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From Correlation Functions to QFT Observables

In elementary quantum mechanics, an observable is represented by an operator, and predictions are probabilities or expectation values in a specified state. Quantum field theory keeps that logic, but its most useful calculational data are usually not isolated field values. They are correlation functions of fields or composite operators at several spacetime points.

Different correlators answer different physical questions:

Physical questionCorrelator or derived object
Which excitations exist?poles, thresholds, and spectral weights of two-point functions
How does a system respond to a source?retarded correlator or susceptibility
What is a scattering amplitude?on-shell residue of a connected time-ordered correlator
What can a Euclidean calculation measure?long-distance decay and moments of Schwinger functions
How do symmetries constrain dynamics?current correlators and Ward identities
Which fluctuations are present?ordered, symmetrized, or connected correlators

The correlator is rarely the final experimental number by itself. One must still choose the state, ordering, contour, operator normalization, Fourier convention, and conversion rule appropriate to the observable.

The detailed path-integral construction belongs to Correlation Functions in Path Integrals, the pole structure belongs to Spectral Representation of Green Functions, response belongs to Green Functions and Response Preview, and scattering conventions belong to QFT Bridge: S-Matrix. This page connects those canonical homes.

Let ∣Ω⟩\lvert\Omega\rangle be a stationary state with energy EΩE_\Omega. For Heisenberg operators A(t)A(t) and B(0)B(0), consider

CAB(t):=⟨Ω∣A(t)B(0)∣Ω⟩.C_{AB}(t) := \langle\Omega\rvert A(t)B(0) \lvert\Omega\rangle.

Insert a complete energy basis:

CAB(t)=∑ne−i(En−EΩ)t/ℏ×⟨Ω∣A∣n⟩⟨n∣B∣Ω⟩.\begin{aligned} C_{AB}(t) &= \sum_n e^{-i(E_n-E_\Omega)t/\hbar} \\ &\qquad\times \langle\Omega\rvert A\lvert n\rangle \langle n\rvert B\lvert\Omega\rangle. \end{aligned}

This one formula already contains the central QFT logic:

  • oscillation frequencies reveal energy differences;
  • residues reveal matrix elements and selection rules;
  • degeneracies and continua alter the spectral structure;
  • the chosen operators decide which states have nonzero overlap.

The connected correlator removes factorized one-point data:

CABc(t):=⟨A(t)B(0)⟩−⟨A⟩⟨B⟩.C_{AB}^{\mathrm c}(t) := \langle A(t)B(0)\rangle - \langle A\rangle\langle B\rangle.

For a nondegenerate ground state, this subtraction removes the n=0n=0 vacuum contribution when AA and BB have nonzero expectation values. The remaining large-time or low-frequency behavior is controlled by the lowest excitation to which the operators couple.

At finite temperature or in a mixed stationary state, the spectral sum contains two energy labels and statistical weights. The principle remains the same: a correlator combines the spectrum with operator overlaps and state populations.

For noncommuting operators, ordering is part of the definition:

NameSchematic definitionPrimary use
Wightman⟨A(x)B(y)⟩\langle A(x)B(y)\ranglefixed-order fluctuations and spectral positivity
Time ordered⟨TA(x)B(y)⟩\langle\mathcal T A(x)B(y)\rangleperturbation theory, in-out amplitudes, source derivatives
Retarded−iℏθ(x0−y0)⟨[A(x),B(y)]⟩-\frac{i}{\hbar}\theta(x^0-y^0)\langle[A(x),B(y)]\ranglecausal response
Symmetrized12⟨{A(x),B(y)}⟩\frac12\langle\{A(x),B(y)\}\ranglefluctuation and noise conventions
Euclidean⟨TτA(xE)B(yE)⟩\langle\mathcal T_\tau A(x_E)B(y_E)\rangleimaginary-time and lattice calculations
In-incontour-ordered expectation in an initial statereal-time expectation values away from simple scattering

These objects can share a spectral density while differing in boundary values, support, thermal factors, and factors of ii. Calling all of them “the propagator” or “the Green function” hides the information needed to use them.

Fermionic time ordering also contributes a minus sign for every odd permutation of fermionic operators. Thermal correlators obey periodic or antiperiodic imaginary-time conditions according to total fermion parity.

