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Plane Waves and Delta Normalization

Plane waves are the natural language of a free particle, but they are not ordinary square-normalizable wavefunctions on the full line. They are generalized eigenfunctions: basis objects used to build physical wave packets. Delta normalization is the bookkeeping that makes this continuum basis behave like an orthonormal basis.

This page uses the momentum convention

⟨x∣p⟩=12πℏeipx/ℏ.\langle x\vert p\rangle = \frac{1}{\sqrt{2\pi\hbar}} e^{ipx/\hbar}.

With this convention,

⟨p∣p′⟩=δ(p−p′).\langle p\vert p'\rangle = \delta(p-p').

The corresponding Fourier-transform conventions are summarized in Fourier Transform and Momentum-Space Representation.

For a nonzero constant amplitude AA,

ψp(x)=Aeipx/ℏ\psi_p(x)=A e^{ipx/\hbar}

has constant probability density:

∣ψp(x)∣2=∣A∣2.\lvert\psi_p(x)\rvert^2 = \lvert A\rvert^2.

On the full real line,

∫−∞∞∣ψp(x)∣2 dx\int_{-\infty}^{\infty} \lvert\psi_p(x)\rvert^2\,dx

diverges. A plane wave has perfectly definite momentum and is completely delocalized. It is therefore not a physical one-particle state with total probability one on the real line.

This does not make plane waves invalid. It means they are like Fourier basis functions: not themselves localized signals, but indispensable for decomposing localized states.

Momentum eigenkets are normalized by the Dirac delta distribution:

⟨p∣p′⟩=δ(p−p′).\langle p\vert p'\rangle = \delta(p-p').

In the position representation, this follows from

⟨p∣p′⟩=∫−∞∞⟨p∣x⟩⟨x∣p′⟩ dx=12πℏ∫−∞∞ei(p′−p)x/ℏ dx=δ(p−p′).\begin{aligned} \langle p\vert p'\rangle &= \int_{-\infty}^{\infty} \langle p\vert x\rangle \langle x\vert p'\rangle\,dx \\ &= \frac{1}{2\pi\hbar} \int_{-\infty}^{\infty} e^{i(p'-p)x/\hbar}\,dx \\ &= \delta(p-p'). \end{aligned}

The last line is a distributional identity, not an ordinary convergent integral. It becomes meaningful when integrated against sufficiently well-behaved wave packets.

The continuum analogue of an orthonormal basis resolution is

∫−∞∞dp ∣p⟩⟨p∣=I^.\int_{-\infty}^{\infty} dp\, \lvert p\rangle\langle p\rvert = \hat I.

In position space this gives

∫−∞∞dp ⟨x∣p⟩⟨p∣x′⟩=δ(x−x′).\int_{-\infty}^{\infty} dp\, \langle x\vert p\rangle \langle p\vert x'\rangle = \delta(x-x').

Using the plane-wave convention above,

12πℏ∫−∞∞eip(x−x′)/ℏ dp=δ(x−x′).\frac{1}{2\pi\hbar} \int_{-\infty}^{\infty} e^{ip(x-x')/\hbar}\,dp = \delta(x-x').

This is the statement that plane waves are complete as a continuum basis.

One can label a plane wave either by momentum pp or by wavenumber kk:

p=ℏk.p=\hbar k.

The normalizations differ. A pp-normalized plane wave is

⟨x∣p⟩=12πℏeipx/ℏ.\langle x\vert p\rangle = \frac{1}{\sqrt{2\pi\hbar}}e^{ipx/\hbar}.

A kk-normalized plane wave is

⟨x∣k⟩=12πeikx,\langle x\vert k\rangle = \frac{1}{\sqrt{2\pi}}e^{ikx},

with

⟨k∣k′⟩=δ(k−k′).\langle k\vert k'\rangle = \delta(k-k').

Because p=ℏkp=\hbar k,

δ(p−p′)=1ℏδ(k−k′).\delta(p-p') = \frac{1}{\hbar}\delta(k-k').

