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Composite Systems

A composite quantum system is a system modeled in terms of two or more subsystems. The parts may be separate objects, such as two atoms, or distinct degrees of freedom of one object, such as an electron’s position and spin.

For distinguishable subsystems AA and BB, the composition postulate is

HAB=HA⊗HB.\mathcal H_{AB} = \mathcal H_A\otimes\mathcal H_B.

The tensor product is the new mathematical rule required by composition. It creates room for independent preparations, joint measurements, correlations, and states that cannot be assigned separate subsystem state vectors. Those nonfactorizing pure states are entangled.

This page explains the physical structure supplied by the rule. Tensor Products develops the notation and basis mechanics, while the later pages give canonical treatments of product states, entangled states, reduced states, and local observables.

Calling a model composite means that it identifies parts whose preparations or observables can be discussed separately. The labels AA and BB can represent:

  • two spatially separated spins or particles;
  • two qubits in one device;
  • position and spin of one particle;
  • an atom and a radiation mode;
  • a system and a measurement probe;
  • a chosen system and its environment.

Subsystems need not be spatial regions, and spatial separation alone is not the definition. What matters is the modeled organization of degrees of freedom and observables.

The subsystem split is additional physical structure. A bare Hilbert space does not always come with one preferred factorization. Statements such as “this state is entangled” or “this operator is local” are meaningful only after specifying the tensor factors relative to which they are being made.

For this chapter, the factors are assumed to be distinguishable and already identified. More subtle decompositions are discussed in Entanglement Depends on Decomposition.

Suppose subsystem AA can be prepared in ∣a⟩\lvert a\rangle and subsystem BB in ∣b⟩\lvert b\rangle. The joint theory must contain a state representing both preparations at once:

∣a⟩A⊗∣b⟩B.\lvert a\rangle_A\otimes\lvert b\rangle_B.

The construction must respect superposition in each subsystem. For example,

(α∣a1⟩+β∣a2⟩)⊗∣b⟩=α∣a1⟩⊗∣b⟩+β∣a2⟩⊗∣b⟩.\begin{aligned} \left( \alpha\lvert a_1\rangle + \beta\lvert a_2\rangle \right) \otimes\lvert b\rangle &= \alpha\lvert a_1\rangle\otimes\lvert b\rangle\\ &\quad+ \beta\lvert a_2\rangle\otimes\lvert b\rangle. \end{aligned}

The same linearity holds in the second factor. The tensor product is the vector space generated by pairs of subsystem vectors subject to exactly these bilinearity relations.

Its inner product satisfies

⟨a⊗b∣a′⊗b′⟩=⟨a∣a′⟩⟨b∣b′⟩.\begin{aligned} \langle a\otimes b \mid a'\otimes b'\rangle &= \langle a\mid a'\rangle \langle b\mid b'\rangle. \end{aligned}

Therefore normalized subsystem states produce a normalized joint state, and independent Born probabilities multiply.

Neither an ordered pair nor a direct sum has the right structure. An ordered pair is not a Hilbert-space vector that supports joint quantum superpositions. A direct sum,

HA⊕HB,\mathcal H_A\oplus\mathcal H_B,

describes alternatives or sectors: a vector has one component in the AA sector and one in the BB sector. It does not describe simultaneous choices of one basis state from each subsystem.

For finite dimensions, the two constructions scale differently:

dim⁡(HA⊕HB)=dA+dB,dim⁡(HA⊗HB)=dAdB.\begin{aligned} \dim(\mathcal H_A\oplus\mathcal H_B) &= d_A+d_B,\\ \dim(\mathcal H_A\otimes\mathcal H_B) &= d_A d_B. \end{aligned}

Thus two qubits have composite dimension 2⋅2=42\cdot2=4. Their direct-sum dimension also happens to be 2+2=42+2=4, but that numerical equality is accidental; three- and four-level examples immediately distinguish the rules.