For a scalar field and vacuum ∣0⟩\lvert0\rangle, the fixed-order Wightman functions are

Wn(x1,…,xn):=⟨0∣ϕ(x1)⋯ϕ(xn)∣0⟩,W_n(x_1,\ldots,x_n) := \langle0\rvert \phi(x_1)\cdots\phi(x_n) \lvert0\rangle,

while the time-ordered functions are

Gn(x1,…,xn):=⟨0∣T{ϕ(x1)⋯ϕ(xn)}∣0⟩.G_n(x_1,\ldots,x_n) := \langle0\rvert \mathcal T \left\{ \phi(x_1)\cdots\phi(x_n) \right\} \lvert0\rangle.

In a translation-invariant vacuum, an nn-point function depends on coordinate differences rather than all positions independently. Lorentz symmetry, internal symmetries, locality, statistics, and conservation laws further constrain its tensor and analytic structure.

Quantum fields are operator-valued distributions. The rigorous objects are smeared:

ϕ(f):=∫dDx f(x)ϕ(x),\phi(f) := \int d^D x\, f(x)\phi(x),

and the correlation functions act as multilinear distributions on test functions. Coincident-point products such as ϕ2(x)\phi^2(x) define composite operators only after regularization and renormalization.

Under suitable Wightman assumptions, the full hierarchy of vacuum correlation functions determines the Hilbert space, fields, vacuum, and symmetry action up to equivalence. This reconstruction statement explains why correlators can serve as primary data for a QFT. It does not imply that a few low-order correlators determine an arbitrary interacting theory, nor does it bypass gauge, positivity, or existence problems.

Sources, Full Correlators, and Connected Correlators

Section titled “Sources, Full Correlators, and Connected Correlators”

For a Lorentzian vacuum generating functional normalized by Z[0]=1Z[0]=1,

Z[J]=⟨0∣Texp⁡[iℏ∫dDx J(x)ϕ(x)]∣0⟩,Z[J] = \left\langle0\left| \mathcal T \exp\left[ \frac{i}{\hbar} \int d^D x\, J(x)\phi(x) \right] \right|0\right\rangle,

functional derivatives generate time-ordered products:

Gn(x1,…,xn)=(ℏi)nδnZ[J]δJ(x1)⋯δJ(xn)∣J=0.G_n(x_1,\ldots,x_n) = \left. \left( \frac{\hbar}{i} \right)^n \frac{\delta^n Z[J]} {\delta J(x_1)\cdots\delta J(x_n)} \right|_{J=0}.

Define the connected generator

W[J]:=−iℏlog⁡Z[J].W[J] := -i\hbar\log Z[J].

Derivatives of W[J]W[J] generate connected correlators, with powers of ℏ/i\hbar/i fixed by the derivative order and convention. The logarithm removes products associated with disconnected vacuum or factorized components.

Several related objects must be distinguished:

ObjectWhat has been removed or reorganizedTypical role
Full correlatornothingcomplete expectation value
Connected correlatordisconnected factorized piecesclustering, response, scattering
Amputated correlatorexternal propagator factorsapproach to a vertex or amplitude
One-particle-irreducible vertexpieces disconnected by cutting one internal lineeffective action and self-energies

These are not interchangeable names for the same function. From Sources in QM to Generating Functionals in QFT owns the functional-derivative derivation, while From Evolution Operators to Time-Ordered Products owns its interaction-picture origin.

Set ℏ=c=1\hbar=c=1 for this section. For a scalar operator in a positive-metric relativistic theory, the momentum-space Feynman two-point function has a Källén–Lehmann representation of the form

G~F(p)=∫0∞dμ2 ρ(μ2)ip2−μ2+i0.\widetilde G_F(p) = \int_0^\infty d\mu^2\, \rho(\mu^2) \frac{i} {p^2-\mu^2+i0}.

If the operator overlaps a stable one-particle state of mass mm, the spectral density contains an isolated contribution:

ρ(μ2)=Zϕδ(μ2−m2)+ρcont(μ2).\rho(\mu^2) = Z_\phi \delta(\mu^2-m^2) + \rho_{\mathrm{cont}}(\mu^2).

The physical interpretations are:

  • the pole location gives the stable particle mass;
  • the residue ZϕZ_\phi measures the overlap of the chosen field with that one-particle state;
  • the continuum begins at multiparticle thresholds allowed by the quantum numbers;
  • branch cuts encode continua rather than individual states;
  • unstable resonances generally do not appear as positive delta-function contributions for asymptotic particles.

Pole locations and threshold positions can be physical, while residues depend on operator normalization and field choice. Two different interpolating operators with the same quantum numbers can reveal the same mass spectrum but have very different overlaps.

