt(g)=1−2g,0<g<12.q_t(g) = \sqrt{ 1-\sqrt{2g} }, \qquad 0\lt g\lt\frac12.

The forbidden interval relevant to the splitting is −qt<q<qt-q_t\lt q\lt q_t. Its one-way action is

W(g)=∫−qtqt2[U(q)−g] dq=2∫0qt(1−q2)2−2g dq.\begin{aligned} W(g) &= \int_{-q_t}^{q_t} \sqrt{ 2\left[ U(q)-g \right] } \,dq \\ &= 2 \int_0^{q_t} \sqrt{ \left( 1-q^2 \right)^2 - 2g } \,dq. \end{aligned}

The elementary leading connection formula for the ground doublet is

ΔϵWKB=gω0πexp⁡[−W(g)g].\Delta\epsilon_{\mathrm{WKB}} = \frac{ g\omega_0 }{\pi} \exp \left[ -\frac{W(g)}{g} \right].

Since ω0=2\omega_0=2,

ΔϵWKB=2gπe−W(g)/g.\Delta\epsilon_{\mathrm{WKB}} = \frac{2g}{\pi} e^{-W(g)/g}.

This formula uses the leading harmonic local energy and the leading connection prefactor consistently. Replacing gg in the turning-point equation by g−g2/4g-g^2/4 changes the exponent at relative algebraic order. Such a refinement can be useful, but combining it with an uncorrected prefactor is only a partial next-order calculation and need not improve the error monotonically.

For g=0.15g=0.15,

qt=1−0.30=0.672514…,q_t = \sqrt{ 1-\sqrt{0.30} } = 0.672514\ldots,

and numerical quadrature gives

W(0.15)=0.8502476075….W(0.15) = 0.8502476075\ldots.

Therefore

ΔϵWKB=3.2980134×10−4.\Delta\epsilon_{\mathrm{WKB}} = 3.2980134\times10^{-4}.

The converged numerical splitting is

Δϵnum=2.9960349×10−4,\Delta\epsilon_{\mathrm{num}} = 2.9960349\times10^{-4},

so this leading WKB estimate is about 10.1%10.1\% high.

As g→0g\to0, the inner turning points approach ±1\pm1 and

W(0)=∫−11(1−q2) dq=43.\begin{aligned} W(0) &= \int_{-1}^{1} \left( 1-q^2 \right) \,dq \\ &= \frac43. \end{aligned}

This is the leading tunneling exponent. It is not safe to insert W(0)=4/3W(0)=4/3 into the energy-dependent WKB formula while keeping its original prefactor and call the result a normalized next-order estimate. Endpoint contributions migrate between exponent and prefactor when ϵloc=O(g)\epsilon_{\mathrm{loc}}=O(g) is taken to zero.

The dimensionless Euclidean action is

SE[q]=∫ds[12(dqds)2+U(q)],S_E[q] = \int ds \left[ \frac12 \left( \frac{dq}{ds} \right)^2 + U(q) \right],

and a path contributes with weight e−SE/ge^{-S_E/g}.

The Euclidean equation of motion is

d2qds2=dUdq=2q(q2−1).\frac{d^2q}{ds^2} = \frac{dU}{dq} = 2q \left( q^2-1 \right).

For a trajectory satisfying

q(−∞)=−1,q(+∞)=1,q(-\infty)=-1, \qquad q(+\infty)=1,

the first integral has zero Euclidean energy:

12(dqds)2=U(q).\frac12 \left( \frac{dq}{ds} \right)^2 = U(q).

For the increasing trajectory,

dqds=1−q2.\frac{dq}{ds} = 1-q^2.

Integration gives the instanton

qI(s)=tanh⁡(s−s0),q_I(s) = \tanh \left( s-s_0 \right),

where s0s_0 is an arbitrary center. Translation invariance in Euclidean time makes s0s_0 a collective coordinate and produces a zero mode in the fluctuation operator.