Mixing pp-normalization and kk-normalization is one of the fastest ways to lose factors of ℏ\hbar.

A physical normalized state is built from a square-integrable momentum amplitude ϕ(p)\phi(p):

∣ψ⟩=∫−∞∞dp ϕ(p)∣p⟩.\lvert\psi\rangle = \int_{-\infty}^{\infty} dp\, \phi(p)\lvert p\rangle.

The position-space wavefunction is

ψ(x)=⟨x∣ψ⟩=12πℏ∫−∞∞ϕ(p)eipx/ℏ dp.\psi(x) = \langle x\vert\psi\rangle = \frac{1}{\sqrt{2\pi\hbar}} \int_{-\infty}^{\infty} \phi(p)e^{ipx/\hbar}\,dp.

The normalization condition is

⟨ψ∣ψ⟩=∫−∞∞∣ϕ(p)∣2 dp=1.\langle\psi\vert\psi\rangle = \int_{-\infty}^{\infty} \lvert\phi(p)\rvert^2\,dp =1.

Thus ∣ϕ(p)∣2\lvert\phi(p)\rvert^2 is the momentum probability density. A sharp momentum distribution gives a spatially broad packet; a sharply localized wavefunction requires a broad range of momenta. Gaussian packets make this tradeoff explicit.

For a free particle,

E(p)=p22m.E(p)=\frac{p^2}{2m}.

A momentum component evolves as

e−iE(p)t/ℏ=e−ip2t/(2mℏ).e^{-iE(p)t/\hbar} = e^{-ip^2t/(2m\hbar)}.

Therefore a free wave packet evolves by

ψ(x,t)=12πℏ∫−∞∞ϕ(p)eipx/ℏe−ip2t/(2mℏ) dp.\psi(x,t) = \frac{1}{\sqrt{2\pi\hbar}} \int_{-\infty}^{\infty} \phi(p) e^{ipx/\hbar} e^{-ip^2t/(2m\hbar)} \,dp.

The packet spreads because the phase is quadratic in pp. The detailed behavior is treated in Wave Packet Spreading.

Delta normalization can be understood by first putting the particle in a large periodic box of length LL:

ψn(x)=1Leiknx,kn=2πnL,n∈Z.\psi_n(x) = \frac{1}{\sqrt L}e^{ik_nx}, \qquad k_n=\frac{2\pi n}{L}, \qquad n\in\mathbb Z.

Then

∫0Lψm∗(x)ψn(x) dx=δmn.\int_0^L \psi_m^*(x)\psi_n(x)\,dx = \delta_{mn}.

The allowed wavenumbers are separated by

Δk=2πL.\Delta k=\frac{2\pi}{L}.

As L→∞L\to\infty, the spectrum becomes dense and sums become integrals:

∑n⟶L2π∫dk=L2πℏ∫dp.\sum_n \longrightarrow \frac{L}{2\pi}\int dk = \frac{L}{2\pi\hbar}\int dp.

The box is a regulator, not a claim that space is literally periodic. It is useful when deriving density-of-states factors, handling intermediate infinities, or comparing continuum formulas with numerical calculations. The boundary-condition details are collected in Periodic Boundary Conditions.

Box-normalized and delta-normalized states have different dimensions. A box-normalized plane wave has amplitude 1/L1/\sqrt L. A kk-delta-normalized plane wave has amplitude 1/2π1/\sqrt{2\pi}.

The replacement

δmn⟷Δk δ(k−k′)\delta_{mn} \longleftrightarrow \Delta k\,\delta(k-k')

is a compact way to remember the continuum limit. Since Δk=2π/L\Delta k=2\pi/L, the discrete Kronecker delta turns into a Dirac delta together with the density of states.

For physical predictions, the artificial factors of LL cancel once states, sums, and densities are converted consistently.