Let

{∣i⟩A}i=1dA\left\{ \lvert i\rangle_A \right\}_{i=1}^{d_A}

and

{∣j⟩B}j=1dB\left\{ \lvert j\rangle_B \right\}_{j=1}^{d_B}

be orthonormal bases. Then

{∣i⟩A⊗∣j⟩B}i,j\left\{ \lvert i\rangle_A\otimes\lvert j\rangle_B \right\}_{i,j}

is an orthonormal basis of the composite space. Orthonormality follows from

⟨i,j∣k,ℓ⟩=⟨i∣k⟩A⟨j∣ℓ⟩B=δikδjℓ.\begin{aligned} \langle i,j\mid k,\ell\rangle &= \langle i\mid k\rangle_A \langle j\mid\ell\rangle_B\\ &= \delta_{ik}\delta_{j\ell}. \end{aligned}

For two qubits, a standard ordering is

∣00⟩,∣01⟩,∣10⟩,∣11⟩,\lvert00\rangle,\quad \lvert01\rangle,\quad \lvert10\rangle,\quad \lvert11\rangle,

where the first slot refers to AA and the second to BB. An ordering convention fixes how pairs (i,j)(i,j) map to matrix rows and columns. It has no physical content, but inconsistent ordering produces wrong matrices and partial traces. See Tensor-Product Ordering.

A product basis consists of product vectors, but the vectors it spans are not all product states. Superposition creates generic vectors that may not factor.

A general bipartite pure state can be expanded as

∣Ψ⟩AB=∑i,jcij∣i⟩A⊗∣j⟩B,\lvert\Psi\rangle_{AB} = \sum_{i,j}c_{ij} \lvert i\rangle_A\otimes\lvert j\rangle_B,

with normalization

∑i,j∣cij∣2=1.\sum_{i,j}|c_{ij}|^2=1.

A product state has the form

∣Ψ⟩AB=∣ψ⟩A⊗∣ϕ⟩B.\lvert\Psi\rangle_{AB} = \lvert\psi\rangle_A \otimes \lvert\phi\rangle_B.

If

∣ψ⟩A=∑iai∣i⟩A,∣ϕ⟩B=∑jbj∣j⟩B,\lvert\psi\rangle_A = \sum_i a_i\lvert i\rangle_A, \qquad \lvert\phi\rangle_B = \sum_j b_j\lvert j\rangle_B,

then its coefficients factor:

cij=aibj.c_{ij}=a_i b_j.

Equivalently, the coefficient matrix C=(cij)C=(c_{ij}) has rank one for a nonzero product state. The dedicated Product States and Bipartite Systems pages develop these tests.

A pure state that cannot be written in product form is entangled. The Bell state

∣Φ+⟩=∣00⟩+∣11⟩2\lvert\Phi^+\rangle = \frac{ \lvert00\rangle+\lvert11\rangle }{\sqrt2}

is the standard example. Its coefficient matrix has rank two, so no choices of local amplitudes aia_i and bjb_j can reproduce it.

Entanglement is not an extra interaction term or force. It is a property of a joint state relative to a specified subsystem split. Interactions can create entanglement, but a state can remain entangled after the subsystems cease interacting.

A general state of the whole is represented by a density operator

ρAB≥0,Tr⁡ABρAB=1.\rho_{AB} \ge 0, \qquad \operatorname{Tr}_{AB}\rho_{AB}=1.

Three different structures should not be conflated.

A product state has

ρAB=ρA⊗ρB.\rho_{AB} = \rho_A\otimes\rho_B.

A separable but correlated state can be a mixture of product states:

ρAB=∑kpk ρA(k)⊗ρB(k).\rho_{AB} = \sum_k p_k\, \rho_A^{(k)} \otimes \rho_B^{(k)}.

An entangled mixed state admits no such separable decomposition.

For example,

ρcc=12∣00⟩⟨00∣+12∣11⟩⟨11∣\rho_{\mathrm{cc}} = \frac12\lvert00\rangle\langle00\rvert + \frac12\lvert11\rangle\langle11\rvert

is not a product density operator, because its outcomes are correlated. It is nevertheless separable: the displayed expression is already a convex mixture of two product states. Correlation alone is therefore not a sufficient test for entanglement.

The distinction is developed at Classical Correlation Versus Entanglement and Separable Mixed States.

An observable MAM_A acting only on subsystem AA is embedded into the composite space as

MA⊗IB.M_A\otimes I_B.

Similarly, a BB-local observable is

IA⊗MB.I_A\otimes M_B.