The action is

S0=∫−112U(q) dq=∫−11(1−q2) dq=43.\begin{aligned} S_0 &= \int_{-1}^{1} \sqrt{ 2U(q) } \,dq \\ &= \int_{-1}^{1} \left( 1-q^2 \right) \,dq \\ &= \frac43. \end{aligned}

Thus a one-instanton process carries the nonperturbative factor

e−S0/g=e−4/(3g).e^{-S_0/g} = e^{-4/(3g)}.

This is the same limiting action found from WKB.

The determinant calculation and zero-mode normalization belong to Fluctuation Determinants Preview. In the present Hamiltonian convention, their one-loop result gives the off-diagonal coupling

Jinst=32gπe−4/(3g)[1+O(g)].J_{\mathrm{inst}} = \sqrt{ \frac{32g}{\pi} } e^{-4/(3g)} \left[ 1+O(g) \right].

The spectral splitting is twice the coupling:

Δϵinst=48gπe−4/(3g)[1+O(g)].\Delta\epsilon_{\mathrm{inst}} = 4 \sqrt{ \frac{8g}{\pi} } e^{-4/(3g)} \left[ 1+O(g) \right].

Three pieces of this formula have different origins:

  • 4/34/3 is the classical instanton action;
  • g1/2g^{1/2} comes from Gaussian fluctuations and the translation zero mode;
  • the factor of 22 converts the one-instanton left–right coupling into the even–odd spectral gap.

At g=0.15g=0.15,

Δϵinst=3.4094183×10−4,\Delta\epsilon_{\mathrm{inst}} = 3.4094183\times10^{-4},

about 13.8%13.8\% above the numerical gap. The error is consistent with omitted relative O(g)O(g) corrections; the one-loop formula is asymptotic, not exact at finite gg.

This section summarizes the spectral audit needed to close the worked calculation. The computational notebook gives the complete implementation, extends the sweep to g=0.06g=0.06, varies NN and Ω\Omega independently, and records the floating-point plateau for the smallest gaps.

Use harmonic-oscillator basis states with adjustable frequency Ω\Omega. With effective Planck constant gg,

q=g2Ω(a+a†),q = \sqrt{ \frac{g}{2\Omega} } \left( a+a^\dagger \right),

and

HΩ=gΩ(N+12).H_\Omega = g\Omega \left( N+\frac12 \right).

The quartic Hamiltonian matrix is assembled as

Hg=HΩ+12(q2−I)2−12Ω2q2.H_g = H_\Omega + \frac12 \left( q^2-I \right)^2 - \frac12\Omega^2q^2.

Because U(q)U(q) is even, the matrix connects only basis states of the same parity. The lowest even and odd eigenvalues can therefore be found in separate blocks, avoiding accidental mixing of a nearly degenerate pair.

The table used Ω=2\Omega=2 and N=220N=220 basis states. Repeating the calculation with N=160N=160, and with Ω=1.5\Omega=1.5 and 33, changed every displayed gap by less than 6×10−146\times10^{-14} in absolute value. This is small enough to resolve the g=0.08g=0.08 gap to better than one part in a million.

The WKB column uses ϵloc=g\epsilon_{\mathrm{loc}}=g in the inner turning points. The instanton column uses the normalized one-loop formula above.

ggW(g)W(g)Δϵnum\Delta\epsilon_{\mathrm{num}}ΔϵWKB\Delta\epsilon_{\mathrm{WKB}}Δϵinst\Delta\epsilon_{\mathrm{inst}}
0.300.4640492.95206×10−22.95206\times10^{-2}4.06651×10−24.06651\times10^{-2}4.10575×10−24.10575\times10^{-2}
0.250.5879331.19615×10−21.19615\times10^{-2}1.51522×10−21.51522\times10^{-2}1.54086×10−21.54086\times10^{-2}
0.200.7162603.01756×10−33.01756\times10^{-3}3.54463×10−33.54463\times10^{-3}3.63286×10−33.63286\times10^{-3}
0.150.8502482.99603×10−42.99603\times10^{-4}3.29801×10−43.29801\times10^{-4}3.40942×10−43.40942\times10^{-4}
0.120.9341622.99115×10−52.99115\times10^{-5}3.17846×10−53.17846\times10^{-5}3.30466×10−53.30466\times10^{-5}
0.100.9919853.01409×10−63.01409\times10^{-6}3.13145×10−63.13145\times10^{-6}3.26917×10−63.26917\times10^{-6}
0.081.0516819.78792×10−89.78792\times10^{-8}9.94791×10−89.94791\times10^{-8}1.04312×10−71.04312\times10^{-7}