In gauge theories, propagators of gauge-dependent elementary fields need not have a positive spectral density and need not themselves be observables. Gauge-invariant composite operators, conserved currents, and on-shell quantities provide safer physical data.

Suppose an external source f(y)f(y) couples to an operator B(y)B(y) through

δH(t)=−∫ddy f(y)B(y).\delta H(t) = - \int d^d y\, f(y)B(y).

To first order, the induced change in A(x)A(x) is

δ⟨A(x)⟩=∫dDy χABR(x−y)f(y),\delta\langle A(x)\rangle = \int d^D y\, \chi_{AB}^{R}(x-y) f(y),

where

χABR(x−y):=iℏθ(x0−y0)⟨[A(x),B(y)]⟩\chi_{AB}^{R}(x-y) := \frac{i}{\hbar} \theta(x^0-y^0) \langle [A(x),B(y)] \rangle

for the source-sign convention used here. Other pages or texts may absorb a minus sign into the definition. The step function guarantees that a later perturbation cannot change an earlier expectation value.

In field theory, response correlators include:

  • current–current correlators for conductivity and polarization;
  • density–density correlators for compressibility and structure;
  • stress-tensor correlators for viscosity and energy transport;
  • order-parameter correlators for susceptibilities near phase transitions.

The observable is obtained only after specifying tensor projections, source normalization, contact terms, and the order of limits. For example, uniform and static limits need not commute:

lim⁡ω→0lim⁡q→0χ(ω,q)≠lim⁡q→0lim⁡ω→0χ(ω,q).\lim_{\omega\to0} \lim_{\mathbf q\to0} \chi(\omega,\mathbf q) \ne \lim_{\mathbf q\to0} \lim_{\omega\to0} \chi(\omega,\mathbf q).

Ward identities from symmetries constrain these correlators. Contact terms are often required for the identity and cannot be discarded merely because they are local. Green Functions and Response Preview gives the canonical first-order derivation and convention checks.

Time-ordered correlators are off-shell functions of their external momenta. The LSZ reduction procedure extracts scattering amplitudes by isolating stable one-particle poles and removing the external propagators.

For a scalar process, the structure is schematically

M∼[∏iZi−1/2lim⁡pi2→mi2(pi2−mi2)]×G~n,c(p1,…,pn),\begin{aligned} \mathcal M &\sim \left[ \prod_i Z_i^{-1/2} \lim_{p_i^2\to m_i^2} \left( p_i^2-m_i^2 \right) \right] \\ &\qquad\times \widetilde G_{n,\mathrm c} (p_1,\ldots,p_n), \end{aligned}

with momentum-conserving delta functions and convention-dependent factors separated from M\mathcal M. The required input is the connected time-ordered correlator. Disconnected pieces describe independent propagation or spectator factors, not one connected scattering event.

LSZ requires identifiable asymptotic particle poles. Unstable particles, confinement, long-range gauge forces, massless infrared sectors, curved backgrounds, or thermal media can obstruct the elementary picture or require modified observables. Even when LSZ applies, the amplitude is not yet a cross section. One must square it, sum or average over quantum numbers, integrate over Lorentz-invariant phase space, and include flux and symmetry factors.

QFT Bridge: S-Matrix owns the normalization and asymptotic-state comparison. This page records why correlation functions are the object from which LSZ starts.

Euclidean Correlators and Lattice Observables

Section titled “Euclidean Correlators and Lattice Observables”

For an operator OO with vacuum quantum numbers removed, a zero-momentum Euclidean correlator has spectral form

CE(τ)=∑n∣⟨0∣O∣n⟩∣2e−(En−E0)τ(τ>0),C_E(\tau) = \sum_n \left| \langle0\rvert O\lvert n\rangle \right|^2 e^{-(E_n-E_0)\tau} \qquad (\tau\gt0),

in natural units and finite volume. At large τ\tau, the lowest state with nonzero operator overlap dominates:

CE(τ)∼∣⟨0∣O∣1⟩∣2e−(E1−E0)τ.C_E(\tau) \sim \left| \langle0\rvert O\lvert1\rangle \right|^2 e^{-(E_1-E_0)\tau}.

This makes Euclidean decay a practical mass or energy-gap estimator. A lattice calculation commonly chooses several gauge-invariant interpolating operators, computes their correlation matrix, and separates low-lying exponentials through fits or variational methods.

Finite volume makes the spectrum discrete and modifies thresholds. Finite lattice spacing modifies short-distance behavior. Taking the continuum and infinite-volume limits is part of the observable extraction, not an optional cleanup.