The identity factor is part of the operator. It states that the other subsystem is left unchanged.

Local operators on different factors commute:

[MA⊗IB, IA⊗MB]=0.\begin{aligned} [ M_A\otimes I_B,\, I_A\otimes M_B ] &=0. \end{aligned}

Indeed,

(MA⊗IB)(IA⊗MB)=MA⊗MB,(IA⊗MB)(MA⊗IB)=MA⊗MB.\begin{aligned} (M_A\otimes I_B) (I_A\otimes M_B) &= M_A\otimes M_B,\\ (I_A\otimes M_B) (M_A\otimes I_B) &= M_A\otimes M_B. \end{aligned}

The operator MA⊗MBM_A\otimes M_B is a product observable that probes joint correlations. More general joint operators are sums of tensor-product terms. In finite dimensions, operator bases on AA and BB generate an operator basis on ABAB.

The canonical local-operator treatment is Subsystems and Local Observables.

Let EaE_a be a measurement effect on subsystem AA. The corresponding effect on the joint system is

Ea⊗IB.E_a\otimes I_B.

For a joint state ρAB\rho_{AB}, the probability of outcome aa is

p(a)=Tr⁡AB ⁣[ρAB(Ea⊗IB)].p(a) = \operatorname{Tr}_{AB}\!\left[ \rho_{AB}(E_a\otimes I_B) \right].

All such local probabilities can be reproduced by one operator on HA\mathcal H_A, the reduced state

ρA=Tr⁡B(ρAB),\rho_A = \operatorname{Tr}_B(\rho_{AB}),

which is defined by the requirement

Tr⁡AB ⁣[ρAB(Ea⊗IB)]=Tr⁡A(ρAEa).\begin{aligned} \operatorname{Tr}_{AB}\!\left[ \rho_{AB}(E_a\otimes I_B) \right] &= \operatorname{Tr}_A(\rho_AE_a). \end{aligned}

The reduced state contains every prediction available from measurements on AA alone. It does not contain all joint correlations with BB.

For the Bell state ∣Φ+⟩\lvert\Phi^+\rangle,

ρA=ρB=I2.\rho_A=\rho_B=\frac{I}{2}.

The whole is in a pure state, while each subsystem is locally mixed. This is not ordinary ignorance about a hidden pure state of AA; it is the local description induced by entanglement with BB.

See Reduced States and Partial Trace: First Encounter for the calculation.

A common Hamiltonian structure is

HAB=HA⊗IB+IA⊗HB+VAB.\begin{aligned} H_{AB} &= H_A\otimes I_B + I_A\otimes H_B + V_{AB}. \end{aligned}

The first two terms generate local dynamics. The interaction term couples the factors.

If VAB=0V_{AB}=0, the local Hamiltonian terms commute and the propagator factorizes:

UAB(t,t0)=UA(t,t0)⊗UB(t,t0).U_{AB}(t,t_0) = U_A(t,t_0)\otimes U_B(t,t_0).

An initial product state remains a product:

UAB(∣ψ⟩A⊗∣ϕ⟩B)=(UA∣ψ⟩A)⊗(UB∣ϕ⟩B).\begin{aligned} & U_{AB} \left( \lvert\psi\rangle_A\otimes\lvert\phi\rangle_B \right)\\ &\qquad= \left(U_A\lvert\psi\rangle_A\right) \otimes \left(U_B\lvert\phi\rangle_B\right). \end{aligned}

More generally, local unitaries preserve whether a pure state is entangled and preserve its Schmidt coefficients. They can change local bases, but they cannot create entanglement from a product state.

A nonlocal interaction can create entanglement. For two qubits, consider

VAB=J σz⊗σz.V_{AB} = J\,\sigma_z\otimes\sigma_z.

Starting from

∣+⟩A⊗∣+⟩B,\lvert{+}\rangle_A\otimes\lvert{+}\rangle_B,

the evolved state is

∣Ψ(t)⟩=12e−iθ(∣00⟩+∣11⟩)+12eiθ(∣01⟩+∣10⟩),\begin{aligned} \lvert\Psi(t)\rangle &= \frac12 e^{-i\theta} \left( \lvert00\rangle+\lvert11\rangle \right)\\ &\quad+ \frac12 e^{i\theta} \left( \lvert01\rangle+\lvert10\rangle \right), \end{aligned}

where θ=J(t−t0)/ℏ\theta=J(t-t_0)/\hbar. Its coefficient determinant is

det⁡C=−i2sin⁡(2θ).\det C = -\frac{i}{2}\sin(2\theta).