The pattern is systematic:

  • the WKB ratio ΔϵWKB/Δϵnum\Delta\epsilon_{\mathrm{WKB}}/\Delta\epsilon_{\mathrm{num}} falls from 1.381.38 at g=0.30g=0.30 to 1.0161.016 at g=0.08g=0.08;
  • the one-loop instanton ratio falls from 1.391.39 to 1.0661.066 over the same range;
  • both methods capture more than five orders of magnitude of suppression;
  • neither finite-gg prefactor should be judged from the exponent alone.

The slightly better performance of the displayed WKB formula at the smallest gg is model- and convention-specific. It uses the finite local energy inside the barrier action, thereby retaining some effects that appear as algebraic corrections when the instanton result is organized around the zero-energy action.

Extract the Exponent Without Fitting the Prefactor

Section titled “Extract the Exponent Without Fitting the Prefactor”

Suppose

Δϵ∼Cg e−S0/g.\Delta\epsilon \sim C\sqrt g\, e^{-S_0/g}.

Define

Seff(g)≡−glog⁡(Δϵnumg).S_{\mathrm{eff}}(g) \equiv -g \log \left( \frac{ \Delta\epsilon_{\mathrm{num}} }{ \sqrt g } \right).

Then

Seff(g)=S0−glog⁡C+O(g2),S_{\mathrm{eff}}(g) = S_0 - g\log C + O(g^2),

so

lim⁡g→0Seff(g)=43.\lim_{g\to0} S_{\mathrm{eff}}(g) = \frac43.

The numerical values increase from 0.8760.876 at g=0.30g=0.30 to 1.1901.190 at g=0.08g=0.08, approaching 4/34/3 from below. Convergence in this scaled logarithm is intentionally slow because the prefactor contributes an O(g)O(g) term. The raw splitting converges much more dramatically on a logarithmic scale.

The wavefunction amplitude crossing the central barrier scales as

Abarrier∼e−W/g.\mathcal A_{\mathrm{barrier}} \sim e^{-W/g}.

The doublet splitting is linear in the induced off-diagonal coupling:

Δϵ∼e−W/g.\Delta\epsilon \sim e^{-W/g}.

A scattering transmission probability would square an amplitude:

T∼e−2W/g.T \sim e^{-2W/g}.

Using e−2W/ge^{-2W/g} for the double-well splitting is therefore a factor-of-two error in the exponent. Boundary conditions decide whether the barrier action enters an amplitude, a probability, a spectral gap, or a decay rate.

Restoring units,

ΔE=2λa4Δϵ.\Delta E = 2\lambda a^4 \Delta\epsilon.

At leading exponential order,

ΔE∝exp⁡[−4a32mλ3ℏ].\Delta E \propto \exp \left[ - \frac{ 4a^3\sqrt{2m\lambda} }{ 3\hbar } \right].

This immediately gives three useful trends:

  • increasing the separation 2a2a suppresses the gap exponentially as a3a^3 for this quartic family;
  • increasing the mass suppresses the gap exponentially as m\sqrt m;
  • increasing λ\lambda raises the local frequency but suppresses tunneling through the stronger λ\sqrt\lambda action.

The last point warns against reasoning from an attempt frequency alone. A stiffer well produces faster local motion and a more opaque barrier; in the semiclassical regime the exponential wins.

The two-state picture requires

Δϵ≪gω0=2g.\Delta\epsilon \ll g\omega_0 = 2g.