A plane wave

ψ(x)=Aeikx\psi(x)=A e^{ikx}

has probability current

j=ℏkm∣A∣2.j=\frac{\hbar k}{m}\lvert A\rvert^2.

For a box-normalized state, this is

j=ℏkmL.j=\frac{\hbar k}{mL}.

For a scattering calculation, one often works instead with amplitudes whose incident or outgoing waves carry a convenient flux. Current normalization is a separate convention from delta normalization. The common rule is the same: state the convention before interpreting amplitudes.

  • Trying to force ∫∣eikx∣2dx=1\int\lvert e^{ikx}\rvert^2dx=1 on the full line.
  • Treating δ(p−p′)\delta(p-p') as an ordinary function rather than a distribution.
  • Mixing pp-normalized and kk-normalized states without the factor of ℏ\hbar.
  • Forgetting that a wave packet, not a single plane wave, represents a localized free particle.
  • Keeping box factors after taking the continuum limit.
  • Comparing scattering amplitudes without checking whether the normalization is square, delta, box, or flux normalization.
  • D. J. Griffiths and D. F. Schroeter, Introduction to Quantum Mechanics, 3rd ed., Cambridge University Press, 2018.
  • R. Shankar, Principles of Quantum Mechanics, 2nd ed., Springer, 1994.
  • C. Cohen-Tannoudji, B. Diu, and F. Laloë, Quantum Mechanics, Wiley, 1977.
  • J. J. Sakurai and J. Napolitano, Modern Quantum Mechanics, 3rd ed., Cambridge University Press, 2020.
  1. Verify the delta normalization of ⟨x∣p⟩\langle x\vert p\rangle using the Fourier representation of the delta function.
Solution

Using

⟨x∣p⟩=12πℏeipx/ℏ,\langle x\vert p\rangle = \frac{1}{\sqrt{2\pi\hbar}}e^{ipx/\hbar},

one finds

⟨p∣p′⟩=∫−∞∞⟨p∣x⟩⟨x∣p′⟩ dx=12πℏ∫−∞∞ei(p′−p)x/ℏ dx=δ(p−p′).\begin{aligned} \langle p\vert p'\rangle &= \int_{-\infty}^{\infty} \langle p\vert x\rangle \langle x\vert p'\rangle\,dx \\ &= \frac{1}{2\pi\hbar} \int_{-\infty}^{\infty} e^{i(p'-p)x/\hbar}\,dx \\ &= \delta(p-p'). \end{aligned}

The final equality is understood distributionally.

  1. Convert the sum over periodic-box wavevectors into an integral as L→∞L\to\infty.
Solution

Periodic boundary conditions give

kn=2πnL,k_n=\frac{2\pi n}{L},

so adjacent wavenumbers are separated by

Δk=2πL.\Delta k=\frac{2\pi}{L}.

For a smooth test function f(k)f(k),

∑nf(kn)≈1Δk∫f(k) dk=L2π∫f(k) dk.\sum_n f(k_n) \approx \frac{1}{\Delta k} \int f(k)\,dk = \frac{L}{2\pi} \int f(k)\,dk.
  1. If ϕ(p)\phi(p) is normalized by ∫∣ϕ(p)∣2dp=1\int\lvert\phi(p)\rvert^2dp=1, show that the corresponding ψ(x)\psi(x) is normalized.
Solution

The momentum kets obey completeness and delta normalization. Therefore

⟨ψ∣ψ⟩=∫dp∫dp′ ϕ∗(p)ϕ(p′)⟨p∣p′⟩=∫dp∫dp′ ϕ∗(p)ϕ(p′)δ(p−p′)=∫dp ∣ϕ(p)∣2=1.\begin{aligned} \langle\psi\vert\psi\rangle &= \int dp \int dp'\, \phi^*(p)\phi(p') \langle p\vert p'\rangle \\ &= \int dp \int dp'\, \phi^*(p)\phi(p') \delta(p-p') \\ &= \int dp\,\lvert\phi(p)\rvert^2 =1. \end{aligned}