The state is entangled whenever this determinant is nonzero. At special times it refactorizes. This simple example shows how a coupling changes not only local states but the factorization structure of the joint state.

Independent Probabilities and Correlations

Section titled “Independent Probabilities and Correlations”

For a product state ρA⊗ρB\rho_A\otimes\rho_B and local measurement effects EaE_a and FbF_b,

p(a,b)=Tr⁡ ⁣[(ρA⊗ρB)(Ea⊗Fb)]=Tr⁡(ρAEa)Tr⁡(ρBFb)=pA(a)pB(b).\begin{aligned} p(a,b) &= \operatorname{Tr}\!\left[ (\rho_A\otimes\rho_B) (E_a\otimes F_b) \right]\\ &= \operatorname{Tr}(\rho_AE_a) \operatorname{Tr}(\rho_BF_b)\\ &= p_A(a)p_B(b). \end{aligned}

Product states therefore have factorized statistics for all product measurements.

The converse requires the phrase “for all local measurements.” One factorized distribution in one chosen basis does not prove that the state is a product. Conversely, correlated outcomes do not prove entanglement because separable mixtures can also be correlated.

Entanglement concerns the structure of the state, whereas correlation concerns a selected collection of measurement statistics. The two ideas are related but not interchangeable.

For two distinguishable spin-half particles,

HAB=C2⊗C2≃C4.\mathcal H_{AB} = \mathbb C^2\otimes\mathbb C^2 \simeq \mathbb C^4.

A magnetic field acting only on spin AA contributes a term such as

HA⊗IB,H_A\otimes I_B,

while a spin-spin coupling has joint terms such as

J σA⋅σB.J\,\boldsymbol\sigma_A \mathbin{\boldsymbol\cdot} \boldsymbol\sigma_B.

The shorthand on the last line denotes a sum of tensor-product Pauli operators.

For one nonrelativistic spin-half particle,

H=L2(R3)⊗C2.\mathcal H = L^2(\mathbb R^3) \otimes \mathbb C^2.

A separated state has the form

∣ψ⟩space⊗∣χ⟩spin.\lvert\psi\rangle_{\mathrm{space}} \otimes \lvert\chi\rangle_{\mathrm{spin}}.

A Stern–Gerlach-type interaction can instead produce

∣Ψ⟩=α∣ϕ+⟩⊗∣↑⟩+β∣ϕ−⟩⊗∣↓⟩.\lvert\Psi\rangle = \alpha\lvert\phi_+\rangle \otimes\lvert\uparrow\rangle + \beta\lvert\phi_-\rangle \otimes\lvert\downarrow\rangle.

If both amplitudes are nonzero and the two spatial packets are not proportional, position and spin are entangled even though they belong to one particle.

A system SS coupled to an environment EE is modeled on

HS⊗HE.\mathcal H_S\otimes\mathcal H_E.

Joint unitary evolution can entangle them. Ignoring EE then leaves a mixed reduced state for SS, providing the structural starting point for decoherence and open-system dynamics. The reduced evolution need not itself be unitary.

The rule

HAB=HA⊗HB\mathcal H_{AB} = \mathcal H_A\otimes\mathcal H_B

is the correct first framework for distinguishable subsystems and separately modeled degrees of freedom. Several important settings require refinement:

  • Identical particles: physical states occupy symmetric or antisymmetric subspaces, and particle labels are not ordinary distinguishable subsystem labels.
  • Variable particle number: bosonic or fermionic Fock space organizes sectors with different occupation numbers.
  • Gauge theories: constraints can obstruct a naive factorization into spatial regions unless boundary or edge degrees of freedom are handled carefully.
  • Quantum field theory: local observable algebras are often more fundamental than a simple tensor factor assigned to each region.
  • Infinite families: infinite tensor products require additional analytic choices beyond finite-system notation.