Euclidean correlators can also encode spectral and transport information, but recovering a real-time spectral density from noisy discrete data is ill-conditioned. From Euclidean Time to Euclidean QFT owns thermal circles, Matsubara frequencies, analytic continuation, and reflection positivity.

Correlation functions make symmetry constraints calculational. If JμJ^\mu is a conserved current, differentiating a time-ordered correlator produces contact terms at operator insertions. Schematically,

∂μ⟨TJμ(x)O1(x1)⋯On(xn)⟩=∑kδ(D)(x−xk)×⟨TO1⋯δOk⋯On⟩,\begin{aligned} \partial_\mu \langle \mathcal T J^\mu(x) O_1(x_1)\cdots O_n(x_n) \rangle &= \sum_k \delta^{(D)}(x-x_k) \\ &\quad\times \langle \mathcal T O_1\cdots\delta O_k\cdots O_n \rangle, \end{aligned}

up to factors and signs fixed by the current and transformation conventions. These Ward identities relate different nn-point functions and protect or constrain charges, masses, tensor structures, and renormalization.

Examples of physical information carried by symmetry correlators include:

  • charge normalization from current matrix elements;
  • polarization tensors from current two-point functions;
  • energy density and transport from stress-tensor correlators;
  • order parameters and susceptibilities from symmetry-breaking operators;
  • anomaly coefficients from otherwise violated Ward identities.

The operator must be properly renormalized, and currents can mix with other operators allowed by the same symmetries. A formal insertion is not automatically a normalized observable.

The conversion can be summarized as follows:

GoalStarting correlatorRequired conversion
Stable mass or gaptwo-point functionlocate a pole or fit long Euclidean-time decay
Spectral densityWightman, retarded, or Euclidean two-point datachoose spectral convention and perform boundary-value or inverse analysis
Linear susceptibilityretarded ABAB correlatorspecify source sign, tensor projection, contacts, and limits
Scattering amplitudeconnected time-ordered nn-point functionamputate, take on-shell residues, and normalize external states
Cross section or decay rateon-shell amplitudeadd phase space, flux, sums, averages, and symmetry factors
Static structure factordensity–density correlatorFourier transform with experimental kinematics and normalization
Lattice energy levelEuclidean correlation matrixcontrol excited states, volume, spacing, and continuum extrapolation

This table is a map, not a set of interchangeable formulas. Each row uses a different ordering, state, limiting procedure, or normalization.

An elementary field is often an interpolating operator rather than a directly measurable quantity. Its normalization can change under field redefinitions, and in a gauge theory it may be gauge dependent. Correlation functions of such fields remain useful intermediate objects, but physical claims should be attached to invariant consequences.

Further cautions include:

  • composite operators require renormalization and can mix;
  • off-shell Green functions can depend on gauge and scheme;
  • pole masses, inclusive rates, conserved charges, and properly defined on-shell amplitudes have different invariance properties;
  • infrared-safe experimental quantities may require sums over unresolved radiation;
  • vacuum, thermal, in-out, and in-in correlators describe different states or measurement protocols;
  • truncating the correlator hierarchy is an approximation whose error must be assessed.

The phrase “QFT observable” therefore includes both operator-algebra observables and experimentally inferred quantities. A correlation function becomes evidence for an observable only through a stated dictionary.

This page owns the map from classes of correlation functions to classes of QFT observables. It does not own the full derivation of source functionals, spectral representations, Kubo response, LSZ reduction, lattice spectroscopy, Ward identities, or cross-section formulas. Those remain in their canonical homes and full QFT treatments.

The one durable lesson is:

state and operator  ⟶  correlator  ⟶  analytic or limiting operation  ⟶  observable.\text{state and operator} \;\longrightarrow\; \text{correlator} \;\longrightarrow\; \text{analytic or limiting operation} \;\longrightarrow\; \text{observable}.

Skipping the middle conversion is the source of many convention and interpretation errors.