At g=0.30g=0.30 the ratio is about 0.0490.049, already separated but not deeply asymptotic. At g=0.08g=0.08 it is about 6.1×10−76.1\times10^{-7}.

The leading local ground energy gg must lie below 1/21/2. The condition g<1/2g\lt1/2 also keeps the inner turning points real. Quantitative semiclassics needs the stronger condition g≪1g\ll1.

The instanton width in ss is order unity, while the characteristic separation between tunneling events grows as eS0/ge^{S_0/g}. A dilute instanton gas is therefore controlled when S0/g≫1S_0/g\gg1.

Agreement of S0=4/3S_0=4/3 proves agreement at leading exponential order. It does not prove that WKB endpoint matching and an instanton determinant have been normalized consistently. A prefactor claim must state its Hamiltonian convention and loop order.

Resolving Δϵ\Delta\epsilon requires absolute eigenvalue errors much smaller than the gap. Convergence of the individual energies is not enough if two nearly equal numbers are subtracted. Parity blocks, basis variation, and sufficient arithmetic precision are part of the calculation.

The transfer formula assumes an isolated closed doublet. Environmental dephasing, dissipation, a static bias, or coupling to higher states changes the dynamics even if the underlying symmetric splitting remains well defined.

  • Calling Δϵ\Delta\epsilon a tunneling probability.
  • Using the transmission exponent e−2W/ge^{-2W/g} instead of the amplitude exponent e−W/ge^{-W/g}.
  • Forgetting that the spectral gap is 2J2J, not JJ.
  • Mixing physical and dimensionless energies without the factor 2λa42\lambda a^4.
  • Treating q=0q=0 as an ordinary minimum rather than the barrier top.
  • Expanding around one well and expecting a finite power series in gg to produce e−4/(3g)e^{-4/(3g)}.
  • Replacing the finite-energy WKB action by S0S_0 while retaining an unrelated prefactor.
  • Quoting an instanton determinant without specifying the normalization of gg and HgH_g.
  • Calling the numerical gap converged after checking only the individual eigenvalues.
  • Assuming localized left and right states remain stationary; the exact stationary states have definite parity.

Starting from HphysH_{\mathrm{phys}}, set x=aqx=aq and divide the equation by 2λa42\lambda a^4. Show that the kinetic term becomes −(g2/2)d2/dq2-(g^2/2)d^2/dq^2 with

g=ℏa32mλ.g = \frac{ \hbar }{ a^3\sqrt{2m\lambda} }.
Solution

The kinetic term transforms as

−ℏ22md2dx2=−ℏ22ma2d2dq2.-\frac{\hbar^2}{2m} \frac{d^2}{dx^2} = -\frac{\hbar^2}{2ma^2} \frac{d^2}{dq^2}.

After division by 2λa42\lambda a^4, its coefficient is

−ℏ24mλa6=−12(ℏa32mλ)2.-\frac{ \hbar^2 }{ 4m\lambda a^6 } = -\frac12 \left( \frac{ \hbar }{ a^3\sqrt{2m\lambda} } \right)^2.

The potential becomes

λa4(q2−1)22λa4=12(q2−1)2.\frac{ \lambda a^4(q^2-1)^2 }{ 2\lambda a^4 } = \frac12(q^2-1)^2.

Thus the dimensionless Hamiltonian has the stated form.

Use harmonic-oscillator perturbation theory around q=1q=1 to show

ϵloc=g−14g2+O(g3).\epsilon_{\mathrm{loc}} = g-\frac14g^2+O(g^3).
Solution

With q=1+yq=1+y,

U=2y2+2y3+12y4.U=2y^2+2y^3+\frac12y^4.

The unperturbed oscillator has frequency ω0=2\omega_0=2 and

y=g2(a+a†).y = \frac{\sqrt g}{2} \left( a+a^\dagger \right).

The quartic first-order correction is

12⟨0∣y4∣0⟩=3g232.\frac12 \langle0\vert y^4\vert0\rangle = \frac{3g^2}{32}.