These are not exceptions to linear quantum mechanics; they are warnings that identifying the physically correct subsystems can be subtler than writing labels AA and BB. Continue to Identical Particles and Fock Space for the first extensions.

  1. Identify the physical subsystem split and state what AA and BB denote.
  2. Assign Hilbert spaces HA\mathcal H_A and HB\mathcal H_B.
  3. Fix a product-basis ordering if matrices will be used.
  4. Place joint states in HA⊗HB\mathcal H_A\otimes\mathcal H_B.
  5. Embed local operators with identity factors.
  6. Separate local Hamiltonian terms from interactions.
  7. Use reduced states for local predictions and the joint state for correlations.
  8. Check whether identical-particle, gauge, or variable-number structure invalidates the naive distinguishable-factor model.
  • Treating a composite state as an ordered pair instead of a vector in a tensor-product Hilbert space.
  • Using a direct sum for two systems that exist simultaneously.
  • Forgetting that the subsystem split is part of the model.
  • Thinking every vector in HA⊗HB\mathcal H_A\otimes\mathcal H_B is a product vector.
  • Assuming a product basis means every superposition in that basis is a product state.
  • Dropping identity factors from local observables.
  • Calling every nonproduct density operator entangled.
  • Treating any observed correlation as proof of entanglement.
  • Assuming an interaction is required for an already-entangled state to remain entangled.
  • Expecting local unitary evolution to create entanglement from a product state.
  • Assigning a pure state vector to one part of an entangled pure state.
  • Applying distinguishable-particle tensor-factor intuition directly to identical particles.
  • P. A. M. Dirac, The Principles of Quantum Mechanics, 4th ed., Oxford University Press, 1958, secs. 20 and 26.
  • J. von Neumann, Mathematical Foundations of Quantum Mechanics, Princeton University Press, 1955, chs. 2–3.
  • L. E. Ballentine, Quantum Mechanics: A Modern Development, 2nd ed., World Scientific, 2014, chs. 2–3.
  • A. Peres, Quantum Theory: Concepts and Methods, Kluwer Academic, 1995, chs. 3 and 5.
  • M. A. Nielsen and I. L. Chuang, Quantum Computation and Quantum Information, 10th anniversary ed., Cambridge University Press, 2010, ch. 2.
  • J. Watrous, The Theory of Quantum Information, Cambridge University Press, 2018, chs. 1–2.
  • B. C. Hall, Quantum Theory for Mathematicians, Springer, 2013, chs. 14–16.
  1. Let dim⁡HA=2\dim\mathcal H_A=2 and dim⁡HB=3\dim\mathcal H_B=3. Compare the dimensions of HA⊗HB\mathcal H_A\otimes\mathcal H_B and HA⊕HB\mathcal H_A\oplus\mathcal H_B, and explain which one describes two simultaneous subsystems.
Solution

The tensor-product dimension is

dim⁡(HA⊗HB)=2⋅3=6.\dim(\mathcal H_A\otimes\mathcal H_B) = 2\cdot3 =6.

Its basis contains every simultaneous pair ∣i⟩A⊗∣j⟩B\lvert i\rangle_A\otimes\lvert j\rangle_B.

The direct-sum dimension is

dim⁡(HA⊕HB)=2+3=5.\dim(\mathcal H_A\oplus\mathcal H_B) = 2+3 =5.

A direct sum organizes alternatives or sectors rather than simultaneous independent choices. The tensor product is therefore the composition rule for the two subsystems.

  1. Let ∣a⟩\lvert a\rangle and ∣b⟩\lvert b\rangle be normalized. Prove that ∣a⟩⊗∣b⟩\lvert a\rangle\otimes\lvert b\rangle is normalized and that product-measurement probabilities factor.
Solution

The tensor-product inner product gives

∥∣a⟩⊗∣b⟩∥2=⟨a∣a⟩⟨b∣b⟩=1.\begin{aligned} \lVert\lvert a\rangle\otimes\lvert b\rangle\rVert^2 &= \langle a\mid a\rangle \langle b\mid b\rangle\\ &=1. \end{aligned}

For local projectors PP and QQ,

p(P,Q)=⟨a⊗b∣P⊗Q∣a⊗b⟩=⟨a∣P∣a⟩⟨b∣Q∣b⟩=pA(P)pB(Q).\begin{aligned} p(P,Q) &= \langle a\otimes b\mid P\otimes Q \mid a\otimes b\rangle\\ &= \langle a\mid P\mid a\rangle \langle b\mid Q\mid b\rangle\\ &= p_A(P)p_B(Q). \end{aligned}

The factorization follows from both the state and the measurement being products.