  • Calling every two-point function a propagator without specifying ordering and state.
  • Treating a connected correlator, an amputated function, and a scattering amplitude as identical.
  • Reading a field-strength residue as a universal observable independent of the interpolating operator.
  • Identifying a gauge-dependent elementary-field correlator with a direct measurement.
  • Using a time-ordered correlator where causal response requires a retarded commutator.
  • Taking static and uniform limits without specifying their order.
  • Extracting a cross section from ∣M∣2\lvert\mathcal M\rvert^2 without flux, phase space, and symmetry factors.
  • Treating an unstable resonance as an ordinary asymptotic one-particle state.
  • Assuming Euclidean data can be continued to real time without uncertainty or additional input.
  • Ignoring contact terms, operator mixing, and renormalization in current or composite-operator correlators.
  • Forgetting that the state or contour changes the correlator being computed.
  • G. Källén, “On the Definition of the Renormalization Constants in Quantum Electrodynamics,” Helvetica Physica Acta 25, 417–434, 1952.
  • H. Lehmann, “Über Eigenschaften von Ausbreitungsfunktionen und Renormierungskonstanten quantisierter Felder,” Il Nuovo Cimento 11, 342–357, 1954, doi:10.1007/BF02783624.
  • H. Lehmann, K. Symanzik, and W. Zimmermann, “On the Formulation of Quantized Field Theories,” Il Nuovo Cimento 1, 205–225, 1955, doi:10.1007/BF02731765.
  • R. Kubo, “Statistical-Mechanical Theory of Irreversible Processes. I,” Journal of the Physical Society of Japan 12, 570–586, 1957, doi:10.1143/JPSJ.12.570.
  • K. Osterwalder and R. Schrader, “Axioms for Euclidean Green’s Functions,” Communications in Mathematical Physics 31, 83–112, 1973, doi:10.1007/BF01645738.
  • R. F. Streater and A. S. Wightman, PCT, Spin and Statistics, and All That, Princeton University Press, 2000.
  • S. Weinberg, The Quantum Theory of Fields, Volume I: Foundations, Cambridge University Press, 1995.
  • M. D. Schwartz, Quantum Field Theory and the Standard Model, Cambridge University Press, 2014.

Let ∣0⟩\lvert0\rangle be a nondegenerate ground state and A=A†A=A^\dagger. Show that

CAc(t):=⟨0∣A(t)A(0)∣0⟩−⟨0∣A∣0⟩2C_A^{\mathrm c}(t) := \langle0\rvert A(t)A(0)\lvert0\rangle - \langle0\rvert A\lvert0\rangle^2

contains no n=0n=0 term in its spectral sum. What determines its longest time scale?

Solution

Insert the energy identity:

⟨0∣A(t)A(0)∣0⟩=∑ne−i(En−E0)t/ℏ∣⟨0∣A∣n⟩∣2.\langle0\rvert A(t)A(0)\lvert0\rangle = \sum_n e^{-i(E_n-E_0)t/\hbar} \left| \langle0\rvert A\lvert n\rangle \right|^2.

The n=0n=0 term is

∣⟨0∣A∣0⟩∣2,\left| \langle0\rvert A\lvert0\rangle \right|^2,

which is exactly removed by the connected subtraction. Therefore

CAc(t)=∑n≠0e−i(En−E0)t/ℏ∣⟨0∣A∣n⟩∣2.C_A^{\mathrm c}(t) = \sum_{n\ne0} e^{-i(E_n-E_0)t/\hbar} \left| \langle0\rvert A\lvert n\rangle \right|^2.

The slowest nonconstant frequency is set by the smallest gap En−E0E_n-E_0 for which ⟨0∣A∣n⟩\langle0\rvert A\lvert n\rangle is nonzero. The lowest energy in the full spectrum is irrelevant if the operator cannot couple to it because of symmetry or other selection rules.

Two scalar interpolating operators O1O_1 and O2O_2 carry the same quantum numbers and both overlap a stable one-particle state ∣p⟩\lvert p\rangle of mass mm. Explain why their two-point functions have a pole at the same p2=m2p^2=m^2 but can have different residues.

Solution

The spectral resolution of each two-point function contains the same physical intermediate state. Its energy–momentum relation fixes the pole location:

p2=m2.p^2=m^2.

The coefficient is the squared operator-state overlap:

Zi∝∣⟨0∣Oi(0)∣p⟩∣2.Z_i \propto \left| \langle0\rvert O_i(0)\lvert p\rangle \right|^2.

Because O1O_1 and O2O_2 can be normalized differently or contain different mixtures of local structures, Z1Z_1 and Z2Z_2 need not agree. The mass is a property of the state; the residue also records how efficiently the chosen operator creates that state from the vacuum.

3. Why the logarithm selects connected pairs

Section titled “3. Why the logarithm selects connected pairs”

For a normalized generating functional Z[J]Z[J], show directly that the second derivative of log⁡Z[J]\log Z[J] at J=0J=0 subtracts the product of one-point functions.