For the cubic term,

(a+a†)3∣0⟩=3∣1⟩+6∣3⟩.\left( a+a^\dagger \right)^3 \lvert0\rangle = 3\lvert1\rangle + \sqrt6\lvert3\rangle.

Second-order perturbation theory gives

Δϵ(3)(2)=−9g232−g216=−11g232.\Delta\epsilon_{(3)}^{(2)} = -\frac{9g^2}{32} - \frac{g^2}{16} = -\frac{11g^2}{32}.

Adding both contributions,

3g232−11g232=−14g2.\frac{3g^2}{32} - \frac{11g^2}{32} = -\frac14g^2.

Substitute qI(s)=tanh⁡(s−s0)q_I(s)=\tanh(s-s_0) into the first-order Euclidean equation and evaluate its action.

Solution

Differentiation gives

dqIds=sech⁡2(s−s0)=1−qI2.\frac{dq_I}{ds} = \operatorname{sech}^2(s-s_0) = 1-q_I^2.

Thus it satisfies

12q˙I2=12(1−qI2)2=U(qI).\frac12\dot q_I^2 = \frac12(1-q_I^2)^2 = U(q_I).

Using ds=dq/(1−q2)ds=dq/(1-q^2),

S0=∫ds q˙I2=∫−11(1−q2) dq=43.\begin{aligned} S_0 &= \int ds\, \dot q_I^2 \\ &= \int_{-1}^{1} \left( 1-q^2 \right) \,dq \\ &= \frac43. \end{aligned}

Diagonalize

Heff=ϵˉI−JσxH_{\mathrm{eff}} = \bar\epsilon I-J\sigma_x

and show that the splitting is 2J2J. Then explain why a barrier transmission probability has twice the tunneling exponent of the splitting.

Solution

The eigenvalues of σx\sigma_x are ±1\pm1, so

ϵe=ϵˉ−J,ϵo=ϵˉ+J.\epsilon_e=\bar\epsilon-J, \qquad \epsilon_o=\bar\epsilon+J.

Their difference is

Δϵ=2J.\Delta\epsilon=2J.

The off-diagonal coupling is linear in the under-barrier amplitude,

J∼e−W/g.J\sim e^{-W/g}.

A transmission probability is the modulus squared of a scattering amplitude, so

T∼∣e−W/g∣2=e−2W/g.T\sim\left|e^{-W/g}\right|^2=e^{-2W/g}.

At g=0.10g=0.10, use the numerical gap in the table to estimate the first complete left-to-right transfer time in dimensionless units.

Solution

The transfer time is

stransfer=πgΔϵ.s_{\mathrm{transfer}} = \frac{\pi g}{\Delta\epsilon}.

With g=0.10g=0.10 and Δϵ=3.01409×10−6\Delta\epsilon=3.01409\times10^{-6},

stransfer≈0.3141593.01409×10−6≈1.04×105.s_{\mathrm{transfer}} \approx \frac{0.314159}{3.01409\times10^{-6}} \approx 1.04\times10^5.

The local oscillator period is order unity in the same time variable, so the system executes many intrawell oscillations on the tunneling timescale.

Suppose the localized wells differ in energy by 2b2b. Analyze

Hbias=ϵˉI+bσz−Jσx.H_{\mathrm{bias}} = \bar\epsilon I + b\sigma_z - J\sigma_x.

Find the spectral gap and state when the eigenstates become localized.

Solution

The traceless part has eigenvalues

±J2+b2.\pm\sqrt{J^2+b^2}.

Therefore the gap is

Δϵbias=2J2+b2.\Delta\epsilon_{\mathrm{bias}} = 2\sqrt{J^2+b^2}.

For ∣b∣≪J\lvert b\rvert\ll J, the eigenstates remain close to even and odd combinations. For ∣b∣≫J\lvert b\rvert\gg J, the bias dominates the exponentially small coupling and the eigenstates become localized predominantly in opposite wells. Thus a bias that is tiny on the intrawell scale can still overwhelm tunneling.

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