  1. Determine whether each two-qubit state is a product state:
∣Ψ1⟩=12(∣00⟩+∣01⟩+∣10⟩+∣11⟩),∣Ψ2⟩=12(∣00⟩+∣11⟩).\begin{aligned} \lvert\Psi_1\rangle &= \frac12( \lvert00\rangle+\lvert01\rangle +\lvert10\rangle+\lvert11\rangle),\\ \lvert\Psi_2\rangle &= \frac{1}{\sqrt2}( \lvert00\rangle+\lvert11\rangle). \end{aligned}
Solution

The first state factors:

∣Ψ1⟩=∣0⟩+∣1⟩2⊗∣0⟩+∣1⟩2=∣+⟩⊗∣+⟩.\begin{aligned} \lvert\Psi_1\rangle &= \frac{\lvert0\rangle+\lvert1\rangle}{\sqrt2} \otimes \frac{\lvert0\rangle+\lvert1\rangle}{\sqrt2}\\ &= \lvert+\rangle\otimes\lvert+\rangle. \end{aligned}

It is a product state.

For ∣Ψ2⟩\lvert\Psi_2\rangle, the coefficient matrix is

C2=12(1001).C_2= \frac{1}{\sqrt2} \begin{pmatrix} 1&0\\ 0&1 \end{pmatrix}.

It has rank two, whereas a nonzero product state’s coefficient matrix has rank one. Thus ∣Ψ2⟩\lvert\Psi_2\rangle is entangled.

  1. Prove that MA⊗IBM_A\otimes I_B commutes with IA⊗MBI_A\otimes M_B. Then find their product.
Solution

Use

(X⊗Y)(X′⊗Y′)=XX′⊗YY′.(X\otimes Y)(X'\otimes Y') = XX'\otimes YY'.

Then

(MA⊗IB)(IA⊗MB)=MA⊗MB,(IA⊗MB)(MA⊗IB)=MA⊗MB.\begin{aligned} (M_A\otimes I_B)(I_A\otimes M_B) &= M_A\otimes M_B,\\ (I_A\otimes M_B)(M_A\otimes I_B) &= M_A\otimes M_B. \end{aligned}

The two products are equal, so

[MA⊗IB, IA⊗MB]=0.[ M_A\otimes I_B,\, I_A\otimes M_B ] =0.

Their product is the joint product operator MA⊗MBM_A\otimes M_B.

  1. For the Bell state ∣Φ+⟩\lvert\Phi^+\rangle, compute the probabilities of measuring Z=+1Z=+1 and Z=−1Z=-1 on subsystem AA only. What local density operator reproduces them in every basis?
Solution

The Bell state is

∣Φ+⟩=∣00⟩+∣11⟩2.\lvert\Phi^+\rangle = \frac{\lvert00\rangle+\lvert11\rangle}{\sqrt2}.

Measuring ZZ on AA gives +1+1 from the ∣00⟩\lvert00\rangle term and −1-1 from the ∣11⟩\lvert11\rangle term, each with probability 1/21/2.

Tracing out BB gives

ρA=12∣0⟩⟨0∣+12∣1⟩⟨1∣=I2.\rho_A = \frac12\lvert0\rangle\langle0\rvert + \frac12\lvert1\rangle\langle1\rvert = \frac{I}{2}.

The maximally mixed state I/2I/2 reproduces all local measurement probabilities, not only the computational-basis probabilities.

  1. Consider
ρcc=12∣00⟩⟨00∣+12∣11⟩⟨11∣.\rho_{\mathrm{cc}} = \frac12\lvert00\rangle\langle00\rvert + \frac12\lvert11\rangle\langle11\rvert.

Show that it is correlated but separable, and compare it with the Bell-state density operator.