Solution

Differentiate:

δ2log⁡ZδJ(x)δJ(y)=1Zδ2ZδJ(x)δJ(y)−1Z2δZδJ(x)δZδJ(y).\frac{\delta^2\log Z} {\delta J(x)\delta J(y)} = \frac{1}{Z} \frac{\delta^2 Z} {\delta J(x)\delta J(y)} - \frac{1}{Z^2} \frac{\delta Z}{\delta J(x)} \frac{\delta Z}{\delta J(y)}.

At J=0J=0, source derivatives of ZZ insert fields, with convention-dependent factors of i/ℏi/\hbar. Since Z[0]=1Z[0]=1, the expression is proportional to

⟨Tϕ(x)ϕ(y)⟩−⟨ϕ(x)⟩⟨ϕ(y)⟩.\langle \mathcal T\phi(x)\phi(y) \rangle - \langle\phi(x)\rangle \langle\phi(y)\rangle.

This is the connected two-point function. Higher derivatives of log⁡Z\log Z similarly subtract every disconnected partition of the insertion set.

4. Causality and analyticity of retarded response

Section titled “4. Causality and analyticity of retarded response”

Let

χR(t)=θ(t)F(t),\chi^R(t) = \theta(t)F(t),

where F(t)F(t) grows slowly enough for the Fourier–Laplace transform to exist. Explain why χR(t)\chi^R(t) gives no response before a source is applied and why χR(ω)\chi^R(\omega) is analytic for Im⁡ω>0\operatorname{Im}\omega\gt0.

Solution

The step function makes

χR(t)=0for t<0.\chi^R(t)=0 \qquad \text{for }t\lt0.

Thus a source at time t′t' contributes only to measurements at t>t′t\gt t'. For complex frequency,

χR(ω)=∫0∞dt eiωtF(t).\chi^R(\omega) = \int_0^\infty dt\, e^{i\omega t}F(t).

If Im⁡ω>0\operatorname{Im}\omega\gt0, then

∣eiωt∣=e−Im⁡ω t,\left| e^{i\omega t} \right| = e^{-\operatorname{Im}\omega\,t},

which supplies exponential damping. Under the stated growth condition, the integral converges uniformly on compact subsets of the upper half-plane and defines an analytic function there. Retarded support and upper-half-plane analyticity are two forms of the same causal structure.

5. No scattering from a free four-point function

Section titled “5. No scattering from a free four-point function”

For a free scalar vacuum, Wick’s theorem gives the four-point function as a sum of products of two-point functions. Why does LSZ yield no connected 2→22\to2 scattering amplitude?

Solution

The free four-point function is

⟨Tϕ1ϕ2ϕ3ϕ4⟩=G12G34+G13G24+G14G23.\begin{aligned} \langle \mathcal T\phi_1\phi_2\phi_3\phi_4 \rangle &= G_{12}G_{34} + G_{13}G_{24} \\ &\quad + G_{14}G_{23}. \end{aligned}

Every term factorizes into two disconnected propagators. Therefore the connected four-point function vanishes:

G4,c=0.G_{4,\mathrm c} = 0.

LSZ amputates the connected correlator for one connected scattering event, so

M2→2=0.\mathcal M_{2\to2} = 0.

The disconnected terms describe free propagation and identity contributions to the SS-matrix, not an interaction-induced collision.

Suppose

CE(τ)=A0e−E0τ(1+re−Δτ),C_E(\tau) = A_0e^{-E_0\tau} \left( 1+r e^{-\Delta\tau} \right),

with A0>0A_0\gt0, r>0r\gt0, and Δ>0\Delta\gt0. Define

Eeff(τ):=−ddτlog⁡CE(τ).E_{\mathrm{eff}}(\tau) := - \frac{d}{d\tau} \log C_E(\tau).

Find Eeff(τ)E_{\mathrm{eff}}(\tau) and its large-τ\tau limit.

Solution

Differentiate the logarithm:

Eeff(τ)=E0+Δre−Δτ1+re−Δτ.\begin{aligned} E_{\mathrm{eff}}(\tau) &= E_0 + \frac{ \Delta r e^{-\Delta\tau} }{ 1+r e^{-\Delta\tau} }. \end{aligned}

As τ→∞\tau\to\infty,

re−Δτ→0,r e^{-\Delta\tau} \to 0,

so

Eeff(τ)→E0.E_{\mathrm{eff}}(\tau) \to E_0.

The approach is exponential with gap Δ\Delta. In a real lattice analysis, additional states, noise growth, finite temporal extent, and correlated fit uncertainties complicate this simple plateau picture.