Solution

In the computational basis, the joint outcomes are perfectly correlated:

p(0,0)=p(1,1)=12,p(0,1)=p(1,0)=0.\begin{aligned} p(0,0)=p(1,1)=\frac12, \\ p(0,1)=p(1,0)=0. \end{aligned}

Each marginal is uniform, so the joint distribution does not factor into its marginals. The state is correlated.

It is separable because it is explicitly a convex mixture of the product states ∣00⟩\lvert00\rangle and ∣11⟩\lvert11\rangle.

The Bell-state density operator contains coherence terms:

∣Φ+⟩⟨Φ+∣=12(∣00⟩⟨00∣+∣00⟩⟨11∣+∣11⟩⟨00∣+∣11⟩⟨11∣).\begin{aligned} \lvert\Phi^+\rangle\langle\Phi^+\rvert &= \frac12\bigl( \lvert00\rangle\langle00\rvert + \lvert00\rangle\langle11\rvert\\ &\quad+ \lvert11\rangle\langle00\rvert + \lvert11\rangle\langle11\rvert \bigr). \end{aligned}

Those off-diagonal joint coherences distinguish the Bell state from ρcc\rho_{\mathrm{cc}}. The Bell state is entangled; ρcc\rho_{\mathrm{cc}} is not.

  1. For VAB=Jσz⊗σzV_{AB}=J\sigma_z\otimes\sigma_z, evolve ∣+⟩⊗∣+⟩\lvert+\rangle\otimes\lvert+\rangle for θ=J(t−t0)/ℏ\theta=J(t-t_0)/\hbar. At which values of θ\theta is the resulting pure state a product?
Solution

The states ∣00⟩\lvert00\rangle and ∣11⟩\lvert11\rangle have eigenvalue +1+1 under σz⊗σz\sigma_z\otimes\sigma_z, while ∣01⟩\lvert01\rangle and ∣10⟩\lvert10\rangle have eigenvalue −1-1. Therefore

∣Ψ(t)⟩=12(e−iθeiθeiθe−iθ)\begin{aligned} \lvert\Psi(t)\rangle &= \frac12 \begin{pmatrix} e^{-i\theta}\\ e^{i\theta}\\ e^{i\theta}\\ e^{-i\theta} \end{pmatrix} \end{aligned}

in the standard product ordering. Its coefficient matrix is

C=12(e−iθeiθeiθe−iθ).C= \frac12 \begin{pmatrix} e^{-i\theta}&e^{i\theta}\\ e^{i\theta}&e^{-i\theta} \end{pmatrix}.

A two-qubit pure state is a product exactly when det⁡C=0\det C=0. Here

det⁡C=−i2sin⁡(2θ).\det C = -\frac{i}{2}\sin(2\theta).

Thus the state is a product when

θ=nπ2,n∈Z,\theta=\frac{n\pi}{2}, \qquad n\in\mathbb Z,

and is entangled at all other times.

  1. Consider the spin-position state
∣Ψ⟩=α∣ϕ+⟩⊗∣↑⟩+β∣ϕ−⟩⊗∣↓⟩.\lvert\Psi\rangle = \alpha\lvert\phi_+\rangle\otimes\lvert\uparrow\rangle + \beta\lvert\phi_-\rangle\otimes\lvert\downarrow\rangle.

Give two distinct conditions under which this state is a product, and explain why the subsystem labels matter.

Solution

The state is a product if one branch is absent, so α=0\alpha=0 or β=0\beta=0.

It is also a product if the spatial states are proportional:

∣ϕ−⟩=eiγ∣ϕ+⟩.\lvert\phi_-\rangle = e^{i\gamma}\lvert\phi_+\rangle.

Then

∣Ψ⟩=∣ϕ+⟩⊗(α∣↑⟩+eiγβ∣↓⟩).\begin{aligned} \lvert\Psi\rangle &= \lvert\phi_+\rangle \otimes \left( \alpha\lvert\uparrow\rangle + e^{i\gamma}\beta\lvert\downarrow\rangle \right). \end{aligned}

Otherwise, with both amplitudes nonzero and linearly independent spatial states, the state is entangled between the position and spin factors.

The conclusion refers specifically to the decomposition

L2(R3)⊗C2.L^2(\mathbb R^3)\otimes\mathbb C^2.

Entanglement is always stated relative to a chosen subsystem factorization.